Boron abundances and isotopic ratios of olivine grains on Itokawa returned by the Hayabusa spacecraft

We report the B abundances and isotopic ratios of two olivine grains from the S‐type asteroid Itokawa sampled by the Hayabusa spacecraft. Olivine grains from the Dar al Gani (DaG) 989 LL6 chondrite were used as a reference. Since we analyzed polished thin sections in both cases, we expect the contribution from the solar wind B (rich in ¹⁰B) to be minimal because the solar wind was implanted only within very thin layers of the grain surface. The Itokawa and DaG 989 olivine grains have homogeneous B abundances (~400 ppb) and ¹¹B/¹⁰B ratios compatible with the terrestrial standard and bulk chondrites. The observed homogeneous B abundances and isotopic ratios of the Itokawa olivine grains are likely the result of thermal metamorphism which occurred in the parent asteroid of Itokawa, which had a similar composition as LL chondrites. The chondritic B isotopic ratios of the Itokawa samples suggest that they contain little cosmogenic B (from cosmic‐ray spallation reactions) rich in ¹⁰B. This observation is consistent with the short cosmic‐ray exposure ages of Itokawa samples inferred from the small concentrations of cosmogenic ²¹Ne. If other Itokawa samples have little cosmogenic B as well, the enrichment in ¹⁰B found previously on the surface of another Itokawa particle (as opposed to the bulk grain study here) may be attributed to implanted solar wind B.     

Comparative dissolution kinetics of biogenic and chemogenic uraninite under oxidizing conditions in the presence of carbonate

The long-term stability of biogenic uraninite with respect to oxidative dissolution is pivotal to the success of in situ bioreduction strategies for the subsurface remediation of uranium legacies. Batch and flow-through dissolution experiments were conducted along with spectroscopic analyses to compare biogenic uraninite nanoparticles obtained from Shewanella oneidensis MR-1 and chemogenic UO_2.00 with respect to their equilibrium solubility, dissolution mechanisms, and dissolution kinetics in water of varied oxygen and carbonate concentrations. Both materials exhibited a similar intrinsic solubility of ∼10⁻⁸ M under reducing conditions. The two materials had comparable dissolution rates under anoxic as well as oxidizing conditions, consistent with structural bulk homology of biogenic and stoichiometric uraninite. Carbonate reversibly promoted uraninite dissolution under both moderately oxidizing and reducing conditions, and the biogenic material yielded higher surface area-normalized dissolution rates than the chemogenic. This difference is in accordance with the higher proportion of U(V) detected on the biogenic uraninite surface by means of X-ray photoelectron spectroscopy. Reasonable sources of a stable U(V)-bearing intermediate phase are discussed. The observed increase of the dissolution rates can be explained by carbonate complexation of U(V) facilitating the detachment of U(V) from the uraninite surface. The fraction of surface-associated U(VI) increased with dissolved oxygen concentration. Simultaneously, X-ray absorption spectra showed conversion of the bulk from UO_2.0 to UO_2+x. In equilibrium with air, combined spectroscopic results support the formation of a near-surface layer of approximate composition UO_2.25 (U₄O₉) coated by an outer layer of U(VI). This result is in accordance with flow-through dissolution experiments that indicate control of the dissolution rate of surface-oxidized uraninite by the solubility of metaschoepite under the tested conditions. Although U(V) has been observed in electrochemical studies on the dissolution of spent nuclear fuel, this is the first investigation that demonstrates the formation of a stable U(V) intermediate phase on the surface of submicron-sized uraninite particles suspended in aqueous solutions.     

Impacts of tectonic and orbital forcing on East African climate: a comparison based on global climate model simulations

A global atmosphere–ocean model has been forced with topographic and orbital scenarios in order to evaluate the relative role of both factors for the past climate of East Africa. Forcing the model with a significantly reduced topography in Eastern and Southern Africa leads to a distinct increase in moisture transport from the Indian Ocean into the eastern part of the continent and increased precipitation in Eastern Africa. Simulations with step-wise reduced height show that this climate change occurs continuously with the change in topography, i.e., an abrupt change of local climatic features with a critical height is not found. Simulations of the last interglacial (at 125,000 years before present, i.e., the Eemian interglacial) and the last glacial inception (at 115,000 years before present) are used as examples for the role of orbital-induced changes in insolation. Here, changes in meridional temperature gradients lead to modifications in moisture transport of similar order of magnitude, but with different spatial and seasonal structure. For the Eemian interglacial, a distinct increase in summer moisture transport from the Atlantic deep into the continent at around 20°N is simulated.     

Tying platform drowning to perturbations of the global carbon cycle with a δ13COrg-curve from the Valanginian of DSDP Site 416

The carbonate carbon isotope record of the Phanerozoic is marked by repeated high-amplitude excursions towards more positive values. Although the interpretation of C-isotope events remains controversial, they are regarded as a proxy of the global C-cycle. Using δ¹³C_Org-measurements of samples from DSDP Site 416, it is shown that a classic example of platform drowning coincided with the onset of the mid-Valanginian carbon-cycle excursion. Widespread carbonate platform drowning would have contributed to the observed positive shift in the C-isotope record. As choking of carbonate production was compensated by increased organic production, both processes favoured a shift in marine carbon partitioning from the oxidized to the reduced carbon reservoir. This would have resulted in an increased flux of CO₂ from the atmosphere into the marine and sedimentary carbon reservoir.     

A system for line profile studies at the 150-foot tower on Mount Wilson

We describe enhancements to the hardware and software for the 150-foot tower system on Mt. Wilson which make possible the acquisition of high precision line profile measurements. This system utilizes the 75-foot pit spectrograph with a photomultiplier detector system to scan line profiles repeatedly in order to study variations induced by the passage of waves vertically through the solar atmosphere. Oscillations of line profile parameters with an amplitude as low as 1.7 m s^–1 have been detected with this system using integrated sunlight. Phase relations between oscillations of different parts of the line profile are appropriate to upward energy transport. Consistent with the previous conclusion by Mein and Schmieder (1981), we find that the magnitude of the energy transport is compatible with the 5-min oscillations making an important contribution to the heating of the low chromosphere.The Mount Wilson Observatory is operated by the Mount Wilson Institute under agreement with the Carnegie Institution of Washington.     

A Multi-Observatory Inter-Comparison of Line-of-Sight Synoptic Solar Magnetograms

The observed photospheric magnetic field is a crucial parameter for understanding a range of fundamental solar and heliospheric phenomena. Synoptic maps, in particular, which are derived from the observed line-of-sight photospheric magnetic field and built up over a period of 27 days, are the main driver for global numerical models of the solar corona and inner heliosphere. Yet, in spite of 60 years of measurements, quantitative estimates remain elusive. In this study, we compare maps from seven solar observatories (Stanford/WSO, NSO/KPVT, NSO/SOLIS, NSO/GONG, SOHO/MDI, UCLA/MWO, and SDO /HMI) to identify consistencies and differences among them. We find that while there is a general qualitative consensus, there are also some significant differences. We compute conversion factors that relate measurements made by one observatory to another using both synoptic map pixel-by-pixel and histogram-equating techniques, and we also estimate the correlation between datasets. For example, Wilcox Solar Observatory (WSO) synoptic maps must be multiplied by a factor of 3?–?4 to match Mount Wilson Observatory (MWO) estimates. Additionally, we find no evidence that the MWO saturation correction factor should be applied to WSO data, as has been done in previous studies. Finally, we explore the relationship between these datasets over more than a solar cycle, demonstrating that, with a few notable exceptions, the conversion factors remain relatively constant. While our study was able to quantitatively describe the relationship between the datasets, it did not uncover any obvious “ground truth.” We offer several suggestions for how this may be addressed in the future.     

A Century of Solar Ca <Emphasis Type="SmallCaps">ii</Emphasis> Measurements and Their Implication for Solar UV Driving of Climate

Spectroheliograms and disk-integrated flux monitoring in the strong resonance line of Ca ii (K line) provide the longest record of chromospheric magnetic plages. We compare recent reductions of the Ca ii K spectroheliograms obtained since 1907 at the Kodaikanal, Mt. Wilson, and US National Solar Observatories. Certain differences between the individual plage indices appear to be caused mainly by differences in the spectral passbands used. Our main finding is that the indices show remarkably consistent behavior on the multidecadal time scales of greatest interest to global warming studies. The reconstruction of solar ultraviolet flux variation from these indices differs significantly from the 20th-century global temperature record. This difference is consistent with other findings that, although solar UV irradiance variation may affect climate through influence on precipitation and storm tracks, its significance in global temperature remains elusive.