Size and shape variation in the planktonic foraminiferHeterohelix striata (late cretaceous,southern Scandinavia)

The biserial planktonic foraminiferal species Heterohelix striata (Ehrenberg)has been analyzed by morphometric techniques from six sequential late Maestrichtian core samples from southern Sweden and one sample from the “Dania”quarry of Denmark. The study is based on measurements of number of chambers, size of test (length, width, and thickness),marginal angle, and chamber sizes. In addition, prolocular and apertural sizes were analyzed in the “Dania”quarry sample. The study includes analyses of the ontogenetic development of the tests, stratigraphic variation in size and shape, intrasample variability, and relationship between gross morphology of the test and prolocular and apertural dimensions.     

Multixenobiotic resistance, acetyl-choline esterase activity and total oxyradical scavenging capacity of the Arctic spider crab, Hyasaraneus, following exposure to bisphenol A, tetra bromo diphenyl ether and diallyl phthalate

The Arctic has become a sink for persistent organic pollutants (POPs) originating from lower latitudes, and relatively high levels have been found in different biota. Recent studies have identified detrimental effects on wildlife including endocrine disruption, impairment of enzyme activity, and reduced immune function. The Arctic spider crab, Hyas araneus, shown interesting potential for its use as sentinel organism in polar ecosystems. This study investigated the effect of 2,2',4,4'-tetra bromo diphenyl ether (BPDE), bisphenol A (BPA), and diallyl phthalte (DPA) on H. araneus in a three weeks exposure study. Expression of multixenibiotic resistance (MXR) proteins has been studied using the C219 monoclonal antibody which allows identifying an immunoreactive protein of 40 kDa in the digestive gland while no such protein could be observed in the gills. Expression of this protein was increased by exposure to DPA (+75%; p<0.05, n=10). All compounds significantly affected muscle acetylcholine esterase (AChE) activity (p<0.05, n=10) with 50 microg/L DPA having the strongest effect by lowering the value to 37% of control. The total oxyradical scavenging capacity measured in the digestive gland toward peroxyl, hydroxyl and peroxynitrite was also significantly reduced indicating a decreased resistance to oxidative stress generated by DPA (p<0.05, n=5). These results thus suggest the potential detrimental effects of DPA even at concentration as low as 50 microg/L on H. araneus.     

Pressure dependence of nickel partitioning between forsterite and aluminous silicate melts

Nickel partitioning between forsterite and aluminosilicate melt of fixed bulk composition has been determined at 1300°C to 20 kbar pressure. The value of the forsterite-liquid nickel partition coefficient is lowered from >20 at pressures equal to or less than 15 kbar to <10 at pressures above 15 kbar.Published data indicate that melts on the join Na₂O-Al₂O₃-SiO₂ become depolymerized in the pressure range 10–20 kbar as a result of Al shifting from four-coordination at low pressure to higher coordination as the pressure is increased. This coordination shift results in a decreasing number of bridging oxygens in the melt. It is suggested that the activity coefficient of nickel decreases with this decrease in the number of bridging oxygens. As a result, the nickel partition coefficient for olivine and liquid is lowered.Magma genesis in the upper mantle occurs in the pressure range where the suggested change in aluminum coordination occurs in silicate melts. It is suggested, therefore, that data on nickel partitioning obtained at low pressure are not applicable to calculation of the nickel distribution between crystals and melts during partial melting in the upper mantle. Application of high-pressure experimental data determined here for Al-rich melts to the partial melting process indicates that the melts would contain about twice as much nickel as indicated by the data for the low-pressure experiments. If, as suggested here, the polymerization with pressure is related to the Al content of the melt, the difference in the crystal-liquid partition coefficient for nickel at low and high pressure is reduced with decreasing Al content of the melt. Consequently, the change ofD_Ni^{ol-andesite melt} is greater than that ofD_Ni^{ol-basalt melt}, for example.     

Defect properties of albite

Knowledge of the defect properties of Lunar and Mercurian minerals has recently become important, with the advent of models which attempt to explain the formation of the thin exosphere of these celestial bodies. Here, we have calculated the formation energies of sodium and oxygen vacancies in the mineral albite (NaAlSi₃O₈), as well as the Schottky defect energy for the removal of a Na₂O unit. We have employed both the supercell and Mott–Littleton approaches, using Kohn–Sham density functional theory and classical interatomic potential methods. As well as reporting the defect energies and structures, we comment upon the relative merits of the methods used.     

Sedimentary recycling in arc magmas: geochemical and U–Pb–Hf–O constraints on the Mesoproterozoic Suldal Arc, SW Norway

The Hardangervidda-Rogaland Block within southwest Norway is host to ~1.52 to 1.48 Ga continental building and variable reworking during the ~1.1 to 0.9 Ga Sveconorwegian orogeny. Due to the lack of geochronological and geochemical data, the timing and tectonic setting of early Mesoproterozoic magmatism has long been ambiguous. This paper presents zircon U–Pb–Hf–O isotope data combined with whole-rock geochemistry to address the age and petrogenesis of basement units within the Suldal region, located in the centre of the Hardangervidda-Rogaland Block. The basement comprises variably deformed grey gneisses and granitoids that petrologically and geochemically resemble mature volcanic arc lithologies. U–Pb ages confirm that magmatism occurred from ~1,521 to 1,485 Ma, and conspicuously lack any xenocrystic inheritance of distinctly older crust. Hafnium isotope data range from εHf_(initial) +1 to +11, suggesting a rather juvenile magmatic source, but with possible involvement of late Palaeoproterozoic crust. Oxygen isotope data range from mantle-like (δ¹⁸O ~5 ‰) to elevated (~10 ‰) suggesting involvement of low-temperature altered material (e.g., supracrustal rocks) in the magma source. The Hf–O isotope array is compatible with mixing between mantle-derived material with young low-temperature altered material (oceanic crust/sediments) and older low-temperature altered material (continent-derived sediments). This, combined with a lack of xenoliths and xenocrysts, exposed older crust, AFC trends and S-type geochemistry, all point to mixing within a deep-crustal magma-generation zone. A proposed model comprises accretion of altered oceanic crust and the overlying sediments to a pre-existing continental margin, underthrusting to the magma-generation zone and remobilisation during arc magmatism. The geodynamic setting for this arc magmatism is comparable with that seen in the Phanerozoic (e.g., the Sierra Nevada and Coast Range batholiths), with compositions in the Suldal Sector reaching those of average upper continental crust. As within these younger examples, factors that drive magmatism towards the composition of the average continental crust include the addition of sedimentary material to magma source regions, and delamination of cumulate material. Underthrusting of sedimentary materials and their subsequent involvement in arc magmatism is perhaps a more widespread mechanism involved in continental growth than is currently recognised. Finally, the Suldal Arc magmatism represents a significant juvenile crustal addition to SW Fennoscandia.     

Chemical composition and acute toxicity in the water after in situ burning--a laboratory experiment

The chemical composition and toxicity of a water soluble fraction (WSF) of oil versus the underlying water after in situ burning (ISB), has been studied in a laboratory experiment. A system for allowing water sampling after ISB was developed. Seawater samples and oil were collected prior to and immediately after ISB, and chemical analysis was conducted. The chemical characterization of the water showed that the disappearance of water soluble oil components during ISB was insignificant. Acute toxicity tests with the marine copepod Calanus finmarchicus and Microtox® bioassay was performed to establish LC₅₀/EC₅₀ values of the water. The results were compared with regular WAF systems with unburned weathered oil, and indicated no increase in toxicity in the underlying water after ISB.     

Continental growth and reworking on the edge of the Columbia and Rodinia supercontinents; 1.86–0.9 Ga accretionary orogeny in southwest Fennoscandia

Geological history from the late Palaeoproterozoic to early Neoproterozoic is dominated by the formation of the supercontinent Columbia, and its break-up and re-amalgamation into the next supercontinent, Rodinia. On a global scale, major orogenic events have been tied to the formation of either of these supercontinents, and records of extension are commonly linked to break-up events. Presented here is a synopsis of the geological evolution of southwest Fennoscandia during the ca. 1.9–0.9 Ga period. This region records a protracted history of continental growth and reworking in a long-lived accretionary orogen. Three major periods of continental growth are defined by the Transscandinavian Igneous Belt (1.86–1.66 Ga), Gothian (1.66–1.52 Ga), and Telemarkian (1.52–1.48 Ga) domains. The 1.47–1.38 Ga Hallandian–Danopolonian period featured reorganization of the subduction zone and over-riding plates, with limited evidence for continental collision. During the subsequent 1.38–1.15 Ga interval, the region is interpreted as being located inboard of a convergent margin that is not preserved today and hosted magmatism and sedimentation related to inboard extensional events. The 1.15–0.9 Ga period is host to Sveconorwegian orogenesis that marks the end of this long-lived accretionary orogen and features significant crustal deformation, metamorphism, and magmatism. Collision of an indenter, typically Amazonia, is commonly inferred for the cause of widespread Sveconorwegian orogenesis, but this remains inconclusive. An alternative is that orogenesis merely represents subduction, terrane accretion, crustal thickening, and burial and exhumation of continental crust, along an accretionary margin. During the Mesoproterozoic, southwest Fennoscandia was part of a much larger accretionary orogen that grew on the edge of the Columbia supercontinent and included Laurentia and Amazonia amongst other cratons. The chain of convergent margins along the western Pacific is the best analogue for this setting of Proterozoic crustal growth and tectonism.     

Using sewage sludge as a sealing layer to remediate sulphidic mine tailings: a pilot-scale experiment, northern Sweden

At the Kristineberg mine, northern Sweden, sulphidic mine tailings were remediated in an 8-year pilot-scale experiment using sewage sludge to evaluate its applicability as a sealing layer in a composite dry cover. Sediment, leachate water, and pore gas geochemistry were collected in the aim of determining if the sludge was an effective barrier material to mitigate acid rock drainage (ARD) formation. The sludge was an effective barrier to oxygen influx as it formed both a physical obstruction and functioned as an organic reactive barrier to prevent oxygen to the underlying tailings. Sulphide oxidation and consequential ARD formation did not occur. Sludge-borne trace elements accumulated in a reductive, alkaline environment in the underlying tailings, resulting in an effluent drainage geochemistry of Cd, Cu, Pb and Zn below 10 μg/L, high alkalinity (810 mg/L) and low sulphate (38 mg/L). In contrast, the uncovered reference tailings received a 0.35-m deep oxidation front and typical ARD, with dissolved concentrations of Cd, Zn and sulphate, 20.8 μg/L, 16,100 μg/L and 1,390 mg/L, respectively. Organic matter degradation in the sludge may be a limiting factor to the function of the sealing layer over time as 85 % loss of the organic fraction occurred over the 8-year experimental period due to aerobic and anaerobic degradation. Though the cover may function in the short to medium term (100 years), it is unlikely to meet the demands of a long-term remedial solution.     

Fluid-assisted zircon and monazite growth within a shear zone: a case study from Finnmark,Arctic Norway

The U–Pb ages, REE content, and oxygen isotopic composition of zircon rims developed within a major shear zone in the Kalak Nappe Complex (KNC), Arctic Norway have been determined along with the age of monazite crystals. Different generations of granitic veins have been distinguished based on both field criteria and monazite ages of 446 ± 3 and 424 ± 3 Ma. Within each of these veins, inherited zircon cores are mantled by homogeneous low CL-response zircon rims which yield a range of concordant U–Pb dates of ca. 470–360 Ma. Significant numbers of zircon rims coincide with the timing of monazite crystallization. The zircon rims have moderate light REE enrichment compared to cores, distinctive (Sm/La) _n values of less than 12, and La between 0.3 and 10 ppm. This indicates free elemental exchange between newly formed zircon rims and the surrounding matrix. The rims have calculated accumulated alpha-radiation dosages corresponding with a crystalline structure and δ¹⁸O values of 1‰. This implies rim crystallization directly from a zirconium-saturated hydrothermal fluid which was modified by some silicate melt. Growth of the zircon rims was prolonged and locally variable due to preferential fluid flow. A third type of zircon can be recognized, forming both rims and cores, with high alpha-radiation doses, and significant enrichment in La, Pr, and Eu. These are interpreted as low-temperature hydrothermally altered metamict zircons. The high volatile input and partial melting in the shear zone favoured prolonged zircon rim growth due to its ability to easily nucleate on inherited seeds. On the other hand, monazite, susceptible to dissolution and re-growth, crystallized in brief episodes, as has been predicted from theoretical phase diagrams. From a regional perspective, these results elucidate cryptic Ar–Ar cooling ages, providing the first record of a Late Ordovician heating and cooling phase within the KNC prior to the climactic Scandian collision.