Identification of waste management development drivers and potential emerging waste treatment technologies

Application and development of municipal solid waste treatment technology depends on various socio-economic and environmental factors. All those factors are work as development drivers for waste management systems. The study aims to identify key drivers from case studies of waste management development trend in Sweden. Social, economic and environmental drivers are identified and presented in this study. The study identifies personal behaviour, local waste management practice, consumption and generation of waste as the key social drivers. Resource value of waste, economic benefit from waste treatment facilities and landfill tax have been acknowledged as economic drivers for developing waste treatment technology. Moreover, global climate change, environmental movement and awareness have been working as environmental drivers for developing various waste treatment methods in Sweden. In addition, the study aims to analyse emerging waste treatment technologies based on a number of literature review and questionnaire survey. Dry composting, pyrolysis-gasification, plasma arc, and anaerobic digestion have been identified as potential emerging technologies for waste management systems in Sweden.     

The Berchtesgaden National Park (Bavaria, Germany): a platform for interdisciplinary catchment research

The Berchtesgaden National Park (Bavaria, Germany), a study site of the UNESCO Man and the Biosphere program in the catchment of Berchtesgadener Ache, is introduced as a platform for interdisciplinary research. As the investigation of how human activities affect the natural resources in the park area, which has been defined a main aim of the program, naturally requires expertise from different scientific fields, interdisciplinary research has been fostered in the national park plan since the very beginning of the Man and the Biosphere program in 1981. To analyze the complex interactions and mutual dependencies between socio-economic and natural systems, a variety of monitoring programs have been initialized in different disciplines (e.g. climate sciences, zoology, botany) that are addressed in this paper. As a result of these research efforts, the park offers a profound data basis to be used in future studies (e.g. land cover classifications, maps of geological and soil conditions). Detailed information is provided on a climate monitoring network that has been installed in the park starting in the year 1993. The network has been continuously extended over the years and now provides extraordinary comprehensive information on meteorological conditions in the park, setting the basis for current as well as for potential future climate-related studies. A special characteristic of the station network is the fact that it covers a large range of elevations from 600 m a.s.l in the valleys to 2,600 m a.s.l in the summit regions and is therefore able to capture altitudinal gradients in meteorological variables as typical for Alpine regions. Due to the large number of stations in high elevations (15 stations are in elevations higher than 1,500 m a.s.l) the network provides information on the complex hydrometeorological conditions in summit regions which are often insufficiently represented in observation networks due to the increased costs for maintenance of climate stations in these locations. Beside the various monitoring programs, a variety of numerical models have been (further) developed for application in the park area that make extensive use of the different data collected and therefore largely benefit from the comprehensive data pool. The potential and necessity of the climate monitoring network for modelling studies is demonstrated by utilizing the meteorological recordings in the framework of a hydrometeorological simulation experiment. Further examples of environmental modelling efforts are shortly described together with preliminary model results.     

Impact of horizontal resolution on prediction of tropical cyclones over Bay of Bengal using a regional weather prediction model

The present study is carried out to examine the performance of a regional atmospheric model in forecasting tropical cyclones over the Bay of Bengal and its sensitivity to horizontal resolution. Two cyclones, which formed over the Bay of Bengal during the years 1995 and 1997, are simulated using a regional weather prediction model with two horizontal resolutions of 165 km and 55 km. The model is found to perform reasonably well towards simulation of the storms. The structure, intensity and track of the cyclones are found to be better simulated by finer resolution of the model as compared to the coarse resolution. Rainfall amount and its distribution are also found to be sensitive to the model horizontal resolution. Other important fields, viz., vertical velocity, horizontal divergence and horizontal moisture flux are also found to be sensitive to model horizontal resolution and are better simulated by the model with finer horizontal grids.     

Lu–Hf and U–Pb isotope systematics of zircons from the Storgangen intrusion, Rogaland Intrusive Complex, SW Norway: implications for the composition and evolution of Precambrian lower crust in the Baltic Shield

The Storgangen orebody is a concordantly layered, sill-like body of ilmenite-rich norite, intruding anorthosites of the Rogaland Intrusive Complex (RIC), SW Norway. 17 zircon grains were separated from ca. 5 kg of sand-size flotation waste collected from the on-site repository from ilmenite mining. These zircons were analysed for major and trace elements by electron microprobe, and for U–Pb and Lu–Hf isotopes by laser ablation microprobe plasma source mass spectrometry. Eight of the zircons define a well-constrained (MSWD=0.37) concordant population with an age of 949±7 Ma, which is significantly older than the 920–930 Ma ages previously reported for zircon inclusions in orthopyroxene megacrysts from the RIC. The remaining zircons, interpreted as inherited grains, show a range of ²⁰⁷Pb/²⁰⁶Pb ages up to 1407±14 Ma, with an upper intercept age at ca. 1520 Ma. The concordant zircons have similar trace element patterns, and a mean initial Hf isotope composition of ¹⁷⁶Hf/¹⁷⁷Hf_{949 Ma}=0.28223±5 (_Hf=+2±2). This is similar to the Hf-isotope composition of zircons in a range of post-tectonic Sveconorwegian granites from South Norway, and slightly more radiogenic than expected for mid-Proterozoic juvenile crust. The older, inherited zircons show Lu–Hf crustal residence ages in the range 1.85–2.04 Ga. One (undated) zircon plots well within the field of Hf isotope evolution of Paleoproterozoic rocks of the Baltic Shield. These findings indicate the presence of Paleoproterozoic components in the deep crust of the Rogaland area, but do not demonstrate that such rocks, or a Sveconorwegian mantle-derived component, contributed significantly to the petrogenesis of the RIC. If the parent magma was derived from a homogeneous, lower crustal mafic granulite source, the lower crustal protolith must be at least 1.5 Ga old, and it must have an elevated Rb/Sr ratio. This component would be indistinguishable in Sr, Nd and Hf isotopes from some intermediate mixtures between Sveconorwegian mantle and Paleoprotoerzoic felsic crust, but it cannot account for the initial ¹⁴³Nd/¹⁴⁴Nd of the most primitive, late Sveconorwegian granite in the region, without the addition of mantle-derived material.     

Structural changes and valence states in the MgCr<Subscript>2</Subscript>O<Subscript>4</Subscript>–FeCr<Subscript>2</Subscript>O<Subscript>4</Subscript> solid solution series

The influence on the structure of Fe²⁺ Mg substitution was studied in synthetic single crystals belonging to the MgCr₂O₄–FeCr₂O₄ series produced by flux growth at 900–1200 °C in controlled atmosphere. Samples were analyzed by single-crystal X-ray diffraction, electron microprobe analyses, optical absorption-, infrared- and Mössbauer spectroscopy. The Mössbauer data show that iron occurs almost exclusively as ^IVFe²⁺. Only minor Fe³⁺ (<0.005 apfu) was observed in samples with very low total Fe. Optical absorption spectra show that chromium with few exceptions is present as a trivalent cation at the octahedral site. Additional absorption bands attributable to Cr²⁺ and Cr³⁺ at the tetrahedral site are evident in spectra of end-member magnesiochromite and solid-solution crystals with low ferrous contents. Structural parameters a₀, u and T–O increase with chromite content, while the M–O bond distance remains nearly constant, with an average value equal to 1.995(1) Å corresponding to the Cr³⁺ octahedral bond distance. The ideal trend between cell parameter, T–O bond length and Fe²⁺ content (apfu) is described by the following linear relations: a₀=8.3325(5) + 0.0443(8)Fe²⁺ (Å) and T–O=1.9645(6) + 0.033(1)Fe²⁺ (Å) Consequently, Fe²⁺ and Mg tetrahedral bond lengths are equal to 1.998(1) Å and 1.965(1) Å, respectively.     

A field evaluation of enhanced reductive dechlorination of chlorinated solvents in groundwater,New York Metropolitan Area

An initial assessment of an old manufacturing site with groundwater impacted by trichloroethene (TCE) contamination in the metropolitan New York area showed that the TCE was being removed naturally by reductive dechlorination. However, complete dechlorination was not expected at the site because the process was progressing too slowly under transitional to aerobic conditions at a degradation constant of –0.0013 and a TCE half life of 533 days. A pilot test was conducted at the site in which a carbohydrate substrate (molasses) was injected into the groundwater to create an In-Situ Reactive Zone (IRZ). Post-pilot test groundwater sampling and analysis indicated that an IRZ was created successfully as the total organic carbon (TOC) content and conductivity increased significantly while oxidation-reduction (REDOX) potential and dissolved oxygen (DO) decreased. The created IRZ caused enhanced reductive dechlorination of TCE at the site, found to proceed with a degradation constant of –0.0158 and a TCE half life of 44 days.     

The Influence of Geodynamic Factors on the Postsedimentary Lithogenesis of Jurassic Terrigenous Complexes of the Caucasus (Southern Dagestan)

The influence of geodynamic factors on the postsedimentary lithogenesis of terrigenous sequences during the replacement of the passive continental-margin regime to the active regime is considered with the Toarcian–Aalenian complexes of southern Dagestan as an example. It has been established that clayey rocks were lithified under conditions of subsidence lithogenesis, whereas the orogenic catagenesis of sandy rocks was related to stress initiated by the initial (amagmatic) subduction phase. The Kübler index has been used to reveal the postsedimentary zonality that is consistent with the intensity of folding and cleavage. The metagenesis zone fits the cleavage zone. The Rb–Sr and K–Ar datings of clayey rocks from the metagenesis zone yielded 180–190 Ma that can be interpreted as the timing of the maximal manifestation of postsedimentary lithogenesis.     

Neutron stars in the multidimensional einstein theory of gravitation

The radius, mass, total number of baryons, and other parameters of static, spherically symmetric, superdense stars are calculated. A model with one Ricci-flat inner space of arbitrary dimensionality and the approximation p₁=?0.5ε + ap for additional components of the energy — momentum tensor are used (ε and ρ are the total energy density and the pressure of the stellar matter and a is a fitting parameter). In the case of white dwarfs, the results of the multidimensional theory do not depend on the dimensionality D of space-time for ?10 ? a ? 10 and coincide with the analogous data of the general theory of relativity (GTR). For neutron stars there is a dependence on D and a. For D>4, in particular, the greatest mass M_max of a neutron star as a function of a has a maximum at 3<a(D) ? 4, which exceeds the greatest mass M _max ⁰ =2.14 M_⊙ in the GTR. A comparison of theoretical results with observational data determines the allowable values of a. Data for PSR 1913 + 16 lead to 0.2 ≤ a ≤ 9.2 in the case of D=26, while the results of [P. C. Joss and S. A. Rappaport, Annu. Rev. Astron. Astrophys.,22, 537 (1984)] lead to the stricter limits 1 ≤ a ≤ 7.4.