Mineralogical and geochemical features of authigenic carbonates on seepings and hydrothermal fields (By the examples of the Black Sea reefs and the mounds of the lost city field)

Two genetically different types of authigenic carbonate mounds are studied: those within an active hydrothermal field related to serpentinite protrusions in the zone of intersection of a transform fracture zone and the Mid-Atlantic Ridge, and those in an active field of methane seepings in the Dnieper canyon of the Black sea. The general geochemical conditions under which authigenic carbonate formation occurs in the two fields considered were found. They include the presence of reduced H₂S, H₂, and CH₄ gases at the absence of free oxygen; the high alkalinity of the waters participating in the carbonate formation; the similarity of the textural and structural features of authigenic aragonite, which represents the initial mineral of the carbonate matter of the mounds; the paragenesis of aragonite with sulfide minerals; and the close relation of carbonate mounds with communities of sulfate-reducing and methane-oxidizing microorganisms. A new mechanism of formation of hydrothermal authigenic carbonates is suggested; it implies their microbial sulfate reduction over the hydrogen of the fluid in the subsurface zone (biosphere) of mixing between the hydrothermal solution and the adjacent seawater.     

Quasi-biennial variations in ozone and meteorological parameters over western Europe from ozonesonde data

Quasi-biennial variations in vertical profiles of ozone, temperature, air pressure, and zonal and meridional wind velocities are analyzed from ozonesonde data obtained at the western European stations of Lindenberg, Hohenpeissenberg, and Payerne. The effect of quasi-biennial variations manifests itself variously in different variables and is nonuniform in altitude. The period of quasi-biennial variations is not constant, and the values of the mean period group mainly around 2 and 2.5 years. As in the North American region, the effects of quasi-biennial variations in different parameters of the stratosphere and troposphere over western Europe are due to a combination of the effects of the quasi-biennial oscillation (QBO) in the equatorial stratosphere, the El Niño-Southern Oscillation (ENSO), and the North Atlantic Oscillation (NAO). The observed 2.5-year variations in stratospheric ozone are related to the equatorial QBO to a larger extent in comparison with variations in other variables. It seems likely that a determining influence on variations in stratospheric wind and temperature is exerted by the ENSO. Variations in tropospheric and stratospheric parameters with a mean period of about 2 years are due to the ENSO and NAO effects.     

Suspended sediment concentration in a buoyant plume: Fraser River,Canada

A study of suspended sediment concentration in the buoyant plume of the Fraser River, Canada, showed that unstratified flow conditions at the river mouth caused resuspension of sandy bed material and high concentrations of coarse sediment. When flow at the mouth was stratified, sediment was fine-grained and concentrations were low. Application of a multivariate model revealed that suspended sediment concentration along the plume axis was controlled primarily by distance seaward of the river mouth, secondly by tidal height, and least by sediment concentration in the river.     

A technique for conducting seismic refraction experiments on the ocean bed using bottom shots

A technique has been devised for firing arrays of bottom shots on the ocean bed in depths upto 4000 m or more. Ten kilogram explosive charges are dropped from the surface while the shooting ship is navigated acoustically. They are detonated at preset times by an electronic timer which initiates an electrical detonator, detonating cord and cast PETN/TNT explosive. Ranges to ocean bottom seismographs, and the shot instants, can be calculated from the arrival-time differences of the direct and surface-reflected water waves. The accuracy, which is dependent on water-depth and range, was better than 22 m in range and 14 msec in shot instant for our experiments.     

An experimental marine ecosystem study of the pelagic biogeochemistry of pentachlorophenol

The marine biogeochemistry of pure pentachlorophenol was studied relative to a control treatment at a scale which provided a good model for the pelagic planktonic environment (70 m³ polyethylene bags). Pentachlorophenol that was dispersed at concentrations of 10 and 100 μg/litre showed identical relative rates of decrease over 25 days to concentrations 32·8% and 31·1%, respectively, of the initial concentrations. No bioaccumulation by phytoplankton or zooplankton was observed and pentachlorophenol removal by adsorption (by particulates, zooplankton or the enclosure walls) was insignificant. The log of the pentachlorophenol concentration was significantly correlated to the hours of bright sunshine up to Day 18, after which the photolysis efficiency decreased as the proportion of pentachlorophenol exposed to sunlight decreased. The results imply a long residence time for pentachlorophenol in deeper waters outside the photolysis zone. A persistent reduction in the primary production and production per unit carbon was observed at 100 μg/litre and, when coupled to the reproducible demise of the centric diatom Skeletonema costatum in culture and the spiked enclosures, suggests that pentachlorophenol inhibits phytoplankton growth.     

A nomogram method for predicting the movement of oil slicks

In order to obtain quick initial guidance on a first estimation of motion of the spilled oil, a simple manual procedure incorporating advection and spreading processes has been devised. This procedure involves the utilization of a nomogram based on simplified equations. Spill displacements throughout a given forecast period can be easily read from the nomogram. The technique is demonstrated with a real spill case.     

Tephrostratigraphy and paleo-environmental implications of Late Quaternary sediments and interstitial water in the western Ulleung Basin, East/Japan Sea

Two piston cores, collected from the western Ulleung Basin of the East/Japan Sea, were used to investigate the Late Quaternary tephrostratigraphy, lithology, and mineralogy of the sediments, as well as the elemental composition of both sediments and interstitial water, and their paleo-environmental implications. The cores show two lapilli tephra layers and one rhyolitic ash layer at the boundaries between sedimentary lithofacies units I, II, and III. These layers can be correlated with the well-known Ulleung-Oki (ca. 9.3 ka; boundary of units I/II), Ulleung-Yamato (ca. 25–33 ka), and Aira-Tanzawa (ca. 25.1 ka; boundary of units II/III) layers, respectively. These data suggest that the cores cover the period from the middle stage of marine isotope stage (MIS) 3 to the Holocene. In each core, a so-called dark laminated mud (DLM) layer in unit II commonly has high contents of Si and Al, suggesting that the DLM layer generally contains significant amounts of fine-grained silicates and/or aluminosilicates. In addition, these DLM layers are enriched in Fe relative to Mn, iron being predominantly bound in framboidal pyrite. The size distribution of pyrite in the DLM layers suggests that these have formed under anoxic (euxinic) conditions at times of reduced water circulation in the basin during sea-level lowstand (euxinic environment). The C/N ratios [5–12] suggest that sedimentary organic matter in the cores is predominantly of marine origin. Total organic carbon (TOC) contents increased shortly before Termination I. This could have been caused by an increased flux of marine organic matter in association with sea-level rise. The C and S values of units II and III (Late Pleistocene sediments; C: <2.0%; S: 0.5–2.1%) suggest a more euxinic environment than that of unit I (Holocene sediments; C: 1.0–3.5%; S: <1.0%). Concentrations of SO₄^2– in the interstitial water decrease with increasing burial depth, whereas CH₄ concentrations show the reverse trend. Therefore, it seems that sulfate reduction, probably related to microbial activity, predominates in the upper core sections (<5 m), shifting to methanogenesis in the lower core sections.     

Structure of the Wave Bottom Boundary Layer over Smooth and Rough Bottoms

The comparison of six well-known models of the wave bottom boundary layer shows that they are identical in the case of a smooth bottom but exhibit serious differences for the other types of conditions. The thickness of the wave bottom boundary layer and the coefficient of vertical diffusion of momentum are studied by using the relations of the k-ε-model. The validity of these estimates is checked by comparing the measured and computed values of the friction velocity. This comparison demonstrates fairly good agreement between the results characterized by a coefficient of correlation equal to 0.851. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 6, pp. 54–67, November–December, 2005.     

Environmental change and oyster colonization within the Hudson River estuary linked to Holocene climate

Geophysical mapping and sampling data provide a record of changing environmental and faunal conditions within the Hudson River estuary during the mid- to late Holocene. On the shallow, broad marginal flats of the mesohaline Hudson, fossil oyster beds (Crassostrea virginica) are found exposed on the river bottom and buried by sediment. The shallowest beds are well imaged in chirp sub-bottom and side-scan sonar data and form discrete flow-perpendicular bands, 0.6–1.0 km wide and up to 3 km long, which cover 30% of the river bottom. Radiocarbon-dated sediment cores indicate oysters thrived within two time periods from ~500–2,400 and ~5,600–6,100 cal. years b.p. Sediment and physical property data indicate a changing depositional regime consistent with the oyster chronology. Similar changes in oyster presence are found in local shell midden sites of the Lower Hudson Valley as well as elsewhere along the Atlantic coast, and may reflect climatic controls associated with warm–cool cycles during the Holocene. Oysters flourished during the mid-Holocene warm period, disappeared with the onset of cooler climate at 4,000–5,000 cal. years b.p., and returned during warmer conditions of the late Holocene. The most recent demise of oysters within the Hudson at 500–900 cal. years b.p. may have accompanied the Little Ice Age.