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91.
92.
Uwe Walzer 《Physics of the Earth and Planetary Interiors》1982,30(1):62-83
A new equation of state for metals is developed. The starting point for this development is a realistic expression for the free energy, allowance being made not only for the lattice energy but also for the Fermi energy, the exchange and correlation energies of the electrons. This expression is extended by means of three free parameters. The equation of state is successfully transformed in such a way that only macrophysical material parameters occur in it. In this way, the equation can be applied both to experimental high-pressure physics and to geophysics, its advantage resting in the fact that the bonding structure has been taken into account better than in other equations of state.The new equation, along with two other well-proven equations of state, was tried out on isothermal and Hugoniot data of 40 materials. Good agreement with the measured data was found not only for metallic elements, but also for halides and some oxides of geophysical importance. This agreement even proved to be better for most of the materials than that obtained with the other two equations of state. 相似文献
93.
The distribution of dissolved and particle-bound phosphorus (P) was investigated in the Elbe estuary during March 1995. The forms of particulate P were studied with a sequential extraction technique. Organic P dominated particle-bound P in the outer reaches of the estuary (52%), decreased to a minimum of 21% in the turbidity zone, and increased to 33% further upstream. Fe-bound P was the second most important P species in the outer reaches (27%) and dominated in the turbidity zone (up to 57%) and upstream of the turbidity zone (up to 48%). The P:Fe ratio increased with decreasing salinity, from 0.11 in the outer reaches to about 0.22 at zero salinity. Dissolved inorganic P release from reverine suspended matter was about two to three times larger than release, from marine suspended matter and was dominated by release of Fe-bound P. Dissolved inorganic P release from marine and from riverine organic matter were of equal importance. Because marine suspended matter dominates in the estuary, this suggests riverine organic matter is remineralized much faster than marine organic matter. This is in line with the refractory nature of marine organic matter (no phytoplankton bloom) and the easily degradable character of the riverine suspended matter (phytoplankton bloom) in the Elbe estuary during March 1995. 相似文献
94.
Summary A simple procedure is presented to eliminate the influence of tidal oscillation from hydrographic measurements. This is done with a transformation from a co-ordinate system fixed in space to a co-ordinate system fixed in time using results of a numerical tidal model. The procedure is applied to a hydrographic survey in the German Bight. The hydrographic structure transformed onto a co-ordinate system fixed in time is much more similar to the structure obtained by satellite pictures and shows dynamical processes much clearer than in a co-ordinate system fixed in space.
Gezeitenkorrektur von hydrographischen Messungen
Zusammenfassung In dieser Arbeit wird ein Verfahren vorgestellt, das hydrographische Messungen vom Einfluß periodischer Variationen durch die Gezeiten bereinigt. Dies geschieht unter Benutzung von Ergebnissen eines numerischen Modells durch eine Transformation einer gemessenen hydrographischen Struktur von einem ortsfesten in ein zeitfestes System. Dieses Verfahren wird auf eine hydrographische Aufnahme der Deutschen Bucht angewandt. Die auf ein zeitfestes Koordinatensystem transformierte hydrographische Messung zeigt sehr viel Ähnlichkeit mit einer synoptischen Messung, die bei einem Satellitenüberflug gewonnen wurde. Bestimmte dynamische Prozesse in der Deutschen Bucht lassen sich zudem im zeitfesten Koordinatensystem besser erkennen als im ortsfesten Koordinatensystem.
Correction de l'influence de la marée sur les mesures hydrologiques
Résumé L'article présente une méthode simple pour éliminer l'influence de la marée sur les mesures hydrologiques. Cela est obtenu par le passage d'un système de coordonnées fixe dans l'espace à un système de coordonnées fixe dans le temps utilisant les résultats d'un modèle numérique de marée. La méthode est appliquée à un levé hydrologique dans la Baie Allemande. La structure hydrologique obtenue dans un système de coordonnées fixe dans le temps est beaucoup plus proche de celle qui est obtenue par les images satellites et décrit le processus dynamique beaucoup plus clairement que dans un système de coordonnées fixe dans l'espace.相似文献
95.
Thomas Neumann Uwe HeiserMarkus A Leosson Michael Kersten 《Geochimica et cosmochimica acta》2002,66(5):867-879
The formation of authigenic Ca-rich rhodochrosite (ACR) in sapropelic sediments of the Gotland Basin, Baltic Sea, is governed by deepwater renewal processes whereby saline water from the North Atlantic flushes the brackish anoxic Baltic Deeps. The carbon and oxygen isotopic compositions of these Mn-carbonates suggest that ACR formation takes place just below the sediment surface and that dissolved compounds from the deepwater column, such as water and bicarbonate molecules, were incorporated in ACR during authigenesis. Porewaters near the sediment surface display δ18O values of −5.4‰ (VSMOW) and are generally depleted in 18O, compared to the oxygen isotopic composition of water in equilibrium with Mn-carbonate solid solutions (ACR δ18O values are −4.6‰). This suggests that early burial diagenetic processes significantly modify the initial isotopic composition of water during Mn-carbonate formation. The reduction of sulfate having δ18O values of +8.4‰ accounts for a permanent enrichment of porewater 18O and observed δ18O values at depth equal to −4.6‰. However, this process does not explain the observed disequilibrium in the oxygen isotopic composition between water and ACR close to the sediment surface where Mn-carbonate formation takes place. Based on isotopic mass balance calculations, we suggest that MnO2 with δ18O values of +8.9‰ released oxygen enriched in 18O into the anoxic porewaters close below the sediment surface. This process should occur after oxygenation events during deepwater renewal when MnO2 accumulates at the surface of anoxic sediments. Manganese carbonates formed in these waters display δ18O values of ∼1.0‰ heavier than values expected solely from the initial deepwater composition. This quantitatively explains the discrepancy between paleosalinities calculated from ACR δ18O based on Mn-carbonate/water isotopic equilibrium fractionation and direct observations for the same period. Our results emphasize the important role of microbial MnO2 reduction during rhodochrosite authigenesis and suggest that Mn(II) activity, rather than alkalinity, is the limiting component for sedimentary Mn-carbonate formation. 相似文献
96.
Natalia Hauser Wolf Uwe Reimold Aaron J. Cavosie Alvaro P. Crsta Winfried H. Schwarz Mario Trieloff Carolinna Da Silva Maia de Souza Luciana A. Pereira Eduardo N. Rodrigues Matthews Brown 《Meteoritics & planetary science》2019,54(10):2286-2311
A silicious impact melt rock from polymict impact breccia of the northern part of the alkali granite core of the Araguainha impact structure, central Brazil, has been investigated. The melt rock is thought to represent a large mass of impact‐generated melt in suevite. In particular, a diverse population of zircon grains, with different impact‐induced microstructures, has been analyzed for U‐Pb isotopic systematics. Backscattered electron and cathodoluminescence images reveal heterogeneous intragrain domains with vesicular, granular, vesicular plus granular, and vesicular plus (presumably) baddeleyite textures, among others. The small likely baddeleyite inclusions are not only preferentially located along grain margins but also occur locally within grain interiors. LA‐ICP‐MS U‐Pb data from different domains yield lower intercept ages of 220, 240, and 260 Ma, a result difficult to reconcile with the previous “best age” estimate for the impact event at 254.7 ± 2.7 Ma. SIMS U‐Pb data, too, show a relatively large range of ages from 245 to 262 Ma. A subset of granular grains that yielded concordant SIMS ages were analyzed for crystallographic orientation by EBSD. Orientation mapping shows that this population consists of approximately micrometer‐sized neoblasts that preserve systematic orientation evidence for the former presence of the high‐pressure polymorph reidite. In one partially granular grain (#36), the neoblasts occur in linear arrays that likely represent former reidite lamellae. Such grains are referred to as FRIGN zircon. The best estimate for the age of the Araguainha impact event from our data set from a previously not analyzed type of impact melt rock is based on concordant SIMS data from FRIGN zircon grains. This age is 251.5 ± 2.9 Ma (2σ, MSWD = 0.45, p = 0.50, n = 4 analyses on three grains), indistinguishable from previous estimates based on zircon and monazite from other impact melt lithologies at Araguainha. Our work provides a new example of how FRIGN zircon can be combined with in situ U‐Pb geochronology to extract an accurate age for an impact event. 相似文献
97.
98.
99.
Collen JD Baker JA Dunbar RB Rieser U Gardner JP Garton DW Christiansen KJ 《Marine pollution bulletin》2011,62(2):251-257
Anthropogenic lead (Pb) inputs to the atmosphere increased greatly over the past century and now dominate Pb supply to the oceans. However, the Pb content of sediments across the equatorial Pacific region is relatively unknown, and data exist only for deep sea sites where Pb deposition lags surface water inputs by up to a century. Here we present ICP-MS analyses of Pb of a core from a lagoon at Palmyra Atoll, northern Line Islands, that spans approximately the past 160 years. The non-bioturbated sediments of the euxinic lagoon, coupled with rapid rates of deposition, provide a unique fine-scale record of atmospheric Pb supply at a remote Pacific location. These first observations of historic Pb sedimentation in an atoll lagoon reveal a 63-fold increase in Pb flux to sediments during the past century and correlate directly with the North American consumption of leaded gasoline that began in 1926. 相似文献
100.
Populations of the American horseshoe crab (Limulus polyphemus) differ in broad areas of their biology. We observed a non-harvested, marked Florida Gulf coast population during their spring
spawning (March–May) in 11 years across a 17-year period (1992–2009). Long-term changes occurred in the number of spawning
pairs: the population was stable from 1992 to 2000 but increased markedly after 2000. Short-term variation in numbers of spawning
pairs, unpaired females, unpaired males, and operational sex ratios was explained by changes over the season and during each
week of spring tides and by differences in actual (not predicted) maximum high tide height. Wind direction strongly affected
tidal inundation and the number of spawning horseshoe crabs. Tagging individuals revealed that females returned to the nesting
beach less often than males and most females were re-sighted only within 1 week of spring tides. No animals were seen across
more than 6 years. Implications for management are discussed. 相似文献