Application of Column Chromatography for Accurate Determination of the Carbon Isotopic Compositions of n-alkanes in Diverse Environmental Samples

Ocean Science Journal - The carbon isotopic compositions (δ13C) of n-alkanes in various environmental samples have been previously proposed as suitable fingerprints for assessing the origin of...     

Reduction of future disaster damages by learning from disaster experiences

This paper examines the effect of a country’s own past disaster experiences and nearby countries’ past experiences on subsequent disaster damage. We use global disaster data from 1990 to 2010, which include disaster-related death tolls for both natural and technological disasters that are further divided into sub-categories. Overall, we find evidence of a reduction effect of past disaster damage on future disaster damage. More detailed analyses show that an adaptation effect seems to be present for certain combinations of disaster types and levels of economic development. The results show that a country’s own experiences reduce future damage for natural disasters but that the marginal effect is larger for lower-income countries. On the other hand, for technological disasters, a robust impact of experiences was found only in higher-income countries. In terms of the disaster experiences of nearby countries, the adaptation effect was found only for natural disasters, and the marginal impact was relatively higher for higher-income countries.     

Comparison of waveform inversion, part 1: conventional wavefield vs logarithmic wavefield

This is the first in a series of three papers focused on using variants of a logarithmic objective function approach to full waveform inversion. In this article, we investigate waveform inversion using full logarithmic principles and compare the results with the conventional least squares approach. We demonstrate theoretically that logarithmic inversion is computational similar to the conventional method in the sense that it uses exactly the same back‐propagation technology as used in least‐squares inversion. In the sense that it produces better results for each of three numerical examples, we conclude that logarithmic inversion is also more robust. We argue that a major reason for the inherent robustness is the fact that the logarithmic approach produces a natural scaling of the amplitude of the residual wavefield by the amplitude of the modelled wavefield that tends to stabilize the computations and consequently improve the final result. We claim that any superiority of the logarithmic inversion is based on the fact that it tends to be tomographic in the early stage of the inversion and more dependent on amplitude differences in the latter stages.     

Organohalogen compounds in deep-sea fishes from the western North Pacific, off-Tohoku, Japan: Contamination status and bioaccumulation profiles

Twelve species of deep-sea fishes collected in 2005 from the western North Pacific, off-Tohoku, Japan were analyzed for organohalogen compounds. Among the compounds analyzed, concentrations of DDTs and PCBs (up to 23,000 and 12,400 ng/g lipid wt, respectively) were the highest. The present study is the foremost to report the occurrence of brominated flame retardants such as PBDEs and HBCDs in deep-sea organisms from the North Pacific region. Significant positive correlations found between δ¹⁵N (‰) and PCBs, DDTs and PBDEs suggest the high biomagnification potential of these contaminants in food web. The large variation in δ¹³C (‰) values observed between the species indicate multiple sources of carbon in the food web and specific accumulation of hydrophobic organohalogen compounds in benthic dwelling carnivore species like snubnosed eel. The results obtained in this study highlight the usefulness of deep-sea fishes as sentinel species to monitor the deep-sea environment.     

Fatty acid profiles of benthic environment associated with artificial reefs in subtropical Hong Kong

Artificial reefs can enhance habitat heterogeneity, especially in seabed degraded by bottom-dredging and trawling. However, the trophodynamics of such reef systems are not well understood. This study provided baseline data on trophic relationships in the benthic environment associated with artificial reefs in late spring and mid summer of subtropical Hong Kong, using fatty acid profiles as an indicator. Data from sediments collected at the reef base, materials from sediment traps deployed on top and bottom of the reefs, total particulate matter from the water column and oyster tissues from reef surface were subjected to principal component analysis. Results showed variations of fatty acid profiles in the total particulate matter, upper sediment trap and oyster tissue samples collected in the two samplings, indicating seasonal, trophodynamic changes within the reef system. The wastes produced by fish aggregating at the reefs can also contribute a source of biodeposits to the nearby benthic environment.     

Distribution and bioaccumulation of polychlorinated biphenyls and organochlorine pesticides residues in sediments and Manila clams (Ruditapes philippinarum) from along the Mid-Western coast of Korea

The distribution and bioaccumulation features of PCBs, DDTs, and HCHs were investigated in the sediments and Manila clams collected from along the Mid-Western coast of Korea. The measured concentrations of ΣPCBs, ΣDDTs and ΣHCHs were 1.08–3.5, 0.12–0.35 and 0.090–0.30 ng g⁻¹ dw in sediment, and 33–390, 7.4–46 and 6.3–27 ng g⁻¹ lipid in Manila clam, respectively. Their levels were found to be relatively lower than those of other contaminated areas and the consumption of Manila clam from these areas seems to be safe for human health according to calculated lifetime cancer risk and hazard indices. The ΣPCBs and ΣDDTs concentrations in sediments showed a significant relationship to those in clams. The significant correlation was observed between BSAF in clams and K_ow for each PCB congeners and DDT metabolites. These findings support that the PCBs and DDTs levels, which are highly hydrophobic chemicals, in clam reflect the sediment pollution through bioaccumulation.     

Improved amplitude preservation for prestack depth migration by inverse scattering theory

A prestack reverse time-migration image is not properly scaled with increasing depth. The main reason for the image being unscaled is the geometric spreading of the wavefield arising during the back-propagation of the measured data and the generation of the forward-modelled wavefields. This unscaled image can be enhanced by multiplying the inverse of the approximate Hessian appearing in the Gauss–Newton optimization technique. However, since the approximate Hessian is usually too expensive to compute for the general geological model, it can be used only for the simple background velocity model.We show that the pseudo-Hessian matrix can be used as a substitute for the approximate Hessian to enhance the faint images appearing at a later time in the 2D prestack reverse time-migration sections. We can construct the pseudo-Hessian matrix using the forward-modelled wavefields (which are used as virtual sources in the reverse time migration), by exploiting the uncorrelated structure of the forward-modelled wavefields and the impulse response function for the estimated diagonal of the approximate Hessian. Although it is also impossible to calculate directly the inverse of the pseudo-Hessian, when using the reciprocal of the pseudo-Hessian we can easily obtain the inverse of the pseudo-Hessian. As examples supporting our assertion, we present the results obtained by applying our method to 2D synthetic and real data collected on the Korean continental shelf.     

Evaluation of density in layer compaction using SASW method

SASW test, which is non-intrusive and rapid in the field application, was used to evaluate the layer density in the roller compaction without performing the complicated inversion process. The concept of normalized shear wave velocity was introduced to minimize the effect of confinement in the density evaluation. SASW test was performed to determine the shear wave velocity of the layer, and the free–free resonant column (FF–RC) test was adopted to determine the correlation between the normalized shear wave velocity and density of the site, which is almost unique independent of confinement. Testing and data reduction procedures of both tests were briefly discussed and an evaluation procedure of the field density was proposed by effectively combining in-situ shear wave velocity determined by the SASW test with the correlation between the normalized shear wave velocity and the density determined by the FF–RC test. Finally, the feasibility of the proposed method was verified by performing a field case study at Hoengsung road construction site. Field densities determined by the proposed method matched well with those determined by sand cone tests, showing the potential of applying the proposed method in the field density evaluation.     

Recent developments in seismically isolated buildings in Japan

The Building Standard Law of Japan and related Enforcement Order and Notifications have been substantially revised since the year 2000 to introduce a performance-based regulatory and deregulation system for building control systems. Up to then, time-history analyses were mandatory for isolated buildings and had to be specially approved by the Minster of the Ministry of Construction (MOC). Simplified design procedures based on the equivalent linear method for seismically isolated buildings have been issued as “Notification 2009 — Structural calculation procedure for buildings with seismic isolation” from MOC, and are now integrated into the Ministry of Land, Infrastructure, and Transportation (MLIT). Along with Notification 2009, “Notification 1446 of year 2000 — Standard for specifications and test methods for seismic isolation devices” was also issued. Buildings with heights equal to or less than 60m and that are designed according to these Notifications, including base isolated buildings, only need approval from local building officials, and no longer require the special approval of the Minister of MLIT. This paper summarizes: 1) some statistics related to buildings with seismic isolation completed up to the end of 2001; 2) simplified design procedures required by Notification 2009 of year 2000; and 3) performance of seismic isolation devices required by Notification 1446 of year 2000.     

TBT toxicity on the marine microalga Nannochloropsis oculata

Commercial antifouling formulations containing TBT are the major source of organotin contamination in coastal waters. In view of the persisting TBT residues (13 ng Sn l⁻¹) in the coastal waters of South Korea, an attempt has been made to evaluate the growth response and biochemical composition of laboratory-cultured Nannochloropsis oculata to TBT toxicity. It is evident that the persisting concentration level of TBT is high enough to cause adverse effect on the microalgal species. The EC₅₀ (24 h) was found to be at 0.89 nM level of TBT for this marine eustigmatophyte N. oculata. Photosynthetic pigment content was significantly affected. At elevated TBT concentrations of 1.0 nM, especially pronounced changes in biochemical composition was found. TBT tolerance of N. oculata and its growth as well as biochemical responses are discussed.