Tectonics of an Early Carboniferous forearc inferred from a high-P/T schist-bearing conglomerate in the Nedamo Terrane, Northeast Japan

The Nedamo Terrane, an Early Carboniferous accretionary complex, is the oldest biostratigraphically dated accretionary complex in Japan. The purpose of this study is to describe and interpret a conglomerate from the Nedamo Terrane that contains clasts of high-pressure/low-temperature (high- P/T ) schist (mainly garnet-bearing phengite schist) and ultramafic rock, and to infer the tectonics of an Early Carboniferous arc–trench system at the eastern margin of the paleo-Asian continent. Clasts of high- P/T schist and ultramafic rock within the conglomerate make up 8.4 and 6.7% of the total clasts, respectively, based on modal counts. These clasts are subangular to subrounded, whereas volcanic clasts are well rounded. The source of the schist clasts, which yield a radiometric age of 347–317 Ma, is considered to be the Renge Metamorphic Rocks of Southwest Japan or equivalent rocks. Based on the chemical composition of chromian spinel, the source of ultramafic clasts is inferred to be the island-arc-type Ordovician Miyamori and Hayachine ultramafic complexes in the Kitakami Massif. The conglomerate records multiple provenance regions, including an island arc (South Kitakami Terrane) and a forearc ridge; the high P/T schist and ultramafic rocks were exhumed in the forearc region. The duration of the interval from the early stages of exhumation of the schist to its deposition in the trench as clasts is estimated to have been less than 30 my.     

Evolution of sandstone peak‐forest landscapes – insights from quantifying erosional processes with cosmogenic nuclides

The sandstone peak‐forest landscape in Zhangjiajie UNESCO Global Geopark of Hunan Province, China, is characterized by >3000 vertical pillars and peak walls of up to 350 m height, representing a spectacular example of sandstone landform variety. Few studies have addressed the mechanisms and timescales of the longer‐term evolution of this landscape, and have focused on fluvial incision. We use in situ cosmogenic nuclides combined with GIS analysis to investigate the erosional processes contributing to the formation of pillars and peak‐forests, and discuss their relative roles in the formation and decay of the landscape. Model maximum‐limiting bedrock erosion rates are the highest along the narrow fluvial channels and valleys at the base of the sandstone pillars (~83–122 mm kyr^?1), and lowest on the peak wall tops (~2.5 mm kyr^?1). Erosion rates are highly variable and intermediate along vertical sandstone peak walls and pillars (~30 to 84 mm kyr^?1). Catchment‐wide denudation rates from river sediment vary between ~26 and 96 mm kyr^?1 and are generally consistent with vertical wall retreat rates. This highlights the importance of wall retreat for overall erosion in the sandstone peak‐forest. In combination with GIS‐derived erosional volumes, our results suggest that the peak‐forest formation in Zhangjiajie commenced in the Pliocene, and that the general evolution of the landscape followed our sequential refined model: (i) slow lowering rates following initial uplift; (ii) fast plateau dissection by headward knickpoint propagation along joints and faults followed by; (iii) increasing contribution of wall retreat in the well‐developed pillars and peak‐forests and a gradual decrease in overall denudation rates, leading to; (iv) the final consumption of pillars and peak‐forests. Our study provides an approach for quantifying the complex interplay between multiple geomorphic processes as required to assess the evolutionary pathways of other sandstone peak‐forest landscapes across the globe. Copyright © 2017 John Wiley & Sons, Ltd.     

Using GIS to develop a mobile communications network for disaster-damaged areas

Communications network damage resulting from a large disaster causes difficulties in the ability to rapidly understand the current situation and thus make appropriate decisions towards mitigating problems, such as where to send and dispense emergency supplies. The research outlined in this paper focuses on the rapid construction of a network after a disaster occurs. This study suggests ZigBee and geographic information systems (GIS) technologies to resolve these problems and provide an effective communication system. The experimental results of the ZigBee network system are presented, examples are provided of the mapping and analysis undertaken using GIS for the disaster-stricken area of Tsukuba City, Japan, and the communications node arrangements are determined for this region. These results demonstrate the effectiveness of establishing such a communications system for supporting efforts to relieve disaster-damaged areas.     

Conversion of sedimentary fatty acids from extractable (unbound + bound) to tightly bound form during mild heating

Prolonged heating (1–248 days) of a recent sediment was conducted under mild conditions (65 and 83°C) to understand the thermal behavior of extractable (unbound and bound) fatty acids (C_12C32). In the course of the heating, the concentrations of saturated and monounsaturated fatty acids first decreased, and then increased. This indicates that extractable fatty acids can be converted to a tightly bound form upon heating, before fatty acids are extensively released from sediment matrices. Changes in molecular distributions of extractable fatty acids upon heating were also observed. The higher molecular weight fatty acids (?C₂₀) are more likely to become tightly bound than are lower molecular weight (<C₂₀). Monounsaturated fatty acids (C_16:1 and C_18:1) are more easily converted to the tightly bound form than polyunsaturated fatty acids (C_18:2 and C_18:3). These differences probably reflect their mode of occurrence in sediments, which are closely related to their origin.     

A dispersion equation and dispersion coefficient for material transport in Inland Seas

To analyse material transport in inland seas, a horizontal two-dimensional dispersion equation is derived, and the dispersion coefficient due to the combined effect of vertical turbulent mixing and vertical shear of both a steady current and a tidal current is studied. In the present study, the assumption that velocity is uniform in horizontal planes is not necessary, and velocity has a free vertical profile; thus the dispersion coefficient formulated is general, and is represented by a tensor of the second order. The properties of the dispersion coefficient in the horizontal two-dimensional dispersion model are also investigated, and it is shown that the time-averaged dispersion coefficient due to the tidal current over a tidal period is approximately half that due to the steady current, if the velocity amplitude and the vertical profile of the tidal current are the same as those of the steady current (a similar result was presented byBowden (1965) for horizontal one-dimensional models). Finally, the dispersion coefficient in Hiuchi-Nada (Hiuchi Sound) in the central part of the Seto Inland Sea is evaluated by using the model. The values of the dispersion coefficient in that region range from 10³ cm² s^–1 to 10⁵ cm² s^–1 when vertical turbulent diffusivity is taken to be 50 cm² s^–1.     

Structure and dynamics of water on Li-, Na-, K-, Cs-, H3O-exchanged muscovite surfaces: A molecular dynamics study

The distribution and dynamics of water molecules and monovalent cations (Li⁺, Na⁺, K⁺, Cs⁺, and H₃O⁺) on muscovite surfaces were investigated by molecular dynamics (MD) simulations. The direct comparison of calculated X-ray reflectivity profiles and electron density profiles with experiments revealed the precise structure at the aqueous monovalent electrolyte solutions/muscovite interface. To explain the experimentally observed electron density profiles for the CsCl solution-muscovite interface, the co-adsorption of Cs⁺ and Cl⁻ ion pairs would be necessary. Two types of inner-sphere complexes and one type of outer-sphere complex were observed for hydrated Li⁺ ions near the muscovite surface. For Na⁺, K⁺, Cs⁺, and H₃O⁺ ions, the inner-sphere complexes were stable on the muscovite surface. The density oscillation of water molecules was observed to approximately 1.5 nm from the muscovite surface. The number of peaks and the locations for the density of water oxygen atoms were almost similar among the water molecules coordinated to Li⁺, Na⁺, K⁺, and H₃O⁺ ions adsorbed on the muscovite surfaces. The water molecules around Cs⁺ ions that were adsorbed to muscovite surfaces seemed to avoid coordinating with Cs⁺ ions on the surface, and the density of water oxygen near the muscovite surface decreased relative to that in a bulk state. There was no significant difference in self-diffusion, viscosity, retention time, and reorientation time of water molecules among different cations adsorbed to muscovite surfaces. These translational and rotational motions of water molecules located at less than 1 nm from the muscovite surfaces were slower than those in a bulk state. A significant difference was observed for the exchange times of water molecules around monovalent cations. The exchange time of water molecules was long around Li⁺ ions and decreased with an increase in the ionic radius.     

The origin of Zn isotope fractionation in sulfides

Isotope fractionation of Zn between aqueous sulfide, chloride, and carbonate species (Zn²⁺, Zn(HS)₂, , , ZnS(HS)⁻, ZnCl⁺, ZnCl₂, , and ZnCO₃) was investigated using ab initio methods. Only little fractionation is found between the sulfide species, whereas carbonates are up to 1‰ heavier than the parent solution. At pH > 3 and under atmospheric-like CO₂ pressures, isotope fractionation of Zn sulfides precipitated from sulfidic solutions is affected by aqueous sulfide species and the δ⁶⁶Zn of sulfides reflect these in the parent solutions. Under high P_CO2 conditions, carbonate species become abundant. In high P_CO2 conditions of hydrothermal solutions, Zn precipitated as sulfides is isotopically nearly unfractionated with respect to a low-pH parent fluid. In contrast, negative δ⁶⁶Zn down to at least −0.6‰ can be expected in sulfides precipitated from solutions with pH > 9. Zinc isotopes in sulfides and rocks therefore represent a potential indicator of mid to high pH in ancient hydrothermal fluids.     

Consistency and fidelity of Indonesian-throughflow total volume transport estimated by 14 ocean data assimilation products

Monthly averaged total volume transport of the Indonesian throughflow (ITF) estimated by 14 global ocean data assimilation (ODA) products that are decade to multi-decade long are compared among themselves and with observations from the INSTANT Program (2004–2006). The main goals of the comparisons are to examine the consistency and evaluate the skill of different ODA products in simulating ITF transport. The ensemble averaged, time-mean value of ODA estimates is 13.6 Sv (1 Sv = 10⁶ m³/s) for the common 1993–2001 period and 13.9 Sv for the 2004–2006 INSTANT Program period. These values are close to the 15-Sv estimate derived from INSTANT observations. All but one ODA time-mean estimate fall within the range of uncertainty of the INSTANT estimate. In terms of temporal variability, the scatter among different ODA estimates averaged over time is 1.7 Sv, which is substantially smaller than the magnitude of the temporal variability simulated by the ODA systems. Therefore, the overall “signal-to-noise” ratio for the ensemble estimates is larger than one. The best consistency among the products occurs on seasonal-to-interannual time scales, with generally stronger (weaker) ITF during boreal summer (winter) and during La Nina (El Nino) events. The scatter among different products for seasonal-to-interannual time scales is approximately 1 Sv. Despite the good consistency, systematic difference is found between most ODA products and the INSTANT observations. All but the highest-resolution (18 km) ODA product show a dominant annual cycle while the INSTANT estimate and the 18-km product exhibit a strong semi-annual signal. The coarse resolution is an important factor that limits the level of agreement between ODA and INSTANT estimates. Decadal signals with periods of 10–15 years are seen. The most conspicuous and consistent decadal change is a relatively sharp increase in ITF transport during 1993–2000 associated with the strengthening tropical Pacific trade wind. Most products do not show a weakening ITF after the mid-1970s’ associated with the weakened Pacific trade wind. The scatter of ODA estimates is smaller after than before 1980, reflecting the impact of the enhanced observations after the 1980s. To assess the representativeness of using the average over a three-year period (e.g., the span of the INSTANT Program) to describe longer-term mean, we investigate the temporal variations of the three-year low-pass ODA estimates. The average variation is about 3.6 Sv, which is largely due to the increase of ITF transport from 1993 to 2000. However, the three-year average during the 2004–2006 INSTANT Program period is within 0.5 Sv of the long-term mean for the past few decades.