Observation and modeling of thermally induced upslope flow

Thermally induced upslope flows were observed on several slopes and in valleys, and a simple one-layer model of upslope flow was developed. In this model, the thickness and speed of upslope flow are expressed in terms of sensible heat flux from the slope surface, drag coefficient of the slope surface, slope steepness and stability of the ambient atmosphere. Model results compare favorably with the observations.The development process in the upslope direction of a steady upslope flow was investigated with this model. A steadily developing state in the upslope direction is expressed by the dimensionless equations together with a unique parameter associated with momentum advection. The vertical distance of the slope required for well-developed upslope flow has a minimum value for a moderate slope steepness, but increases monotonously with decreasing ambient stability. The effect of unsteadiness on upslope flow was also investigated. The transient time required to reach a steady state becomes shorter with increasing ambient stability and slope steepness.     

A new high-pressure phase of strontium carbonate

High-pressure and high-temperature experiments conducted in a laser-heated diamond-anvil cell with a synchrotron X-ray diffraction method have revealed a phase transformation in the aragonite-type SrCO₃ at pressures above 10 GPa. The new phase has an orthorhombic symmetry and was confirmed to remain stable to 32 GPa. The Birch-Murnaghan equation of state for new phase was determined from the experimental unit cell parameters, with K₀ = 101 (± 16) GPa, K₀ = 4 (constrained value), and V₀ = 111.9 (± 2.2). This transformation in SrCO₃ is different from that in BaCO₃ as reported in previous studies. After decompression at ambient pressure, the high-pressure phase transforms to a metastable structure, which has an orthorhombic symmetry. This result should also resolve a dispute regarding the stable high-pressure phases in BaCO₃, which is an analog material of CaCO₃ and SrCO₃.This revised version was published in February 2005 with corrections to the Introduction and to the References.     

Abundance and size composition of the summer phytoplankton communities in the western North Pacific Ocean,the Bering Sea,and the Gulf of Alaska

Chlorophylla concentrations (Chla) of size-fractionated phytoplankton samples were measured in the western North Pacific Ocean, the Bering Sea, and the Gulf of Alaska during the summer of 1986. Among samples collected in the upper 100 m (total of 210 samples), 207 samples were dominated by micro- (>10 m) or picoplankton (<2 m) and only three samples were represented by nanoplankton (2–10 m). These 207 samples were classified based on the total Chla content into three types: Type H (>1.0 g l^–1), Type M (0.5–1.0 g l^–1), and Type L (<0.5 g l^–1). These types further divided into two subtypes (-p and-m), depending upon dominancy of pico (-p) and microplankton (-m). The phytoplankton community was represented by Type L-p in the Gulf of Alaska, where 80% of the samples fell into this type. It was represented by Type M-p in the western North Pacific and the Oceanic Domain in the Bering Sea, where 53 and 41% of samples were identified as this type, respectively. In the Middle Domain of the Bering Sea, 68% of samples collected below the nitracline was Type H-m, which indicates blooms of microplanton. This type was also observed in the neritic waters near the Aleutian Islands. These types described above are consistent with a general trend that an increase in phytoplankton abundance is attributed to the growth of microplankton. An unusual type occurred above the nitracline of the Middle Domain, where microplankton prevailed, although the total Chla was less (Type L-m). This type represents a feature of late phase of an ice edge bloom. Another unusual type was found mainly in the Outer Domain of the Bering Sea, where the total Chla was high and picoplankton prevailed (Type H-p). The predominance of picoplankton seems to result from the heavy grazing intensity of large calanoid copepods upon microplankton but not upon picoplankton     

Comparison of Time-Dependent Tracer Ages in the Western North Pacific: Oceanic Background Levels of (SF6, CFC-11, CFC-12 and CFC-113

To verify the actual usefulness of time-dependent tracer dating techniques in the ocean, we simultaneously obtained two cross sections of sulfur hexafluoride (SF₆) and chlrofluoromethanes (CFC-11, trichlorofluoromethane; CFC-12, dichloro-difluromethane; CFC-113, trichlorotrifluoroethane) in the western North Pacific in 1998. The vertical distribution patterns of SF₆ and CFC-113 were similar in shape to those of CFC-11 and CFC-12. Maximum penetration depths of SF₆ and CFC-113 remained around 800 m in the subpolar region and 400 m in the tropical region, while the maximum penetration depths of CFC-11 and CFC-12 were still found below 1000 m depth. We also found all maximum contents of these tracers around 26.6−26.8σ_θ with a gradual decrease southward. This suggested that a new subsurface water mass in the subpolar region spread out over the entire North Pacific, which agrees closely with previous studies based on the salinity minimum. Moreover, we compared the tracer ages (the elapsed period of a water mass from when the water mass left from the ocean surface) using ten time-dependent tracer dating techniques, CFC-11, CFC-12, CFC-113, SF₆, CFC-11/CFC-12, CFC-113/CFC-11, CFC-113/CFC-12, SF₆/CFC-11, SF₆/CFC-12 and SF₆/CFC-113. This quantitative evaluation of multiple tracer dating techniques in the ocean was the first confirmation of its usefulness based on the observational data on the ocean basin-wide scale. We conclude that SF₆/CFC-11, SF₆/CFC-12, SF₆/CFC-113 and SF₆ dating techniques would be the most promising tools for determining the age of water mass not only just for the past several decades but for the future, too. This revised version was published online in July 2006 with corrections to the Cover Date.     

Distribution of cyanobacteria and other picophytoplankton in the western North Pacific Ocean,Summer 1989

Cell densities of phycoerythrin-fluorescing cyanobacteria and other chlorophyll-fluorescing picophytoplankton in the 0.2–2.0 µm size fraction were investigated, using an epifluorescence microscope, in the western North Pacific Ocean (36.5–44.0 °N, 155.0°E) in the summer of 1989. Cyanobacteria were most abundant in the surface of the subtropical water (36.5–38.0°N) and less in the northern sea area (39.5–44.0°N). The cell density of other picophytoplankton was, however, high in the northern part and low in the subtropical water. Results showed that algae other than cyanobacteria may significantly contribute to the picophytoplankton community under the low water temperature conditions of open waters. Chlorophylla concentration represented well the abundance of picophytoplankton other than cyanobacteria, but had no significant correlation with the cyanobacteria cell density. Chlorophylla-based data must be interpreted with caution, since the abundances of cyanobacteria were often considerably different even though the chlorophylla concentrations were the same level.     

Seasonal and Interannual Variation of DIC in Surface Mixed Layer in the Oyashio Region: A Climatological View

Eight-year observation results of DIC from 1996 to 2003 in the Oyashio region have been analyzed to obtain a climatological view of its seasonal variation and interannual variation. Data of DIC obtained by several institutes are synthesized to give a dataset with an uncertainty lower than 5 μmol/kg. The obtained climatology of NDIC seasonal variation in the Oyashio mixed layer shows a seasonal amplitude of 176 μmol/kg, with a maximum in January and a minimum in September. These features closely resemble those observed in the southern half of the western subarctic North Pacific (WSNP) including Station KNOT, although the timing of the NDIC maximum is slightly advanced in the case of the Oyashio. Analysis using a quasi-conservative tracer Cp0 (NDIC - 106NP) shows that among 176 μmol/kg of NDIC seasonal variation, only 16 μmol/kg is attributed to hydrographic processes while the remaining 160 μmol/kg is attributed to biological processes. The Cp0 value in the Oyashio mixed layer also resembles that of the WSNP mixed layer during the months May to November, suggesting further resemblance of the Oyashio water mass to that of WSNP in terms of carbon dynamics. The present results also suggest that a single data obtained in Oyashio mixed layer contains 30 μmol/kg of potential uncertainty for the representativity of this region, which leads to a note about a need to treat with caution results obtained by a single observation in this region.     

Seasonal changes in size-fractionated primary production and nutrient concentrations in the temperate neritic water of Funka Bay,Japan

Size-fractionated primary productivity and chlorophylla concentration were studied at two stations in the temperate neritic water of Funka Bay, Japan, from April 1984 to May 1985. Size distributions of phytoplankton were discussed in relation to nutrient availability. In the central part of the bay, 66% of the annual primary production occurred during the spring phytoplankton bloom with 95% of the spring production being accounted for by the greater than 10µm size fraction, which was dominated by diatoms. The increase in this large fraction was enhanced at both stations when nutrient concentrations increased in the bay's upper layer. Under low nutrient concentrations during summer, small phytoplankters (<2µm) accounted for 40 to 75% (average 60%) of the total¹⁴C uptake at the central station, and from 25 to 59% (average, 45%) at the coastal station. However, a sudden nutrient enrichment at the coastal station during the summer triggered the growth of the large size fraction. These seasonal and regional changes in total¹⁴C uptake were attributed to the large size fraction, composed mainly of diatoms. From the decreases in various nutrients during diatom blooms, it was further suggested that the predominance of diatoms was determined, not only by nutrient concentrations, but also by their relative availability.Contribution No. 205 from the Research Institute of North Pacific Fisheries, Faculty of Fisheries, Hokkaido University.     

Seasonal changes in the biomass of zooplankton and their food requirement in Funka Bay

Zooplankton biomass consisting of large and small-size copepods, copepod nauplii and tintinnids were investigated over a period of one year at two stations in Funka Bay, Japan. The food requirement of zooplankton was also estimated using the method of Ikeda and Motoda. Estimated total carbon requirement of zooplankton in the coastal and central parts of the bay was equivalent to 52 and 38% of the annual primary production, respectively. These corresponded to zooplankton production of 12–13 gC·m^–2·yr^–1.The total carbon requirement at each station increased to 63 and 74% of the primary production during summer compared with 26 and 3% in spring or 19 and 17% in winter. The microzooplankton (copepod nauplii and tintinnids) accounted for about half of the carbon requirement from April to November.Food requirements reached 161% at the coastal station and 194% at the central station of the daily organic carbon production during September. Zooplankton may also feed on carbon sources other than living phytoplankton. This could account for the observed decrease in particulate organic carbon in a water column.Contribution No. 202 from the Research Institute of North Pacific Fisheries, Faculty of Fisheries, Hokkaido University.     

Reynolds-Number Dependence of Gas Dispersion Over a Wavy Wall

Direct numerical simulations of an Ekman layer are performed to study flow evolution during the response of an initially neutral boundary layer to stable stratification. The Obukhov length, L, is varied among cases by imposing a range of stable buoyancy fluxes at the surface to mimic ground cooling. The imposition of constant surface buoyancy flux , i.e. constant-flux stability, leads to a buoyancy difference between the ground and background that tends to increase with time, unlike the constant-temperature stability case where a constant surface temperature is imposed. The initial collapse of turbulence in the surface layer owing to surface cooling that occurs over a time scale proportional to \(L/u_*\), where \(u_*\) is the friction velocity, is followed by turbulence recovery. The flow accelerates, and a “low-level jet” (LLJ) with inertial oscillations forms during the turbulence collapse. Turbulence statistics and budgets are examined to understand the recovery of turbulence. Vertical turbulence exchange, primarily by pressure transport, is found to initiate fluctuations in the surface layer and there is rebirth of turbulence through enhanced turbulence production as the LLJ shear increases. The turbulence recovery is not monotonic and exhibits temporal intermittency with several collapse/rebirth episodes. The boundary layer adjusts to an increase in the surface buoyancy flux by increased super-geostrophic velocity and surface stress such that the Obukhov length becomes similar among the cases and sufficiently large to allow fluctuations with sustained momentum and heat fluxes. The eventual state of fluctuations, achieved after about two inertial periods (\(ft \approx 4\pi \)), corresponds to global intermittency with turbulent patches in an otherwise quiescent background. Our simplified configuration is sufficient to identify turbulence collapse and rebirth, global and temporal intermittency, as well as formation of low-level jets, as in observations of the stratified atmospheric boundary layer.     

First-principles simulation of high-pressure polymorphs in MgAl<Subscript>2</Subscript>O<Subscript>4</Subscript>

We have used density functional theory to investigate the stability of MgAl₂O₄ polymorphs under pressure. Our results can reasonably explain the transition sequence of MgAl₂O₄ polymorphs observed in previous experiments. The spinel phase (stable at ambient conditions) dissociates into periclase and corundum at 14 GPa. With increasing pressure, a phase change from the two oxides to a calcium-ferrite phase occurs, and finally transforms to a calcium-titanate phase at 68 GPa. The calcium-titanate phase is stable up to at least 150 GPa, and we did not observe a stability field for a hexagonal phase or periclase + Rh₂O₃(II)-type Al₂O₃. The bulk moduli of the phases calculated in this study are in good agreement with those measured in high-pressure experiments. Our results differ from those of a previous study using similar methods. We attribute this inconsistency to an incomplete optimization of a cell shape and ionic positions at high pressures in the previous calculations.