Mathematical modeling of PCB bioaccumulation in Perna viridis

In the present work, we built a mathematical model of polychlorinated biphenyl (PCB) bioaccumulation in Perna viridis, namely, a one-compartment model with a time dependent incorporation rate R (μg g⁻¹ lipid per ppb water per day), with positive substrate cooperativity as the underlying physical mechanism. The temporal change of the PCB concentration Q (μg g⁻¹ lipid) in the soft tissues of the mussel depends on the competition of the input rate RW and the output rate kQ, where W is the concentration of PCB in water (ppb water) and k is the elimination rate (per day). From our experimental data, k=0.181±0.017 d⁻¹. The critical concentration in water W_c for positive substrate cooperativity was found to be 2.4 ppb. Below W_c, R is a constant. For a water concentration of 0.5 ppb Aroclor 1254, R=24.0±2.4 μg g⁻¹ lipid ppb⁻¹ d⁻¹. Above W_c, positive substrate cooperativity comes into effect and R becomes a function of time and dependent on the concentration Q in a form R=γQ/(Q+δ). This is the case for a water concentration of 5 ppb Aroclor 1254, where γ=15.1 μg g⁻¹ lipid ppb⁻¹ d¹ and δ≈200 μg g⁻¹ lipid. From this model, the uptake is exponentially increasing when the PCB concentration in the mussel is small compared to 200 μg g⁻¹ lipid, and hyperbolically increasing when the concentration is large compared to 200 μg g⁻¹ lipid, which are consistent with the experimental data. The model is useful for understanding the true processes taking place during the bioaccumulation and for risk assessment with higher confidence. Future experimental data which challenge the present model are anticipated and in fact desirable for improvement and perfection of the model.     

Fractal properties of medium and seismoelectric phenomena

Electrokinetic phenomena in a water-porous medium with a fractal structure above percolation threshold are theoretically investigated. Fracture zone with space-variable porosity is considered as a model of an earthquake hypocenter zone in which the electrokinetic current results from fluid filtration in a fractal pore network. A critical exponent of the streaming potential coefficient is found to depend on both the transport critical exponent and correlation length critical exponent. In this model, logarithmic dependence of electric field amplitude E on the earthquake magnitude M is derived which is compatible with the one observed by the VAN group. Without fractal properties, this form of dependence contradicts the empirical data. The electromagnetic field far from the hypocenter is calculated, which leads to the prediction of weak magnetic field variations. To explain the observed amplitude of VAN's Seismic Electric Signals (SES), the electric source must be at a distance of about 10 km from the registration point if the medium is homogeneous. Therefore, some conductive channel(s) are needed to explain the long distance selective SES transmission.     

Seismic evaluation of existing nuclear facility using ambient vibration test to characterize dynamic behavior of the structure and microtremor measurements to characterize the soil: a case study

The methods used for a building seismic hazard evaluation are presented with the associated results. The goals of the study are (1) to check the soil nature and the existence or not of a possible site effect around the installation and (2) to characterize the dynamic behavior of the building using ambient vibration records.

The results of the soil study with the Nakamura method are very difficult to interpret because they are not stable in space and time. The spectral ratios method has been used with regional earthquake records. The results of the application of this method allowed us to conclude that the installation was free of site effect.

The ambient vibration measurements on the building brought the conclusion to determine the first and second modes of the structure. These results have been used to calibrate numerical model. The modal shapes in plan (high roof) and in elevation (main column) have been evaluated. The damping of the building has been computed using ambient vibration records.     

A rifted inside corner massif on the Mid-Atlantic Ridge at 5°S

The structure of the Mid-Atlantic Ridge at 5°S was investigated during a recent cruise with the FS Meteor. A major dextral transform fault (hereafter the 5°S FZ) offsets the ridge left-laterally by 80 km. Just south of the transform and to the west of the median valley, the inside corner (IC – the region bounded by the ridge and the active transform) is marked by a major massif, characterized by a corrugated upper surface. Fossil IC massifs can also be identified further to the west. Unusually, a massif almost as high as the IC massif also characterizes the outside corner (OC) south of the inactive fracture zone and to the east of the median valley. This OC massif has axis-parallel dimensions identical to the IC massif and both are bounded on their sides closest to the spreading axis by abrupt, steep slopes. An axial volcanic ridge is well developed in the median valley both south of the IC/OC massifs and in an abandoned rift valley to the east of the OC massif, but is absent along the new ridge-axis segment between the IC and OC massifs. Wide-angle seismic data show that between the massifs, the crust of the median valley thins markedly towards the FZ. These observations are consistent with the formation of the OC massif by the rifting of an IC core complex and the development of a new spreading centre between the IC and OC massifs. The split IC massif presents an opportunity to study the internal structure of the footwall of a detachment fault, from the corrugated fault surface to deeper beneath the fault, without recourse to drilling. Preliminary dredging recovered gabbros from the scarp slope of the rifted IC massif, and serpentinites and gabbros from the intersection of this scarp with the corrugated surface. This is compatible with a concentration of serpentinites along the detachment surface, even where the massif internally is largely plutonic in nature.     

The Influence of 3-D Structure on the Propagation of Seismic Waves Away from Earthquakes

-- The seismic records from significant earthquakes are profoundly affected by 3-D variations in crustal structure both in the source zone itself and in propagation to some distance. Even in structurally complex zones such as Japan and Mexico relatively coherent arrivals are found associated with different classes of propagation paths. The presence of strong lateral variations can disrupt the arrivals, and impose significant variations in propagation characteristics for different directions from the source as illustrated by observations for the 1995 Kobe and 2000 Tottori-ken Seibu earthquakes in western Japan. Such effects can be modelled in 3 dimensions using a hybrid scheme with a pseudospectral representation for horizontal coordinates and finite differences in depth. This arrangement improves parallel implementation by minimising communication costs. For a realistic 3-D model for the structure in western Japan the 3-D simulations to frequencies close to 1 Hz provide a good representation of the observations from subduction zones events such as the 1946 Nankai earthquake and the 2000 Tottori-ken Seibu earthquake. The model can therefore be used to investigate the pattern of ground motion expected for future events e.g., in current seismic gaps.     

Structural Variations of Bottom Sediments in the Rybinsk Reservoir

Long-standing variations in the structure of bottom sediments within typical habitats of the aquatic life are characterized using the Volzhskii Pool of the Rybinsk Reservoir as an example. The role of hydrodynamic processes of the littoral zone in the formation of the ground complex of shallow water areas of the pool is discussed. The trends in variation in the quality of bottom substrate in fish habitats are analyzed. The peculiarities of long-standing variations in the distribution of types of bottom sediments in the entire reservoir are shown.     

Analysis of Space and Time Variations in the Suspended Matter Distribution in Kaliningrad Bay of the Baltic Sea

The distribution of suspension, its composition, and particle size characteristics are studied in Kaliningrad Bay. Zoning of the bay according to the water turbidity is made. The main factors controlling the formation and space and time variations in the suspended matter are determined.     

The Hydrological Regime and the Peculiarities of Formation of the Po River Delta

The peculiarities of the hydrological regime of the delta and near-shore zone of the Po River are discussed. The intrusion of salt seawater into the delta is described. The history of the Po Delta formation has been restored on the basis of the analysis of historical, archeological, and cartographic data. As shown, the peculiarities of hydrological and morphological processes in the Po River mouth are associated with natural and specifically with human-induced variations in sediment runoff of the river, with levee construction along branches, subsidence of deltaic deposits, and eustatic rise of the sea level.     

Gravity and magnetic signatures of volcanic plugs related to Deccan volcanism in Saurashtra, India and their physical and geochemical properties

The Bouguer anomaly and the total intensity magnetic maps of Saurashtra have delineated six circular gravity highs and magnetic anomalies of 40-60 mGal (10⁻⁵m/s²) and 800-1000 nT, respectively. Three of them in western Saurashtra coincide with known volcanic plugs associated with Deccan Volcanic Province (DVP), while the other three in SE Saurashtra coincide with rather concealed plugs exposed partially. The DVP represents different phases of eruption during 65.5±2.5 Ma from the Reunion plume. The geochemical data of the exposed rock samples from these plugs exhibit a wide variation in source composition, which varies from ultramafic/mafic to felsic composition of volcanic plugs in western Saurashtra and an alkaline composition for those in SE Saurashtra. Detailed studies of granophyres and alkaline rocks from these volcanic plugs reveal a calc-alkaline differentiation trend and a continental tectonic setting of emplacement. The alkaline plugs of SE Saurashtra are associated with NE-SW oriented structural trends, related to the Gulf of Cambay and the Cambay rift basin along the track of the Reunion plume. This indicates a deeper source for these plugs compared to those in the western part and may represent the primary source magma. The Junagadh plug with well differentiated ring complexes in western Saurashtra shows well defined centers of magnetic anomaly while the magnetic anomalies due to other plugs are diffused though of the same amplitude. This implies that other plugs are also associated with mafic/ultramafic components, which may not be differentiated and may be present at subsurface levels. Paleomagnetic measurements on surface rock samples from DVP in Saurashtra suggest a susceptibility of 5.5×10⁻² SI units with an average Koenigsberger ratio (Q_n) of almost one and average direction of remanent magnetization of D=147.4° and I=+56.1°. The virtual geomagnetic pole (VGP) position computed from the mean direction of magnetization for the volcanic plugs and Deccan basalt of Saurashtra is 30°N and 74°W, which is close to the VGP position corresponding to the early phases of Deccan eruption. Modeling of gravity and magnetic anomalies along two representative profiles across Junagadh and Barda volcanic plugs suggest a bulk density of 2900 and 2880 kg/m³, respectively and susceptibility of 3.14×10⁻² SI units with a Q_n ratio of 0.56 which are within the range of their values obtained from laboratory measurements on exposed rock samples. The same order of gravity and magnetic anomalies observed over the volcanic plugs of Saurashtra indicates almost similar bulk physical properties for them. The inferred directions of magnetization from magnetic anomalies, however, are D=337° and 340° and I=−38° and −50° which represent the bulk direction of magnetization and also indicate a reversal of the magnetic field during the eruption of these plugs. Some of these plugs are associated with seismic activities of magnitude ≤4 at their contacts. Based on this analysis, other circular/semi-circular gravity highs of NW India can be qualitatively attributed to similar subsurface volcanic plugs.