A Method to Suppress Isobaric and Polyatomic Interferences for Measurements of Highly Siderophile Elements in Desilicified Geological Samples

Sample decomposition using inverse aqua regia at elevated temperatures and pressures (e.g., Carius tube or high‐pressure asher) is the most common method used to extract highly siderophile elements (HSEs: Ru, Rh, Pd, Re, Os, Ir, Pt and Au) from geological samples. Recently, it has been recognised that additional HF desilicification is necessary to better recover HSEs, potentially contained within silicate or oxide minerals in mafic samples, which cannot be dissolved solely by inverse aqua regia. However, the abundance of interfering elements tends to increase in the eluent when conventional ion‐exchange purification procedures are applied to desilicified samples. In this study, we developed an improved purification method to determine HSEs in desilicified samples. This method enables the reduction of the ratios of isobaric and polyatomic interferences, relative to the measured intensities of HSE isotope masses, to less than a few hundred parts per million. Furthermore, the total procedural blanks are either comparable to or lower than conventional methods. Thus, this method allows accurate and precise HSE measurements in mafic and ultramafic geological samples, without the need for interference corrections. Moreover, the problem of increased interfering elements, such as Zr for Pd and Cr for Ru, is circumvented for the desilicified samples.     

Predictive modelling of rainfall-induced landslide hazard in the Lesser Himalaya of Nepal based on weights-of-evidence

Landslide hazard mapping is a fundamental tool for disaster management activities in mountainous terrains. The main purpose of this study is to evaluate the predictive power of weights-of-evidence modelling in landslide hazard assessment in the Lesser Himalaya of Nepal. The modelling was performed within a geographical information system (GIS), to derive a landslide hazard map of the south-western marginal hills of the Kathmandu Valley. Thematic maps representing various factors (e.g., slope, aspect, relief, flow accumulation, distance to drainage, soil depth, engineering soil type, landuse, geology, distance to road and extreme one-day rainfall) that are related to landslide activity were generated, using field data and GIS techniques, at a scale of 1:10,000. Landslide events of the 1970s, 1980s, and 1990s were used to assess the Bayesian probability of landslides in each cell unit with respect to the causative factors. To assess the accuracy of the resulting landslide hazard map, it was correlated with a map of landslides triggered by the 2002 extreme rainfall events. The accuracy of the map was evaluated by various techniques, including the area under the curve, success rate and prediction rate. The resulting landslide hazard value calculated from the old landslide data showed a prediction accuracy of > 80%. The analysis suggests that geomorphological and human-related factors play significant roles in determining the probability value, while geological factors play only minor roles. Finally, after the rectification of the landslide hazard values of the new landslides using those of the old landslides, a landslide hazard map with > 88% prediction accuracy was prepared. The methodology appears to have extensive applicability to the Lesser Himalaya of Nepal, with the limitation that the model's performance is contingent on the availability of data from past landslides.     

Molecular orbital study on the onset of the pressure-induced transformations of the metastably compressed germanates

In order to elucidate the onset of the pressure-induced transformations of germanates consisting of GeO₄ tetrahedra at room temperature, we have investigated the stability of the crystal structures near the transition pressure in terms of the stability of the linkage of the tetrahedra. The stability of the linkage near the transition pressure is estimated from the results of the molecular orbital calculations for the model cluster H₆Ge₂O₇, which mimics the linkage of tetrahedra, as functions of the bond length d(Ge–O_br) with bridging oxygen and bond angles Ge–O_br–Ge. The calculation shows that the total energy of the linkage becomes minimum at d(Ge–O_br)=1.758 Å and br–Ge=130.4°, and that it increases with the deviation from the energy minimum geometry. From the compression behavior of framework and chain germanates, we find that the linkage of the tetrahedra becomes unstable with increasing pressure, and that these germanates commonly transform into their high-pressure phases when the linkage of the tetrahedra largely departs from the energy minimum geometry. This suggests that the high-pressure transformations of the metastably compressed germanates are induced by the instability of the linkage of tetrahedra.