El Niño related interannual variations in biological production in the North Pacific as evidenced by satellite and ship data

A recently proposed method for estimating nitrate and new production from remotely sensed data (Goes and Goes) allowed us to observe significant deviations from the normal in the quantum of winter-time nitrate injected into the euphotic column and its consumption by phytoplankton in the North Pacific following the El Niño event of 1997. Results from this study allowed us to observe large differences in the ways in which the El Niño event affected the western and the eastern margins of the North Pacific basin. For the western North Pacific, a long-term (1972–1992) historical record of oceanographic data provided us with clear evidence supporting of our findings from satellite observations. In the eastern North Pacific Ocean also, our results compared well with those previously reported (Wong, Whitney, Matear, & Iseki, 1998). While it is clear from this study that El Niño/La Niña oscillations can have a major influence on interannual variations in biological processes in the North Pacific, these results also serve to highlight the value of remote sensing as a tool for studying large regional to basin-scale biological oceanographic events.     

Graphitization of carbonaceous matter during metamorphism with references to carbonate and pelitic rocks of contact and regional metamorphisms,Japan

This study is an attempt to correlate the graphitization process of carbonaceous matter during metamorphism with metamorphic grade. Graphitization can be parameterized using crystal structure and chemical and isotopic compositions. The extent of graphitization could be characterized mainly by temperature, duration of metamorphism and rock composition. We compared the graphitization trends for two metamorphic terrains, a contact aureole of the Kasuga area and a regional metamorphic terrain of high-temperature/low pressure type of the Ryoke metamorphic terrain in Northern Kiso area, Central Japan, and for two different lithologies (carbonate and pelite), using X-ray diffractogram, DTA-TG analysis, and chemical and stable isotope analyses. During contact metamorphism, graphitization and carbon isotopic exchange reactions proceeded simultaneously in pelitic and carbonate rocks. The decreases in basal spacing d(002) of the carbonaceous matter in carbonate rocks is greatly accelerated at temperatures higher than about 400° C. Furthermore, carbon isotopic ratios of graphite in carbonate rocks also change to ¹³C-enriched values implying exchange with carbonates. The beginning of this enrichment of ¹³C in the carbonaceous matter coincides with an abrupt increase of the graphitization processes. Carbon isotopic shifting up to 5 in pelites could be observed as metamorphic temperature increased probably by about 400° C. Carbonaceous matter in pelitic rocks is sometimes a mixture of poorly crystallized organic matter and well-crystallized graphite detritus. DTA-TG analysis is an effective tool for the distinction of detrital graphitic material. Two sources for the original carbon isotopic composition of carbonaceous matter in pelites in the Kasuga contact aureole can be distinguished, about-28 and-24 regardless of the presence of detrital graphite, and were mainly controlled by depositional environment of the sediments. Graphitization in limestones and pelitic rocks in regional metamorphism proceeds further than in a contact aureole. In the low-temperature range, the differences in extent of graphitization between the two metamorphic regions is large. However, at temperatures higher than 600° C, the extent of graphitization in both regions is indistinguishable. The degree of graphitization is different in limestones and pelitic rocks from the Ryoke metamorphic terrain. We demonstrate that the graphitization involves a progressive re-construction process of the crystal structure. The sequence of the first appearance of crystal inter planar spacing correlates with the metamorphic grade and indicates the crystal growth of three-dimensional structured graphite.     

A carbon budget in Tokyo Bay

Organic carbon flux from eutrophicated Tokyo Bay to the Pacific Ocean is estimated as 260 ton C day^–1 based on the horizontal gradient of COD and the dispersion coefficient at the bay mouth. Also, carbon flux from the air or from the open ocean to Tokyo Bay is estimated as 156 ton C day^–1. If we suppose that five percent of the coastal seas in the world might be eutrophicated as Tokyo Bay and the organic carbon flux from the shelf to the open ocean in other coastal seas might be one third of that in Tokyo Bay, 1.12 G tons year^–1 would be transported from the eutrophicated coastal seas to the open ocean and such carbon flux may account for the missing sink in the global carbon budget.     

Surface currents around Hokkaido in the late fall of 1981 obtained from analysis of satellite images

This paper describes the characteristics of currents around Hokkaido using a current vector map compiled by chasing the displacement of sea marks on a pair of successive thermal infrared images taken from a satellite, NOAA-6. The points of some sea surface patterns showing distinctive features which can be commonly identified in both images are called Sea Marks≓. This sea mark chase method≓ has a great advantage over velocity measurements by boats or buoys, in that it gives a synoptic view of the velocity distribution over a broad sea area extending for some hundreds of miles on a short time scale of half a day.In order to investigate the current in the late fall of 1981, we used the data taken at 19:05 JST on 30 October and at 7:20 JST on 31 October. With these data taken with a 12 hr difference, the measurement accuracy of the speed of sea marks reached ±0.1 knot through geometrical correction. The velocity vectors of sea marks agreed with results of GEK measurements performed on those days, and also with the mean current pattern obtained in the past based on sea surface data.The most distinct features recognized were some cyclonic and anticyclonic eddies of the order of 100 km in diameter which dominated in the Kuril Basin of the Okhotsk Sea. They appeared clearly in the original NOAA images and their physical parameters were determined quantitatively from the vector map. These eddies were located in the region of decay of the Soya Warm Current and were rotating at a speed nearly as large as that of the current. The problems of what feeds energy to these eddies and how long they live remain to be solved in future studies.     

Water content of primitive low-K tholeiitic basalt magma from Iwate Volcano,NE Japan arc: implications for differentiation mechanism of frontal-arc basalt magmas

The water content of low-K tholeiitic basalt magma from Iwate volcano, which is located on the volcanic front of the NE Japan arc, was estimated using multi-component thermodynamic models. The Iwate lavas are moderately porphyritic, consisting of ~8 vol.% olivine and ~20 vol.% plagioclase phenocrysts. The olivine and plagioclase phenocrysts show significant compositional variations, and the Mg# of olivine phenocrysts (Mg#78–85) correlates positively with the An content of coexisting plagioclase phenocrysts (An_85–92). The olivine phenocrysts with Mg# > ~82 do not form crystal aggregates with plagioclase phenocrysts. It is inferred from these observations that the phenocrysts with variable compositions were primarily derived from mushy boundary layers along the walls of a magma chamber. By using thermodynamic calculations with the observed petrological features of the lavas, the water content of the Iwate magma was estimated to be 4–5 wt.%. The high water content of the magma supports the recent consensus that frontal-arc magmas are remarkably hydrous. Using the estimated water content of the Iwate magma, the water content and temperature of the source mantle were estimated. Given that the Iwate magma was derived from a primary magma solely by olivine fractionation, the water content and temperature were estimated to be ~0.7 wt.% and ~1,310 °C, respectively. Differentiation mechanisms of low-K frontal-arc basalt magmas were also examined by application of a thermodynamics-based mass balance model to the Iwate magma. It is suggested that magmatic differentiation proceeds primarily through fractionation of crystals from the main molten part of a magma chamber when it is located at <~200 MPa, whereas magma evolves through a convective melt exchange between the main magma and mushy boundary layers when the magma body is located at >~200 MPa.     

A catalytic oxidation method for the determination of total nitrogen dissolved in seawater

A detailed examination of a high-temperature catalytic oxidation method for liquid samples in the analysis of total nitrogen dissolved in seawater is reported. The nitrogenous compounds in liquid samples are oxidized on a platinum catalyzer at 680°C under oxygen atmosphere and the generated NO₂ is absorbed into a chromogenic reagent, followed by a spectrophotometric determination. The results of this method are much higher than those of wet oxidation methods. Molecular size dependency of the results clearly indicates that the above discrepancy is caused by the low oxidation capacity of the wet oxidation method against high-polymer organic matter dissolved in seawater. The results revealed that the concentration of total nitrogen in seawater is nearly constant from surface to bottom, ranging from 30 to 40 μM 1^?1, which organic nitrogen concentration higher in the surface layer, and a rapid decrease with depth. An examination of molecular size distribution indicates that the concentration of high-polymer organic nitrogen decreases rapidly from surface to deeper layers, with molecular sizes ranging from 5 × 10³ to 3 × 10⁴. Because of the well-defined principle of the oxidation process, its reliability, ease of sample handling and of analytical procedure on board or in the land laboratory, the present method is much more suitable for the marine analytical chemistry of total and organic nitrogen than the other previous methods.     

Morphology of intergranular pores and wetting angles in pelitic schists studied by transmission electron microscopy

In pelitic schists composed mainly of quartz and albite grains, the morphology of intergranular pores, which were filled with water, was studied by transmission electron microscopy (TEM). Although some pores are defined by crystallographic planes (F-face), most of their form has an ideal shape determined by interface tensions between grains and fluid. High-resolution TEM observations demonstrate that pore-free regions at grain boundaries are tight even at the nanometer scale, showing that the wetting angle is larger than 0° in this rock. The pore distribution in two-grain junctions can be compared to a "necklace microstructure" developed by instability of a fluid film along the boundary induced by microcracking. Wetting angles for pores located at grain edges of quartz and albite decrease in the order albite/albite, quartz/quartz, and quartz/albite. The quartz/quartz wetting angle in a calcite-free sample is smaller than that in a calcite-containing sample. This angle also changes due to grain misorientation. Our results confirm that solid-solid and solid-fluid interfacial energies control the geometry of intergranular fluid in natural rocks.     

Biogeochemical evidence of large diapycnal diffusivity associated with the subtropical mode water of the North Pacific

A profiling float equipped with a fluorimeter, a dissolved oxygen (DO) sensor, and temperature and salinity sensors was deployed in the subtropical mode water (STMW) formation region of the North Pacific. It acquired quasi-Lagrangian, 5-day-interval time-series records from March to July 2006. The time-series distribution of chlorophyll showed a sustained and sizable subsurface maximum at 50–100 m, just above the upper boundary of the STMW, throughout early summer (May–July). The DO concentration in this lower euphotic zone (50–100 m) was almost constant and supersaturated in the same period, becoming more supersaturated with time. On the other hand, the DO concentration at 100–150 m near the upper boundary of the STMW decreased much more slowly compared with the main layer of STMW below 150 m, even though oxygen consumption by organisms was expected to be larger in the former depth range. The small temporal variations of DO in the lower euphotic zone and near the upper boundary of the STMW were reasonably explained by downward oxygen transport because of large diapycnal diffusion near the top of the STMW. Assuming that the oxygen consumption rate at 100–150 m was the same as that in the main layer of STMW and compensated by the downward oxygen flux, the diapycnal diffusivity was estimated to be 1.7 × 10⁻⁴ m² s⁻¹. Nitrate transport into the euphotic zone by the same large diffusion was estimated to be 0.8 mmol N m⁻² day⁻¹. All of the transported nitrate could have been used for photosynthesis by the phytoplankton; net community production was estimated to be 5.3 mmol C m⁻² day⁻¹.