Sampling uncertainties and source <Emphasis Type="Italic">b</Emphasis> likelihood for the Gutenberg-Richter <Emphasis Type="Italic">b</Emphasis> value from the Aki-Utsu method

The Aki-Utsu method of Gutenberg-Richter (G-R) b value estimation is often misapplied so that estimations not using the G-R histogram are often meaningless because they are not based on adequate samples. We propose a method to estimate the likelihood Pr(b?b _m , N, M ₁, M ₂) that an observed b _m estimate, based on a sample of N magnitudes within an [M ₁????≤?ΔM/2,?M ₂?+?ΔM/2) range, where ΔM?=?0.1 is the usual rounding applied to magnitudes, is due to a “true” source b value, b, and use these likelihoods to estimate source b ranges corresponding to various confidence levels. As an example of application of the method, we estimate the b values before and after the occurrence of a 7.4-magnitude earthquake in the Mexican subduction zone, and find a difference of 0.82 between them with 100% confidence that the b values are different.     

Removal of Pyridine from Aqueous Solution by Adsorption on an Activated Carbon Cloth

Pyridine is a very toxic pollutant that has to be removed from wastewater. In this work, adsorption of pyridine on activated carbon cloth (ACC) is studied as a possible alternative for eliminating pyridine from aqueous solution. The ACC was produced from polyacrylonitrile. The adsorption equilibrium data of pyridine on ACC was obtained in a batch adsorber. The experimental data was interpreted with the isotherms of Langmuir, Freundlich, and Prausnitz‐Radke (PR), and the PR isotherm better represented the experimental data. The capacity of ACC for adsorbing pyridine was favored increasing the solution pH from 3 to 6, and this effect was due to the π–π dispersive and electrostatic interactions between the pyridine species in solution and the surface complexes of ACC. The modified Langmuir model fitted reasonably well the influence of pH on the adsorption capacity. In this model was assumed that both neutral pyridine and pyridinium were simultaneously adsorbed on ACC accordingly to the experimental results. The adsorption capacity was almost independent of temperature. The reversibility study revealed that 75% of the pyridine can be desorbed from ACC indicating that part of the pyridine was irreversibly adsorbed, and possibly chemisorbed.     

Sky luminance distribution in Pamplona (Spain) during the summer period

In this work the outdoor daylight conditions in Pamplona (South Europe) during the summer period have been studied. The selected sky type (from fifteen standards) at a given moment is the one exhibiting the lowest RMSD when comparing the theoretical and experimental luminance distributions in the sky hemisphere. Two year data of luminance distribution registered every 10 min in 145 positions of the sky hemisphere have been used for selecting the sky type. The most frequent sky type in Pamplona is V.5 (cloudless polluted with a broad solar corona), with an occurrence of 29.5%. This result coincides with the one observed in a previous study in Athens.Six types of sky (V.5, IV.4, III.4, III.3, V.4 y II.2) out of the fifteen standards become practically the 80% of all the studied ones. Regarding a possible use in daylight climate studies, the frequency of occurrence of the fifteen types of sky for fourteen solar elevation intervals has been included.     

Undocumented Students’ Narratives of Liminal Citizenship: High Aspirations,Exclusion, and “In-Between” Identities

This study illustrates how national immigration policy relegates undocumented immigrant children to spaces of liminal citizenship, which shape their aspirations for higher education. Recognizing the power of migrant narratives, and the importance of privileging youths’ voices through children's geographies, we present the narratives of undocumented high school students from several rural North Carolina communities. Despite various barriers facing undocumented students, most have high academic aspirations. Students construct new forms of citizenship, legitimating their claims to higher education access through their achievement. Their liminal status, however, contributes to the formation of conflicted, “in-between” identities.     

Paleosol geochemistry of the late Paleocene Goler Formation of Southern California

Paleosol (fossilized soil) geochemistry can provide a record of paleoclimatic conditions due to the relationships between pedogenic processes and climate. In this study, paleosols from the late Paleocene Goler Formation of Southern California were used to determine the paleoclimatic conditions active during pedogenesis. The enrichment and retention of soluble elements (Ca, Mg and Na) and the mobilization of Fe and Mn within the paleosol profiles suggest a climate with strongly seasonal precipitation. Similarly, variations in the Mn content and δ¹³C ratio of pedogenic carbonate nodules also reflect seasonal precipitation. Regional paleotopography was likely an important control on the paleoclimate of the Goler Formation due to rain shadow effects. Although the size and location of these ancient mountains are poorly constrained, the identification of climatic effects specifically associated with these variables provides new constraints.     

Detection of the old stellar component of the major Galactic bar

We present near-infrared colour–magnitude diagrams and star counts for a number of regions along the Galactic plane. It is shown that along the l =27°, b =0° line of sight there is a feature at 5.7±0.7 kpc with a density of stars at least a factor of 2 and probably more than a factor of 5 times that of the disc at the same position. This feature forms a distinct clump on an H versus J − H diagram and is seen at all longitudes from the bulge to about l =28°, but at no longitude greater than this. The distance to the feature at l =20° is about 0.5 kpc further than at l =27°, and by l =10° it has merged with, or has become, the bulge. Given that at l =27° and l =21° there is also a clustering of very young stars, the only component that can reasonably explain what is seen is a bar with half-length of around 4 kpc and a position angle of about 43°±7°.     

A warm-season comparison of WRF coupled to the CLM4.0, Noah-MP,and Bucket hydrology land surface schemes over the central USA

In climate modeling studies, there is a need to choose a suitable land surface model (LSM) while adhering to available resources. In this study, the viability of three LSM options (Community Land Model version 4.0 [CLM4.0], Noah-MP, and the five-layer thermal diffusion [Bucket] scheme) in the Weather Research and Forecasting model version 3.6 (WRF3.6) was examined for the warm season in a domain centered on the central USA. Model output was compared to Parameter-elevation Relationships on Independent Slopes Model (PRISM) data, a gridded observational dataset including mean monthly temperature and total monthly precipitation. Model output temperature, precipitation, latent heat (LH) flux, sensible heat (SH) flux, and soil water content (SWC) were compared to observations from sites in the Central and Southern Great Plains region. An overall warm bias was found in CLM4.0 and Noah-MP, with a cool bias of larger magnitude in the Bucket model. These three LSMs produced similar patterns of wet and dry biases. Model output of SWC and LH/SH fluxes were compared to observations, and did not show a consistent bias. Both sophisticated LSMs appear to be viable options for simulating the effects of land use change in the central USA.     

TPH and PAH concentrations in the subsoil of polyduct segments, oil pipeline pumping stations, and right-of-way pipelines from Central Mexico

For the year 1996, 366 incidents related with clandestine poaching of oil-products were reported in Mexico, 159 in 1997, and 240 in 1998. For the year 2003 (the most recently reported figure), there were 136 events. Petroleos Mexicanos (PEMEX), very concerned with the environmental agenda, has developed programs oriented to diminish contamination levels in all of its oil facilities. This work was aimed at characterizing zones around polyduct segments, pipelines, pumping stations, and right-of-way pipelines located in the center of Mexico. The TPH contaminated sites were, in decreasing order, polyduct km 39 + 150 > polyduct km 25 + 020 > Zoquital > Tepetitlan > Catalina > Venta Prieta > Ceiba. Most of the sampled points showed the presence of more than one of the 16 PAHs considered by USEPA as priority pollutants. Except point TEPE 2A, where no PAHs were detected, all the sampled points showed values from low to medium concentrations; however, values found at the sites did not exceed the limits according to the Mexican or the American legislation. The place with the largest contaminated area corresponded to the polyduct km 39 + 150, with 130 m² and 260 m³ to be treated. The least contaminated area was that around the JUAN 4 point at Juandho station, with 20 m² and 22 m³ of contaminated soil. The total area to be treated is about 230 m² and 497 m³.