Effect of the alkaline industrial residues fly ash,green liquor dregs,and lime mud on mine tailings oxidation when used as covering material

The potential to use the alkaline residue products fly ash, green liquor dregs, and lime mud originating from paper mills as dry cover materials to seal tailings has been investigated. Metals concentration in lime mud and fly ash had the lowest and highest contents, respectively. The tailings (<1 % sulfur content, primarily pyrite) were disposed about 50 years ago and originated from the former Rönnskär mine site in Sweden. The results of chemical composition analysis show that the raw unoxidized tailings are active toward oxidation, while the components of the adjacent oxidized tailings are not. To quantify the release of metals from the tailings and to evaluate the effect of a sealing layer on oxidation and weathering of the tailings, batch leaching tests were conducted in which leachate from alkaline residue materials was fed to the tailings. The results show that a higher concentration of most trace elements is leached from the unoxidized tailings than from the oxidized tailings. Except As and Cr, the rest of analyzed metals (Cd, Cu, Ni, Pb) became immobilized in response to the increased pH as a consequence of the amendment. The three tested alkaline amendments show a similar potential for preventing the release of metals (with the exception of As and Cr) from the tailings. Under either aerobic or anaerobic conditions, microbial activity was found to be of minor importance. XRD analysis of the field samples revealed that it was feasible to use alkaline residue products in covering tailings, and that it was advantageous to use ash as a cover material more than dregs.     

The Fugløy Reef at 70°N; acoustic signature,geologic, geomorphologic and oceanographic setting

This is the first in-depth study of a cluster of cold-water coral reefs, the Fugløy Reefs, found at 70°N on the Norwegian margin. Combining high-resolution seismic reflection data, side-scan sonar, video-images, and oceanographic measurements reveals the geologic, geomorphologic and oceanographic setting in which the reefs occur. The reefs consist mainly of the scleractinian ahermatypic Lophelia pertusa, and exist below the thermocline at water depths between 140  m and 190 m. The reefs appear as cone-shaped, acoustically transparent features on seismic reflection data, consistently located in places characterized by the availability of hard substrate, high relief, and periodical exposure to high tidal currents (>30 cm/s). These currents transport water of the Norwegian Atlantic Current to the reefs from an area with fluid expulsion-related pockmarks. The spatial relationship between reef, pockmark locations, and current directions suggests that seepage of biogenic gas might be a catalyst to reef growth. With a height of more than 40 m some of the Fugløy reefs are among the highest reported from the Norwegian Margin. This indicates highly favourable growth conditions, and conservative estimates indicate a net growth rate for the reefs of ~5 mm/year. We expect that cold-water reefs will be found further north along the Barents Sea margin as general awareness on the geophysical signature and appearance of the reefs increases, because all known factors involved in reef establishment and growth are within the required intervals also further north.     

Radiogenic trigger and driver for continental rifting and initial ocean spreading

Closure and opening of oceans on time‐scales of a few hundred million years is a fundamental tectonic process on Earth, typically referred to as a “Wilson cycle”. Subduction of oceanic and continental crust leading up to and during continent–continent collision can refertilize and enrich the orogenic continental lithospheric mantle in heat‐producing elements. The resulting thermal anomaly weakens the lithosphere and, along with structural weaknesses (e.g. sutures), make this orogenic lithosphere more prone to rifting given an extensional stress field. Thermal modelling shows that anomalously hot lithosphere can focus asthenospheric upwellings over time‐scales of a few hundred million years. Processes related to closure of oceans thus provide a mechanism for later localization of rifting and an extensional driving force.     

Turbidites in the Upper Carboniferous Ross Formation, western Ireland: reconstruction of a channel and spillover system

ABSTRACT The Upper Carboniferous deep‐water rocks of the Shannon Group were deposited in the extensional Shannon Basin of County Clare in western Ireland and are superbly exposed in sea cliffs along the Shannon estuary. Carboniferous limestone floors the basin, and the basin‐fill succession begins with the deep‐water Clare Shales. These shales are overlain by various turbidite facies of the Ross Formation (460 m thick). The type of turbidite system, scale of turbidite sandstone bodies and the overall character of the stratigraphic succession make the Ross Formation well suited as an analogue for sand‐rich turbidite plays in passive margin basins around the world. The lower 170 m of the Ross Formation contains tabular turbidites with no channels, with an overall tendency to become sandier upwards, although there are no small‐scale thickening‐ or thinning‐upward successions. The upper 290 m of the Ross Formation consists of turbidites, commonly arranged in thickening‐upward packages, and amalgamated turbidites that form channel fills that are individually up to 10 m thick. A few of the upper Ross channels have an initial lateral accretion phase with interbedded sandstone and mudstone deposits and a subsequent vertical aggradation phase with thick‐bedded amalgamated turbidites. This paper proposes that, as the channels filled, more and more turbidites spilled further and further overbank. Superb outcrops show that thickening‐upward packages developed when channels initially spilled muds and thin‐bedded turbidites up to 1 km overbank, followed by thick‐bedded amalgamated turbidites that spilled close to the channel margins. The palaeocurrent directions associated with the amalgamated channel fills suggest a low channel sinuosity. Stacks of channels and spillover packages 25–40 m thick may show significant palaeocurrent variability at the same stratigraphic interval but at different locations. This suggests that individual channels and spillover packages were stacked into channel‐spillover belts, and that the belts also followed a sinuous pattern. Reservoir elements of the Ross system include tabular turbidites, channel‐fill deposits, thickening‐upward packages that formed as spillover lobes and, on a larger scale, sinuous channel belts 2·5–5 km wide. The edges of the belts can be roughly defined where well‐packaged spillover deposits pass laterally into muddier, poorly packaged tabular turbidites. The low‐sinuosity channel belts are interpreted to pass downstream into unchannellized tabular turbidites, equivalent to lower Ross Formation facies.     

Formation and composition of cemented layers in low-sulphide mine tailings, Laver, northern Sweden

Cemented layers (hardpans) are common in carbonate or sulphide-rich mine tailings and where pyrrhotite is the predominating Fe-sulphide. Laver, northern Sweden, is an abandoned Cu-mine where the tailings have low pyrrhotite content, almost no pyrite and no carbonates. Two cemented layers at different locations in the Laver tailings impoundment were investigated, with the aim to determine their effects on metal mobility. The cementing agents were mainly jarosite and Fe-oxyhydroxides in the layer formed where the tailings have a barren surface, whereas only Fe-oxyhydroxides were identified below grass-covered tailings surface. Arsenic was enriched in both layers which also exhibit high concentrations of Mo, V, Hg and Pb compared to unoxidised tailings. Sequential extraction indicates that these metals and As were mainly retained with crystalline Fe-oxides, and therefore potentially will be remobilised if the oxic conditions become more reducing, for instance as a result of remediation of the tailings impoundment.An erratum to this article can be found at     

Estimating the net flux of nutrients between a salt marsh and a tidal creek

Statistical aspects of estimating net fluxes of nutrients between a salt marsh and a tidal creek on a tidal cycle basis and an annual basis are explored. For individual tidal cycles, the instantaneous flux of a nutrient is written in a constrained linear model as a function of time. The model is rewritten as an unconstrained model, and net flux is shown to be a linear combination of the parameters of the model. Standard linear models techniques can be used to make inferences about net fluxes on a tidal cycle basis. Considering a year as a finite population of tidal cycles, annual net flux can be estimated using a regression estimator. In the case of the flux of dissolved nitrite plus nitrate, the marsh was found to be a statistically significant sink for nitrogen (in this form) from adjacent tidal creeks.     

Further analyses of radiogenic minerals from the Bidjovagge gold-copper deposit,Finnmark, Northern Norway

Summary We recently reported U/Pb and Sm/Nd dates on davidite from albitic felsites hosting the gold-copper mineralization of the Bidjovagge gold-copper deposit of northern Norway (69°17N, 22°29E). Isotopic dating of the north-south trending Proterozoic Kautokeino greenstone belt host rocks is sparse and confirmation of the dates was desirable, since the U/Pb data in particular were highly discordant and therefore somewhat uncertain.We have now supplemented the earlier measurements with U/Pb dating of uraninite from the felsites. The new uraninite data yield a well defined upper intersection with the concordia at 1837 ± 8 Ma, somewhat younger than the age of 1885 ± 18 Ma obtained on the davidites. The fact that the two minerals are apparently different in age lends support to the suggestion of a metamorphic origin of this deposit since a rather long period of cooling subsequent to metamorphism is indicated.

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Weitere Analysen von radiogenen Mineralen aus der Bidjovagge, Gold-Kupfer Lagerstätte, Finnmark, Nord-Norwegen

Zusammenfassung Wir haben erst kürzlich über U/Pb and Sm/Nd Daten von Davidit aus Albit-reichen, felsischen Gesteinen, in denen die Gold-Kupfer Mineralisation der Bidjovagge GoldKupfer Lagerstätte in Nord-Norwegen (69°17N, 22°29E) aufsitzt, berichtet. Es gibt wenige Isotopen-Datierungen der Gesteine, des N-S streichenden, proterozoischen Kautokeino Greenstone Belt. Außerdem ist eine Bestätigung der existierenden Daten wünschenswert, denn die bisherigen U/Pb Daten sind sehr widersprüchlich und unklar.Nun konnten wir die früheren Messungen mit U/Pb Daten von Uraninit aus den felsischen Gesteinen ergänzen. Die neuen Daten ergeben einen gut definierten Schnitt mit der Konkordia bei 1837 ± 8 Millionen Jahre, und sind damit etwas jünger als das von den Daviditen stammende Alter von 1885 ± 18 Millionen Jahre. Die Tatsache, daß diese beiden Minerale ein offensichtlich unterschiedliches Alter zeigen, unterstützt die Ansicht, daß die Lagerstätte metamorphen Ursprungs ist, wobei eine lange Periode der Abkühlung nach der Metamorphose zu vermuten ist.

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With 3 Figures