Assessment of chemical and physical treatments to selectively kill non-indigenous freshwater zooplankton species

Non-indigenous zooplankton species pose a biosecurity threat to New Zealand’s freshwater native taxa. Nine species are known to have established in New Zealand lakes to date. The spread of some zooplankton taxa is linked to the translocation of farmed fish, principally grass carp (Ctenopharyngodon idella), and recreational vessel movements. The aims of this study were to assess the effectiveness of a range of chemical and physical treatments for transport water and associated equipment to kill freshwater cladoceran, copepod, and rotifer zooplankton species, and their risk to non-target fish. Sodium chloride was the most effective and applicable chemical treatment tested at length in the cladoceran and, combined with physical treatment via mechanical filtration of water or hot water immersion of equipment (to also manage the risk of diapausing eggs), represents an effective option for the control of non-indigenous zooplankton, with limited impact on stenohaline fish.     

A data-model intercomparison study of Arctic sea-ice variability

The dynamic-thermodynamic granular rheology sea-ice model of Tremblay and Mysak is validated against 40 years of observed sea-ice concentration (SIC) data. Subsequently, the mechanisms responsible for producing SIC anomalies in the model are evaluated by studying the coupled variance (using the singular value decomposition method, SVD) between the simulated SIC anomalies and the ice speed and air temperature anomalies. To execute this validation, a 49-year (1949-97) simulation (including a 9-year spin-up period) of the Arctic and peripheral sea-ice cover using daily varying winds and monthly mean air temperatures is produced. In general, the simulated SIC variations for 1958-97 in the East Siberian, Chukchi and Beaufort seas are in agreement with observations, while larger discrepancies occur in the Laptev and Kara seas. Moreover, the sensitivity of the model to southerly wind anomalies in creating summer SIC anomalies compares well with the observed sensitivity; however, the model's sensitivity to summer air temperature anomalies is weaker than observed. The summer SIC anomalies over an entire sea are not influenced by variations in the level of river runoff. Results from the SVD analysis show that the main source of variability in the peripheral seas is associated with the variation in the strength of the Arctic High; in the East Siberian and Laptev seas, the strengthening and weakening of the Transpolar Drift Stream also play an important role. Over the entire Arctic domain, surface air temperature anomalies are negatively correlated with sea-ice anomalies. Finally, the observed downward trend in total sea-ice cover in the last two decades as well as record minima in the East Siberian Sea are well reproduced in the simulation.     

Development and analysis of echo classification using time delays

The results from an investigation of an analytically based method for determining the performance of echo classifiers are presented. In particular, the problem of classifying echo waveforms reflected from objects that are composed of multiple scatterers is considered. The time delays between the multiple echo returns from the individual scattering centers that characterize an object are investigated as features. A generic stochastic point scatterer model is developed for representing the classes of reflecting objects which are of interest. The model allows for uncertainty in prior knowledge about the exact relative location of the individual component scatterers or uncertainty in the delay measurements. A classifier decision algorithm, in the form of a general optimum Bayesian binary classification decision rule suitable for a large variety of classification problems, is derived for the case when the orientation of the reflecting object is known. The case of unknown aspect angle is addressed through the numerical implementation and analysis of two classifiers. The associated performance for all three classifiers is obtained in terms of the probability of error and tied to standard sonar equation parameters. Example binary classification problems are presented and analyzed and some general observations made. A pragmatic framework is established within which complex echo classification issues can be further examined     

Simulation of the interannual variability of the wind-driven Arctic sea-ice cover during 1958–1998

A thermodynamic-dynamic sea-ice model based on a granular material rheology developed by Tremblay and Mysak is used to study the interannual variability of the Arctic sea-ice cover during the 41-year period 1958–98. Monthly wind stress forcing derived from the National Centers for Environmental Prediction (NCEP) Reanalysis data is used to produce the year-to-year variations in the sea-ice circulation and thickness. We focus on analyzing the variability of the sea-ice volume in the Arctic Basin and the subsequent changes in sea-ice export into the Greenland Sea via Fram Strait. The relative contributions of the Fram Strait sea-ice thickness and velocity anomalies to the sea-ice export anomalies are first investigated, and the former is shown to be particularly important during several large export events. The sea-ice export anomalies for these events are next linked to prior sea-ice volume anomalies in the Arctic Basin. The origin and evolution of the sea-ice volume anomalies are then related to the sea-ice circulation and atmospheric forcing patterns in the Arctic. Large sea-ice export anomalies are generally preceded by large volume anomalies formed along the East Siberian coast due to anomalous winds which occur when the Arctic High is centered closer than usual to this coastal area. When the center of this High relocates over the Beaufort Sea and the Icelandic Low extends far into the Arctic Basin, the ice volume anomalies are transported to the Fram Strait region via the Transpolar Drift Stream. Finally, the link between the sea-ice export and the North Atlantic Oscillation (NAO) index is briefly discussed. The overall results from this study show that the Arctic Basin and its ice volume anomalies must be considered in order to fully understand the export through Fram Strait. Received: 27 January 1999 / Accepted: 8 July 1999     

Behaviour and modelling of partial‐strength beam‐to‐column composite joints for seismic applications

A refined component model is proposed to predict the inelastic monotonic response of exterior and interior beam‐to‐column joints for partial‐strength composite steel–concrete moment‐resisting frames. The joint typology is designed to exhibit ductile seismic response through plastic deformation developing simultaneously in the column web panel in shear, the bolted end‐plate connection, the column flanges in bending and the steel reinforcing bars in tension. The model can handle the large inelastic deformations consistent with high ductility moment‐resisting frames. Slip response between the concrete slab and the beams was taken into account. A fibre representation was adopted for the concrete slab to accurately capture the non‐uniform stress distribution and progressive crushing of the concrete at the interface between the concrete slab and the column flange. The model is validated against results from full‐scale subassemblages monotonic physical tests performed at the University of Pisa, Italy. A parametric study is presented to illustrate the capabilities of the model and the behaviour of the joints examined. Copyright © 2006 John Wiley & Sons, Ltd.     

Regional controls on geomorphology, hydrology, and ecosystem integrity in the Orinoco Delta, Venezuela

Interacting river discharge, tidal oscillation, and tropical rainfall across the 22,000 km² Orinoco delta plain support diverse fresh and brackish water ecosystems. To develop environmental baseline information for this largely unpopulated region, we evaluate major coastal plain, shallow marine, and river systems of northeastern South America, which serves to identify principal sources and controls of water and sediment flow into, through, and out of the Orinoco Delta.The regional analysis includes a summary of the geology, hydrodynamics, sediment dynamics, and geomorphic characteristics of the Orinoco drainage basin, river, and delta system. Because the Amazon River is a major source of sediment deposited along the Orinoco coast, we summarize Amazon water and sediment input to the northeastern South American littoral zone. We investigate sediment dynamics and geomorphology of the Guiana coast, where marine processes and Holocene history are similar to the Orinoco coast.Major factors controlling Orinoco Delta water and sediment dynamics include the pronounced annual flood discharge; the uneven distribution of water and sediment discharge across the delta plain; discharge of large volumes of water with low sediment concentrations through the Río Grande and Araguao distributaries; water and sediment dynamics associated with the Guayana littoral current along the northeastern South American coast; inflow of large volumes of Amazon sediment to the Orinoco coast; development of a fresh water plume seaward of Boca Grande; disruption of the Guayana Current by Trinidad, Boca de Serpientes, and Gulf of Paria; and the constriction at Boca de Serpientes.     

Carbon to nitrogen (C:N) stoichiometry of the spring–summer phytoplankton bloom in the North Water Polynya (NOW)

The carbon to nitrogen (C:N) stoichiometry of phytoplankton production varied significantly during the spring–summer bloom in the North Water Polynya (NOW), from April through July 1998. The molar ratio of particulate organic carbon (POC) to nitrogen (PON) production by phytoplankton (ΔPOC:ΔPON) increased from 5.8 during April through early June to 8.9 in late June and July. The molar dissolved inorganic carbon (DIC) to nitrate+nitrite (NO₃) drawdown ratio (ΔDIC: ΔNO₃) increased from 6.7 in April and May, to 11.9 in June (no estimate for July because of ice melting). The discrepancy between ΔPOC:ΔPON and ΔDIC:ΔNO₃ was likely due to dissolved organic carbon (DOC) production. Increased ΔPOC:ΔPON of phytoplankton and surface water ΔDIC:ΔNO₃ throughout the phytoplankton blooms resulted from changes in physical properties of the upper water column, such as reduced thickness of the surface mixed layer that exposed phytoplankton to increased photosynthetically available radiation (PAR), accompanied by NO₃ depletion. This is expected to have significant effects on the cycling of carbon (C) and nitrogen (N) in pelagic ecosystems, as the increased C:N ratio of organic matter decreases its quality as substrate for grazers and microbial communities. Based on ΔPOC:ΔPON, the ratio of POC to chlorophyll a (Chl) production (ΔPOC:ΔChl) and the relationship between Chl yields and NO₃ depletion, we estimate that 71±17% and 46±20% of the depleted NO₃ went to PON production in the euphotic zone over the polynya from April to early June, and late June to July, respectively. The remaining NO₃ was likely channelled to dissolved organic nitrogen (DON) and heterotrophic bacteria, which were not returned to the dissolved inorganic nitrogen (DIN) pool through recycling during the course of the study. Hence, the autotrophic production of organic N and its recycling by the microbial food web were not coupled temporally.     

Trophic structure and pathways of biogenic carbon flow in the eastern North Water Polynya

In the eastern North Water, most of the estimated annual new and net production of carbon (C) occurred during the main diatom bloom in 1998. During the bloom, at least 30% of total and new phytoplankton production occurred as dissolved organic carbon (DOC) and was unavailable for short-term assimilation into the herbivorous food web or sinking export. Based on particle interceptor traps and ²³⁴Th deficits, 27% of the particulate primary production (PP) sank out of the upper 50 m, with only 7% and 1% of PP reaching the benthos at shallow (≈200 m) and deep (≈500 m) sites, respectively. Mass balance calculations and grazing estimates agree that ≈79% of PP was ingested by pelagic consumers between April and July. During this period, the vertical flux of biogenic silica (BioSi) at 50 m was equivalent to the total BioSi produced, indicating that all of the diatom production was removed from the euphotic zone as intact cells (direct sinking) or empty frustules (grazing or lysis). The estimated flux of empty frustules was consistent with rates of herbivory by the large, dominant copepods and appendicularians during incubations. Since the carbon demand of the dominant planktivorous bird, Alle alle, amounted to ≈2% of the biomass synthesized by its main prey, the large copepod Calanus hyperboreus, most of the secondary carbon production was available to pelagic carnivores. Stable isotopes indicated that the biomass of predatory amphipods, polar cod and marine mammals was derived from these herbivores, but corresponding carbon fluxes were not quantified. Our analysis shows that a large fraction of PP in the eastern North Water was ingested by consumers in the upper 50 m, leading to substantial carbon respiration and DOC accumulation in surface waters. An increasingly early and prolonged opening of the Artic Ocean is likely to promote the productivity of the herbivorous food web, but not the short-term efficiency of the particulate, biological CO₂ pump.     

Fluoride in Nebraska's Ground Water

Fluoride concentrations in ground water are generally low but play an important role in dental health. This study evaluates the vertical and spatial distribution of fluoride in Nebraska's ground water and examines the geological and geochemical processes that control its concentration. Data from 1794 domestic wells sampled by the Nebraska Department of Health and Human Services. Regulation, and Licensure (NDOH) had a range of fluoride concentrations from <0.1 to 2.6 mg/L. and a median concentration of 0.3 mg/L. The median fluoride concentrations for Nebraska's 13 ground water regions varied from 0.2 to 0.7 mg/L. In each of these regions, individual wells may have either insufficient or overabundant F concentrations; we recommend that individual private water systems be tested for fluoride. Based on these data, system-specific recommendations can be made regarding the necessity for fluoridation.
Geochemical data indicated that the majority of fluoride occurs as F. Dissolution of F-bearing minerals controls fluoride occurrence. Apatite plus minor amounts of fluorite along with significant ground water residence times are the primary factors controlling F in the water from the Dakota Formation in Knox County, as well as in other parts of northeastern Nebraska. In western and southwestern Nebraska, dissolution of volcanic glass is the most probable source of F Long residence times plus fluorite also may contribute to the F concentrations in the Chadron Formation.