Intermetallic compounds,copper and palladium alloys in Au–Pd ore of the Skaergaard pluton,Greenland

Copper–palladium intermetallic compounds and alloys (2314 grains) from the Au–Pd ore of the Skaergaard layered gabbroic pluton have been studied. Skaergaardite PdCu, nielsenite PdCu₃, (Cu,Pd)_β, (Cu,Pd)_α, (Pd,Cu,Au,Pt) alloys, and native palladium have been identified as a result of 1680 microprobe analyses. The average compositions and various chemical varieties of these minerals are characterized, as well as vertical and lateral zoning in distribution of noble metals. The primary Pd–Cu alloys were formed within a wide temperature interval broadly synchronously with cooling and crystallization of host gabbro and in close association with separation of Fe–Cu sulfide liquid. In the course of crystallization of residual gabbroic melt enriched in iron, noble and heavy metals and saturated with the supercritical aqueous fluid, PGE and Au are selectively concentrated in the Fe–Cu sulfide phase as Pd–Cu and Cu–Au alloys.     

First results of micropulsation activity observed by sabre

Between September 1981 and March 1982 many Pc5 micropulsation events have been observed by the Wick component of the new SABRE auroral radar. A feature of these observations is that in addition to the characteristic poleward drifting regions of radar backscatter, equatorward moving regions are frequently observed. A consistent diurnal pattern in the direction of drift emerges from a statistical analysis of the data.     

Joint two-dimensional observations of ground magnetic and ionospheric electric fields associated with auroral zone currents: Current systems associated with local auroral break-ups

On 15 February, 1977, ground magnetic, ionospheric electric and auroral signatures of a multiple onset substorm were observed simultaneously by the Scandinavian Magnetometer Array (SMA), the Scandinavian Twin Auroral Radar Experiment (STARE) and the Finnish all-sky camera chain. Between 21:00 and 21:30 U.T., i.e. around local magnetic midnight, three consecutive local auroral break-ups were observed over Scandinavia. Each of these break-ups was preceded by a clear fading of the aurora and magnetic fields (while the electric fields remained unaffected), and occurred slightly south of the Harang discontinuity in the region of north-westward-directed electric fields. They were associated with a sudden change in direction of the electric field from north-west to south-west and the appearance of a westward equivalent current in the localized active region (about 1200 × 300 km²). These observations matched the features to be expected during the generation of a Cowling channel by a strong increase of the ionospheric conductivities due to precipitating auroral electrons. Numerical model calculations, based on the observations during the initial brightening and peak development of the second, most conspicuous break-up, show that the field-aligned currents at the northern and southern border of the active region are indeed very weak. However, highly localized and intense upward field-aligned currents at the western edge of the active region and more widespread and less intense downward currents in the eastern half preserve current continuity of the westward Cowling current and complete the substorm current wedge.     

Trace element distribution during the reproductive cycle of female and male spiny and Pacific scallops, with implications for biomonitoring

Trace element concentrations and contents in gills, gonad, kidneys, mantle, muscle and remainder during the reproductive cycle of female and male spiny and Pacific scallops, from the Strait of Georgia, BC, Canada, were quantified by using ICPMS. The elements investigated were chromium, manganese, iron, cobalt, nickel, selenium, molybdenum, cadmium, tin and mercury. For all ten elements, the tissue distribution was to some extent influenced by species, sex and reproductive status. The implications of the present study in relation to the design of biomonitoring programmes are: (1) care should be taken to ensure an equal/constant sex composition when making interannual comparisons of pooled samples. Preferably the sexes should be monitored separately. (2) the practice of obtaining pooled samples in the interspawn phase is applicable only to monitoring long-term trends in contaminant levels, while the reproductive status should be heeded when studying short-term changes. (3) the present study confirms that direct temporal or spatial comparisons of absolute accumulated element concentrations are only valid intraspecifically.     

Coherent integration time limit of a mobile receiver for indoor GNSS applications

There is an emerging requirement for processing global navigation satellite system (GNSS) signals indoor where the signal is very weak and subjected to spatial fading. Typically, longer coherent integration intervals provide the additional processing gain required for the detection and processing of such weak signals. However, the arbitrary physical motion of the handset imputed by the user limits the effectiveness of longer coherent integration intervals due to the spatial decorrelation of the multipath-faded GNSS signal. In this paper, limits of coherent integration due to spatial decorrelation are derived and corroborated with experimental verification. A general result is that the processing gain resulting from direct coherent integration saturates after the antenna has moved through a certain distance, which for typical indoor propagation, is about half a carrier wavelength. However, a refined Doppler search coupled with a prolonged coherent integration interval extends this limit, which is effectively a manifestation of selective diversity.     

Qualitative satellite image analysis: Mapping spatial distribution of farming types in Ethiopia

Satellite images have enormous potential for qualitative land use analysis. This paper presents empirical results that demonstrate how normally invisible dimensions produced by land use can be identified by enriching satellite data with qualitative information from field studies.Land use can be defined as the intentional use of a specific piece of land resulting in patterns of ecological responses that are visible in the land cover and landscape. Responses to land use often result in a heterogeneous combination of reflectance in satellite images. Statistical methods used in the classification of satellite imagery are limited in their capacity to handle categories consisting of heterogeneous combinations of spectral values. To overcome this limitation, a contextual post-classification method has been used to map land cover configurations as related to different agricultural practices in the district of Sodo, Ethiopia.The results show that it is possible to map socio-spatial distribution of different agricultural and socioeconomic practices on a regional level by combining field observations and spatial contextual information. The empirical findings show local agricultural activity variations in cash crop production and subsistence agriculture in the Sodo district of Ethiopia.     

Strategies to mitigate aliasing of loading signals while estimating GPS frame parameters

Although GNSS techniques are theoretically sensitive to the Earth center of mass, it is often preferable to remove intrinsic origin and scale information from the estimated station positions since they are known to be affected by systematic errors. This is usually done by estimating the parameters of a linearized similarity transformation which relates the quasi-instantaneous frames to a long-term frame such as the International Terrestrial Reference Frame (ITRF). It is well known that non-linear station motions can partially alias into these parameters. We discuss in this paper some procedures that may allow reducing these aliasing effects in the case of the GPS techniques. The options include the use of well-distributed sub-networks for the frame transformation estimation, the use of site loading corrections, a modification of the stochastic model by downweighting heights, or the joint estimation of the low degrees of the deformation field. We confirm that the standard approach consisting of estimating the transformation over the whole network is particularly harmful for the loading signals if the network is not well distributed. Downweighting the height component, using a uniform sub-network, or estimating the deformation field perform similarly in drastically reducing the amplitude of the aliasing effect. The application of these methods to reprocessed GPS terrestrial frames permits an assessment of the level of agreement between GPS and our loading model, which is found to be about 1.5 mm WRMS in height and 0.8 mm WRMS in the horizontal at the annual frequency. Aliased loading signals are not the main source of discrepancies between loading displacement models and GPS position time series.     

On the homeostasis and bistability on a Gaian planet

Geochemical disequilibrium of Earth's atmosphere is a sign of life. The fact that Earth's atmosphere is just right for life led Lovelock to propose the Gaia hypothesis: life itself regulates the environment on planetary scale in order to maintain habitability. This hypothesis is supported by the so-called Daisyworld parable, which illustrates a possible mechanism for such a self regulation. Here we revisit Daisyworld and challenge some of its conclusions from a closer examination of the model. We find that even within this simple, conceptual model of a Gaian planet there are regimes where climate is less homeostatic than on a dead planet. Furthermore, in other regimes, bistability between two climate states is found to exist due to the presence of life. This indicates that even if the Gaian stability might describe life in some planetary conditions, it need not be generic to all inhabited planets.     

Equilibrium H/H fractionations in organic molecules: I. Experimental calibration of ab initio calculations

Carbon-bound hydrogen in sedimentary organic matter can undergo exchange over geologic timescales, altering its isotopic composition. Studies investigating the natural abundance distribution of ¹H and ²H in such molecules must account for this exchange, which in turn requires quantitative knowledge regarding the endpoint of exchange, i.e., the equilibrium isotopic fractionation factor (α_eq). To date, relevant data have been lacking for molecules larger than methane. Here we describe an experimental method to measure α_eq for C-bound H positions adjacent to carbonyl group (H_α) in ketones. H at these positions equilibrates on a timescale of days as a result of keto-enol tautomerism, allowing equilibrium ²H/¹H distributions to be indirectly measured. Molecular vibrations for the same ketone molecules are then computed using Density Functional Theory at the B3LYP/6-311G** level and used to calculate α_eq values for H_α. Comparison of experimental and computational results for six different straight and branched ketones yields a temperature-dependent linear calibration curve with slope = 1.081−0.00376T and intercept = 8.404−0.387T, where T is temperature in degrees Celsius. Since the dominant systematic error in the calculation (omission of anharmonicity) is of the same size for ketones and C-bound H in most other linear compounds, we propose that this calibration can be applied to analogous calculations for a wide variety of organic molecules with linear carbon skeletons for temperatures below 100 °C. In a companion paper (Wang et al., 2009) we use this new calibration dataset to calculate the temperature-dependent equilibrium isotopic fractionation factors for a range of linear hydrocarbons, alcohols, ethers, ketones, esters and acids.