Konzepte zur Mobilitätsabschätzung von Schadstoffen in Boden- und Abfallmaterialien

Concepts for the Evaluation of Contaminant Mobility in Soil and Waste Materials Elution tests (S4, pH_stat, and SDS test) are presented, enabling the evaluation of the mobility of hydrophilic/hydrophobic and inorganic/organic contaminants in soil and waste materials. While elution tests for estimation of the mobilization potential of hydrophilic substances are performed following the pH_stat method, for hydrophobic species surfactant-containing eluents are used. The individual parameters of the elution process are selected assuming a "worst-case" scenario. In principle, because of economic reasons, detailed analytical investigations should be preceded by relevant screening tests.     

From stable dipolar towards reversing numerical dynamos

We are using a three-dimensional convection-driven numerical dynamo model without hyperdiffusivity to study the characteristic structure and time variability of the magnetic field in dependence of the Rayleigh number (Ra) for values up to 40 times supercritical. We also compare a variety of ways to drive the convection and basically find two dynamo regimes. At low Ra, the magnetic field at the surface of the model is dominated by the non-reversing axial dipole component. At high Ra, the dipole part becomes small in comparison to higher multipole components. At transitional values of Ra, the dynamo vacillates between the dipole-dominated and the multipolar regime, which includes excursions and reversals of the dipole axis. We discuss, in particular, one model of chemically driven convection, where for a suitable value of Ra, the mean dipole moment and the temporal evolution of the magnetic field resemble the known properties of the Earth’s field from paleomagnetic data.     

Die neue EG‐Wasserrahmenrichtlinie: Bewertung der chemischen und ökologischen Qualität von Oberflächengewässern

The New EC Framework Water Directive: Assessment of the Chemical and Ecological Status of Surface Waters The main objective of the draft EC Framework Water Directive is the good quality of all surface waters. The directive provides for an assessment of the chemical status of surface waters (EU‐wide valid environmental quality standards for approximately 30 priority substances) and a five‐stage ecological classification of waters, comprising the stages high, good, moderate, poor, and bad. The starting point for the assessment are the reference conditions, which are defined as corresponding to high water quality and characterising a water status with no significant anthropogenic impact. The reference sites in the various water body types are to be selected using hydromorphological and physico‐chemical parameters and subsequently characterised by means of biological parameters. For surface waters, three groups of characteristics are provided for, namely: 1. with priority the biology – in the case of surface waters – with the four elements phytoplankton, macrophytes/phytobenthos, benthic invertebrate fauna, and fish fauna; 2. supporting the hydromorphology, e.g. flowing waters with the three elements hydrological regime, river continuity, and morphological conditions and 3. supporting the physico‐chemical conditions with the three elements general conditions, specific synthetic pollutants, and specific non synthetic pollutants (other than the priority substances of the chemical status).     

Kurzzeit-Toxizitätstests zur Messung der Toxizität von Chemikalien gegenüber Belebtschlamm

Short-term Toxicity Tests for the Measurement of Toxicity of Chemicals Towards Activated Sludge. To avoid severe damage to the activated sludge of a wastewater treatment plant it is necessary to control the sludge activity by means of biological test systems. Especially the short-term respiration assay and the dehydrogenase assay with resazurin as a redox-dye seem to be appropriate for this monitoring program. The practical performance of both test systems was optimized in some essential points. With the help of several reference substances both monitoring systems were tested for practical use as short-term toxicity tests. The results of the investigations showed that the inhibitory concentrations measured in both test systems were partially very different. In monitoring experiments with laboratory-scale wastewater treatment plants it could be shown that a positive correlation between respiration activity and dehydrogenase activity is not always given. Furthermore, a pH-dependent toxicity could be demonstrated for several substituted phenols.     

The Holocene–Anthropocene transition in lakes of western Spitsbergen,Svalbard (Norwegian High Arctic): climate change and nitrogen deposition

Lake sediments from four small lakes on western Spitsbergen (Svalbard Archipelago, Norwegian High Arctic) preserve biostratigraphic and isotopic evidence for a complex suite of twentieth century environmental changes. At Lake Skardtjørna and Lake Tjørnskardet on Nordenskiöldkysten, there is a marked diatom floristic change coupled to increased diatom concentrations beginning around 1920. At Lake Istjørna and Lake Istjørnelva, 25 km southwest of Longyearbyen, both diatom total valve and chrysophyte stomatocyst concentrations have increased dramatically since the beginning of the 1900s. The early twentieth century changes are probably related to climate warming after the Little Ice Age. However, the most pronounced changes in diatom assemblages seem to have occurred in the last few decades. At the same time, nitrogen stable isotopes in sediment organic matter in two of the lakes became progressively depleted by ~2‰, which is consistent with diffuse atmospheric inputs from anthropogenic sources and attendant fertilization. These data suggest that climate change and nitrogen deposition may be acting together in driving these lakes towards new ecological states that are unique in the context of the Holocene.     

The seasonal cycle in coupled ocean-atmosphere general circulation models

We examine the seasonal cycle of near-surface air temperature simulated by 17 coupled ocean-atmosphere general circulation models participating in the Coupled Model Intercomparison Project (CMIP). Nine of the models use ad hoc “flux adjustment” at the ocean surface to bring model simulations close to observations of the present-day climate. We group flux-adjusted and non-flux-adjusted models separately and examine the behavior of each class. When averaged over all of the flux-adjusted model simulations, near-surface air temperature falls within 2?K of observed values over the oceans. The corresponding average over non-flux-adjusted models shows errors up to ～6?K in extensive ocean areas. Flux adjustments are not directly applied over land, and near-surface land temperature errors are substantial in the average over flux-adjusted models, which systematically underestimates (by ～5?K) temperature in areas of elevated terrain. The corresponding average over non-flux-adjusted models forms a similar error pattern (with somewhat increased amplitude) over land. We use the temperature difference between July and January to measure seasonal cycle amplitude. Zonal means of this quantity from the individual flux-adjusted models form a fairly tight cluster (all within ～30% of the mean) centered on the observed values. The non-flux-adjusted models perform nearly as well at most latitudes. In Southern Ocean mid-latitudes, however, the non-flux-adjusted models overestimate the magnitude of January-minus-July temperature differences by ～5?K due to an overestimate of summer (January) near-surface temperature. This error is common to five of the eight non-flux-adjusted models. Also, over Northern Hemisphere mid-latitude land areas, zonal mean differences between July and January temperatures simulated by the non-flux-adjusted models show a greater spread (positive and negative) about observed values than results from the flux-adjusted models. Elsewhere, differences between the two classes of models are less obvious. At no latitude is the zonal mean difference between averages over the two classes of models greater than the standard deviation over models. The ability of coupled GCMs to simulate a reasonable seasonal cycle is a necessary condition for confidence in their prediction of long-term climatic changes (such as global warming), but it is not a sufficient condition unless the seasonal cycle and long-term changes involve similar climatic processes. To test this possible connection, we compare seasonal cycle amplitude with equilibrium warming under doubled atmospheric carbon dioxide for the models in our data base. A small but positive correlation exists between these two quantities. This result is predicted by a simple conceptual model of the climate system, and it is consistent with other modeling experience, which indicates that the seasonal cycle depends only weakly on climate sensitivity.     

Monthly prediction of rainfall over India and its homogeneous zones during monsoon season: a supervised principal component regression approach on general circulation model products

A supervised principal component regression (SPCR) technique has been employed on general circulation model (GCM) products for developing a monthly scale deterministic forecast of summer monsoon rainfall (June–July–August–September) for different homogeneous zones and India as a whole. The time series of the monthly observed rainfall as the predictand variable has been used from India Meteorological Department gridded (1°?×?1°) rainfall data. Lead 0 (forecast initialized in the same month) monthly products from GCMs are used as predictors. The sources of these GCMs are International Research Institute for Climate and Society, Columbia University, National Center for Environmental Prediction, and Japan Agency for Marine Earth Science and Technology. The performance of SPCR technique is judged against simple ensemble mean of GCMs (EM) and it is found that over almost all the zones the SPCR model gives better skill than EM in June, August, and September months of monsoon. The SPCR technique is able to capture the year to year observed rainfall variability in terms of sign as well as the magnitude. The independent forecasts of 2007 and 2008 are also analyzed for different monsoon months (Jun–Sep) in homogeneous zones and country. Here, 1982–2006 have been considered as development year or training period. Results of the study suggest that the SPCR model is able to catch the observational rainfall over India as a whole in June, August, and September in 2007 and June, July, and August in 2008.     

The mass accommodation coefficient of ammonia on water

The mass accommodation coefficient of ammonia gas on water has been determined by measuring the absorption rate of 50–200 ppm NH₃ in one atm of air or helium into a liquid jet of 97 µm diameter as function of the exposed jet length, and comparing the results with numerical simulations which treat as the only free parameter. The model considers in detail transport of NH₃ by molecular diffusion, penetration of the gas/water interface, hydrolysis in the acidified water, and transport of the solutes from the surface into the jet. A correction is applied for the time evolution of the jet surface speed, using literature data on the fluid mechanics of liquid jets. The result of nine sets of independent measurements is

European winter precipitation extremes and large-scale circulation: a coupled model and its scenarios

Summary The physical coupling between the occurrence of winter heavy precipitation in Europe and the surface large-scale circulation is studied by isolating their coupled modes with a singular value decomposition technique. The leading mode is a clear manifestation of the North Atlantic Oscillation forcing. The second mode reflects the influence of a centre-of-action in the pressure field westward of the British Isles. The Hadley Centre Coupled Model (3^rd generation) is skilful in reproducing these two modes and an eastward extension of the North Atlantic Oscillation towards the Mediterranean Basin is projected under two future climatic scenarios. This extension yields an increase in the North Atlantic Oscillation forcing over the occurrence of heavy precipitation in several regions of Southern Europe, which is corroborated by the changes in the coupling of the daily precipitation. A combination of the first six coupled modes of the daily precipitation revealed that its amounts in some parts of Western Europe and the Mediterranean are effectively governed by the large-scale circulation. The model is still reasonably skilful in reproducing this large-scale coupling. The projected modifications, both in the strength and in the patterns of the coupled modes, explain important fractions of the projected changes in variance, which ultimately have implications in the occurrence of heavy precipitation in several European areas. Therefore, the ability of a model in reproducing the large-scale forcing over the daily precipitation is important for the reliability of its projections of the occurrence of heavy precipitation in Europe.