Atmospheric lead fallout over the last century recorded in Gulf of Lions sediments (Mediterranean Sea)

Six marine sediment cores from the Gulf of Lions continental slope (700-1700 m water depth) were analyzed for stable lead isotopes and (210)Pb geochronology in order to reconstruct lead atmospheric fallout pattern during the last century. The detrital lead contribution is 25 microg g(-1) and the mean sediment anthropogenic inventory is 110+/-7 microg cm(-2), a little bit higher than atmospheric deposition estimate. Anthropogenic lead accumulation in sediments peaked in early 1970s (1973+/-2) in agreement with lead emissions features. For the period 1986-1997, the sediment signal also reflect the decrease of atmospheric lead described by independent atmospheric fallout investigations. The anthropogenic Pb deposition in the late 1990s was similar to the 1950s deposition, attesting thus of the output of European environmental policies.     

Current state and trends in Canadian Arctic marine ecosystems: II. Heterotrophic food web, pelagic-benthic coupling, and biodiversity

As part of the Canadian contribution to the International Polar Year (IPY), several major international research programs have focused on offshore arctic marine ecosystems. The general goal of these projects was to improve our understanding of how the response of arctic marine ecosystems to climate warming will alter food web structure and ecosystem services provided to Northerners. At least four key findings from these projects relating to arctic heterotrophic food web, pelagic-benthic coupling and biodiversity have emerged: (1) Contrary to a long-standing paradigm of dormant ecosystems during the long arctic winter, major food web components showed relatively high level of winter activity, well before the spring release of ice algae and subsequent phytoplankton bloom. Such phenological plasticity among key secondary producers like zooplankton may thus narrow the risks of extreme mismatch between primary production and secondary production in an increasingly variable arctic environment. (2) Tight pelagic-benthic coupling and consequent recycling of nutrients at the seafloor characterize specific regions of the Canadian Arctic, such as the North Water polynya and Lancaster Sound. The latter constitute hot spots of benthic ecosystem functioning compared to regions where zooplankton-mediated processes weaken the pelagic-benthic coupling. (3) In contrast with another widely shared assumption of lower biodiversity, arctic marine biodiversity is comparable to that reported off Atlantic and Pacific coasts of Canada, albeit threatened by the potential colonization of subarctic species. (4) The rapid decrease of summer sea-ice cover allows increasing numbers of killer whales to use the Canadian High Arctic as a hunting ground. The stronger presence of this species, bound to become a new apex predator of arctic seas, will likely affect populations of endemic arctic marine mammals such as the narwhal, bowhead, and beluga whales.     

Shake table testing and numerical simulation of a self‐centering energy dissipative braced frame

The self‐centering energy dissipative (SCED) brace is a new steel bracing member that provides both damping to the structure and a re‐centering capability. The goal of this study was to confirm the behavior of SCED braces within complete structural systems and to confirm the ability to model these systems with both a state‐of‐the‐art computer model as well as a simplified model that would be useful to practicing engineers. To these ends, a three‐story SCED‐braced frame was designed and constructed for testing on a shake table. Two concurrent computer models of the entire frame were constructed: one using the opensees nonlinear dynamic modeling software, and a simplified model using the commercial structural analysis software sap2000 . The frame specimen was subjected to 12 significant earthquakes without any adjustment or modification between the tests. The SCED braces prevented residual drifts in the frame, as designed, and did not show any significant degradation due to wear. Both numerical models were able to predict the drifts, story shears, and column forces well. Peak story accelerations were overestimated in the models; this effect was found to be caused by the absence of transitions at stiffness changes in the hysteretic model of the braces. Copyright © 2013 John Wiley & Sons, Ltd.     

Fossil brines preserved in the St-Lawrence Lowlands, Québec, Canada as revealed by their chemistry and noble gas isotopes

Brines in Cambrian sandstones and Ordovician dolostones of the St-Lawrence Lowlands at Bécancour, Québec, Canada were sampled for analysis of all stable noble gases in order to trace their origin and migration path, in addition to quantifying their residence time. Major ion chemistry indicates that the brines are of Na-Ca-Cl type, possibly derived from halite dissolution. ⁸⁷Sr/⁸⁶Sr ratios and Ca excess indicate prolonged interactions with silicate rocks of the Proterozoic Grenville basement or the Cambrian Potsdam sandstone. The brines constrain a 2-3% contribution of mantle ³He and large amounts of nucleogenic ²¹Ne^∗ and ³⁸Ar^∗ and radiogenic ⁴He and ⁴⁰Ar^∗. ⁴He/⁴⁰Ar^∗ and ²¹Ne^∗/⁴⁰Ar^∗ ratios, corrected for mass fractionation during incomplete brine degassing, are identical to their production ratios in rocks. The source of salinity (halite dissolution), plus the occurrence of large amounts of ⁴⁰Ar^∗ in brines constrain the residence time of Bécancour brines as being older than the Cretaceous. Evaporites in the St-Lawrence Lowlands likely existed only during Devonian-Silurian time. Brines might result from infiltration of Devonian water leaching halite, penetrating into or below the deeper Cambrian-Ordovician aquifers. During the Devonian, the basin reached temperatures higher than 250 °C, allowing for thermal maturation of local gas-prone source rocks (Utica shales) and possibly facilitating the release of radiogenic ⁴⁰Ar^∗ into the brines. The last thermal event that could have facilitated the liberation of ⁴⁰Ar^∗ into fluids and contributed to mantle ³He is the Cretaceous Monteregian Hills magmatic episode. For residence times younger than the Cretaceous, it is difficult to find an appropriate source of salinity and of nucleogenic/radiogenic gases to the Bécancour brines.     

Structural changes of humic acids from sinking organic matter and surface sediments investigated by advanced solid-state NMR: Insights into sources, preservation and molecularly uncharacterized components

Knowledge of the structural changes that particulate organic matter (POM) undergoes in natural systems is essential for determining its reactivity and fate. In the present study, we used advanced solid-state NMR techniques to investigate the chemical structures of sinking particulate matter collected at different depths as well as humic acids (HAs) extracted from these samples and underlying sediments from the Saguenay Fjord and the St. Lawrence Lower Estuary (Canada). Compared to bulk POM, HAs contain more non-polar alkyls, aromatics, and aromatic C-O, but less carbohydrates (or carbohydrate-like structures). In the two locations studied, the C and N contents of the samples (POM and HAs) decreased with depth and after deposition onto sediments, leaving N-poor but O-enriched HAs and suggesting the involvement of partial oxidation reactions during POM microbial degradation. Advanced NMR techniques revealed that, compared to the water-column HAs, sedimentary HAs contained more protonated aromatics, non-protonated aromatics, aromatic C-O, carbohydrates (excluding anomerics), anomerics, OC_q, O-C_q-O, OCH, and OCH₃ groups, but less non-polar alkyls, NCH, and mobile CH₂ groups. These results are consistent with the relatively high reactivity of lipids and proteins or peptides. In contrast, carbohydrate-like structures were selectively preserved and appeared to be involved in substitution and copolymerization reactions. Some of these trends support the selective degradation (or selective preservation) theory. The results provide insights into mechanisms that likely contribute to the preservation of POM and the formation of molecules that escape characterization by traditional methods. Despite the depletion of non-polar alkyls with depth in HAs, a significant portion of their general structure survived and can be assigned to a model phospholipid. In addition, little changes in the connectivities of different functional groups were observed. Substituted and copolymerized carbohydrates and fused-ring aromatics detected in the present study likely represented an important part of molecularly uncharacterized components (MUC).     

Biogenic carbon flows through the planktonic food web of the Amundsen Gulf (Arctic Ocean): A synthesis of field measurements and inverse modeling analyses

Major pathways of biogenic carbon (C) flow are resolved for the planktonic food web of the flaw lead polynya system of the Amundsen Gulf (southeast Beaufort Sea, Arctic Ocean) in spring-summer 2008. This period was relevant to study the effect of climate change on Arctic marine ecosystems as it was characterized by unusually low ice cover and warm sea surface temperature. Our synthesis relied on a mass balance estimate of gross primary production (GPP) of 52.5 ± 12.5 g C m⁻² calculated using the drawdown of nitrate and dissolved inorganic C, and a seasonal f-ratio of 0.64. Based on chlorophyll a biomass, we estimated that GPP was dominated by phytoplankton (93.6%) over ice algae (6.4%) and by large cells (>5 μm, 67.6%) over small cells (<5 μm, 32.4%). Ancillary in situ data on bacterial production, zooplankton biomass and respiration, herbivory, bacterivory, vertical particle fluxes, pools of particulate and dissolved organic carbon (POC, DOC), net community production (NCP), as well as selected variables from the literature were used to evaluate the fate of size-fractionated GPP in the ecosystem. The structure and functioning of the planktonic food web was elucidated through inverse analysis using the mean GPP and the 95% confidence limits of every other field measurement as lower and upper constraints. The model computed a net primary production of 49.2 g C m⁻², which was directly channeled toward dominant calanoid copepods (i.e. Calanus hyperboreus 20%, Calanus glacialis 10%, and Metridia longa 10%), other mesozooplankton (12%), microzooplankton (14%), detrital POC (18%), and DOC (16%). Bacteria required 29.9 g C m⁻², a demand met entirely by the DOC derived from local biological activities. The ultimate C outflow comprised respiration fluxes (82% of the initial GPP), a small sedimentation (3%), and a modest residual C flow (15%) resulting from NCP, dilution and accumulation. The sinking C flux at the model limit depth (395 m) supplied 60% of the estimated benthic C demand (2.8 g C m⁻²), suggesting that the benthos relied partly on other C sources within the bottom boundary layer to fuel its activity. In summary, our results illustrate that the ongoing decline in Arctic sea ice promotes the growth of pelagic communities in the Amundsen Gulf, which benefited from a ∼80% increase in GPP in spring-summer 2008 when compared to 2004 – a year of average ice conditions and relatively low GPP. However, 53% of the secondary production was generated within the microbial food web, the net ecological efficiency of zooplankton populations was not particularly high (13.4%), and the quantity of biogenic C available for trophic export remained low (6.6 g C m⁻²). Hence it is unlikely that the increase in lower food web productivity, such as the one observed in our study, could support new harvestable fishery resources in the offshore Beaufort Sea domain.     

Seismic performance of a 3D full‐scale high‐ductile steel–concrete composite moment‐resisting frame—Part II: Test results and analytical validation

This paper presents the results of a multi‐level pseudo‐dynamic seismic test program that was performed to assess the performance of a full‐scale three‐bay, two‐storey steel–concrete composite moment‐resisting frame built with partially encased composite columns and partial‐strength beam‐to‐column joints. The system was designed to develop a ductile response in the joint components of beam‐to‐column joints including flexural yielding of beam end plates and shear yielding of the column web panel zone. The ground motion producing the damageability limit state interstorey drift caused minor damage while the ultimate limit state ground motion level entailed column web panel yielding, connection yielding and plastic hinging at the column base connections. The earthquake level chosen to approach the collapse limit state induced more damage and was accompanied by further column web panel yielding, connection yielding and inelastic phenomena at column base connections without local buckling. During the final quasi‐static cyclic test with stepwise increasing displacement–amplitudes up to an interstorey drift angle of 4.6%, the behaviour was ductile although cracking of beam‐to‐end‐plate welds was observed. Correlations with numerical simulations taking into account the inelastic cyclic response of beam‐to‐column and column base joints are also presented in the paper together. Inelastic static pushover and time history analysis procedures are used to estimate the structural behaviour and overstrength factors of the structural system under study. Copyright © 2008 John Wiley & Sons, Ltd.     

Evaporation from boreal reservoirs: A comparison between eddy covariance observations and estimates relying on limited data

Hydrological models used for reservoir management typically lack an accurate representation of open-water evaporation and must be run in a scarce data context. This study aims to identify an accurate means to estimate reservoir evaporation with simple meteorological inputs during the open-water season, using long-term eddy covariance observations from two boreal hydropower reservoirs with contrasting morphometry as reference. Unlike the temperate water bodies on which the majority of other studies have focused, northern reservoirs are governed by three distinct periods: ice cover in the cold season, warming in the summer and energy release in the fall. The reservoirs of interest are Eastmain-1 (52°N, mean depth of 11 m) and Romaine-2 (51°N, mean depth of 42 m), both located in eastern Canada. Four approaches are analysed herein: a combination approach, a radiation-based approach, a mass-transfer approach, and empirical methods. Of all the approaches, the bulk transfer equation with a constant Dalton number of 1.2 x 10⁻³ gave the most accurate estimation of evaporation at hourly time steps, compared with the eddy covariance observations (RMSE of 0.06 mm h⁻¹ at Eastmain-1 and RMSE of 0.04 mm h⁻¹ at Romaine-2). The daily series also showed good accuracy (RMSE of 1.38 mm day⁻¹ at Eastmain-1 and RMSE of 0.62 mm day⁻¹ at Romaine-2) both in the warming and energy release phases of the open-water season. The bulk transfer equation, on the other hand, was incapable of reproducing condensation episodes that occurred soon after ice breakup. Basic and variance-based sensitivity analyses were conducted, in particular to measure the variation in performance when the bulk transfer equation was applied with meteorological observations collected at a certain distance (~10–30 km) from the reservoir. This exercise illustrated that accurate estimates of open water evaporation require representative measurements of wind speed and water surface temperature.