Episodic fluid migration in the Fennoscandian Shield recorded by stable isotopes, rare earth elements and fluid inclusions in fracture minerals at Forsmark, Sweden

Drilling through the Palaeoproterozoic bedrock at Forsmark, central Sweden, during the site investigation for a potential geological repository of highly radioactive nuclear waste has provided high quality drill-core material from the upper 1 km of the Fennoscandian Shield. Analyses of stable isotopes (δ¹³C, δ¹⁸O, δ³⁴S, ⁸⁷Sr/⁸⁶Sr), rare earth elements and fluid inclusions in fracture filling calcite and pyrite from these drill cores have resulted in the discrimination of several episodes of fracture mineralisations. These events represent migration of fluids during a wide range of conditions, ranging from high-temperature hydrothermal to present-day groundwater circulation. Four major events have been distinguished: 1) Precipitation of epidote, chlorite and quartz under hydrothermal conditions (T > 150–200 °C) during the Proterozoic, sometime between 1.8 and 1.1 Ga. 2) Hydrothermal circulation at temperatures close to 200 °C with precipitation of adularia, albite, prehnite, laumontite, calcite and chlorite. Most of these minerals precipitated during a tectonothermal event between 1.1 and 1.0 Ga, possibly in response to far-field effects of the Sveconorwegian orogeny. 3) Precipitation of mainly quartz, calcite, pyrite and asphaltite occurred during the Palaeozoic, at temperatures between 60 and 190 °C (mainly at < 100 °C). Mixing of a fluid emanating from an organic rich overlying sedimentary cover and a deep basinal fluid from the crystalline bedrock is suggested to have caused this precipitation, possibly as a far-field response to the Caledonian orogeny and/or the development of the Caledonian foreland basin. 4) The youngest generation of fracture minerals is associated with formation of clay minerals and calcite with minor occurrences of pyrite and goethite. These minerals have probably precipitated episodically during a long time period (possibly from the Late Palaeozoic to the present) from various fluids at low temperature conditions (< 50 °C). Few calcites in equilibrium with the present groundwater suggest that the ongoing precipitation of calcite is very limited.     

Reaction induced fracturing during replacement processes

Replacement processes are common transformation mechanisms in minerals and rocks at a variety of conditions and scales. The underlying mechanisms are, in general, poorly understood, but both mechanical and chemical processes are thought to be important. Replacement of leucite (KAlSi₂O₆) by analcime (NaAlSi₂O₆ ^.H₂O) is common in silica-poor igneous rocks. A 10% increase in volume is associated with the replacement process, and this generates stresses that eventually cause fracturing of the reacting leucite. Experimentally reacted leucite samples display characteristic fracturing patterns that include both spalling of concentric ‘onion-skin’-like layers near the reacting interface and the formation of cross-cutting, often hierarchically arranged, sets of fractures that divide the remaining leucite into progressively smaller domains. These structures may explain the ‘patchy’ alteration patterns observed in natural leucite samples and similar, so-called, mesh-textures associated with the serpentinization of olivine grains during hydration of mafic or ultramafic rocks. They are also strikingly similar to larger scale patterns formed during spheroidal weathering processes. A simple discrete element model illustrates the mechanics that control the formation of such systems, and shows how these replacement processes may be accelerated due to the generation of new reactive surface area by hierarchical fracturing processes.     

Holocene evolution of a drowned melt-water valley in the Danish Wadden Sea

Cores from the salt marshes along the drowned melt-water valley of river Varde Å in the Danish Wadden Sea have been dated and analysed (litho- and biostratigraphically) to reconstruct the Holocene geomorphologic evolution and relative sea level history of the area. The analysed cores cover the total post-glacial transgression, and the reconstructed sea level curve represents the first unbroken curve of this kind from the Danish Wadden Sea, including all phases from the time where sea level first reached the Pleistocene substrate of the area. The sea level has been rising from − 12 m below the present level at c. 8400 cal yr BP, interrupted by two minor drops of < 0.5 m at c. 5500 cal yr BP and 1200 cal yr BP, and one major drop of ∼ 1.5 m at c. 3300 cal yr BP. Sediment deposition has been able to keep pace with sea level rise, and the Holocene sequence consists in most places of clay atop a basal peat unit overlying sand of Weichselian age and glacio-fluvial origin. In its deepest part, the basal peat started to form around 8400 cal yr BP, and reached a thickness of up to 3.5 m. This thickness is about half of the original, when corrected for auto-compaction. The superimposed clay contains small (63-355 μm) red iron stains in the top and bottom units, and foraminifers of the calcareous type in the middle. The fact that iron stains and foraminifers in no cases coexist, but always exclude each other is interpreted as a result of the difference between salt-marsh facies (iron stains) and tidal-flat facies (foraminifers). This represents a novel and easy way to distinguish between these two otherwise often undistinguishable sedimentary facies in the geological record.     

Numerical Analysis of the 650,000 m<Superscript>2</Superscript> Åknes Rock Slope based on Measured Displacements and Geotechnical Data

The unstable 650,000 m² Åknes rock slope (Western Norway) poses a hazard, as a sudden failure may cause a destructive tsunami in the fjord. In this study the slope was divided into blocks based on displacements measured at the slope surface. Discontinuous deformation analysis (DDA) showed that three or four blocks in the upper half may be considered as potential subareas that may fail catastrophically. The lower half may be divided into two or three blocks, but more limited data introduces more uncertainty into block definition. The Universal Distinct Element code (UDEC) was used for two-dimensional (2D) stability analyses. By varying fracture geometry, fracture friction, and groundwater conditions within reasonable limits based on site-specific data a number of possible models were compared. The conclusions show that models that were unstable to great depths were in closer agreement with shear strength parameters derived from an earlier study than models that were unstable to smaller depths. The length (depth) of the outcropping fracture, along which shear displacements are shown to occur, plays an important role. A (shallow) slide at 30 m, in which displacements have been documented by borehole measurements, will reduce the stability at greater depths. Increased groundwater pressure is demonstrated to be less critical for very deep slope instability. The results of the DDA and UDEC modelling will be useful for planning of future investigations, interpretation of the subsequent results, further development of the early warning system and in the tsunami modelling.     

Heavy-metal pollution of sediments from the Polish exclusive economic zone,southern Baltic Sea

Analysis of 59 surface sediment samples from the Polish exclusive economic zone (EEZ) shows that Szczecin Lagoon sediments are the most polluted by heavy metals and that the degree of heavy-metal pollution decreases substantially on passing from the Szczecin Lagoon to the Pomeranian Bay and the inner shelf area and then on passing to the Bornholm Deep and Słupsk Furrow. Heavy-metal pollution in the sediments of the western part of the Polish EEZ therefore appears to follow the dispersion of the Oder River. Fluffy material from the Oder estuary appears to be the main source of heavy metals in the muddy sediments of the Bornholm Deep. The formation of sulphides is therefore not the principal factor controlling the enrichment of heavy metals in the sediments of this anoxic basin, although it may be responsible for the uptake of Mo, Sb and As. Two main factors control the distribution of the rare earth elements (REE) in sediments of the Polish EEZ: the input of Fe-organic colloids from rivers and the presence of detrital material in the sediments.     

Trends in chronic marine oil pollution in Danish waters assessed using 22 years of beached bird surveys

Beached bird surveys provide an important tool for monitoring the level of oil pollution at sea, which is the most significant observable cause of death for a large number of waterbird species and pose a serious threat to wintering seabird populations. Linear regression analyses of oil rates from the Danish 22 year dataset show a decline in the oil pollution level in offshore areas of the eastern North Sea and Skagerrak and in near-shore parts of the Kattegat; but a worsening in the offshore areas of the Kattegat. These results raise concern for species such as common scoter, velvet scoter, eider and razorbill, for which the Kattegat serves as a globally important wintering area. It is recommended that surveillance for oil spills is intensified in inner Danish waters, and that action is taken to make responses towards offenders faster, and penalties for oil seepage higher.     

Non-gravitational force modeling of Comet 81P/Wild 2: I. A nucleus bulk density estimate

The nucleus of Comet 81P/Wild 2 is modeled by assuming various smooth triaxial ellipsoidal or irregular body shapes, having different rotational periods, spin axis orientations, and thermophysical properties. For these model nuclei, a large number of surface activity patterns (e.g., maps of active and inactive areas) are studied, and in each case the resulting water production rate and non-gravitational force vector versus time are calculated. By requiring that the model nuclei simultaneously reproduce certain properties of the empirical water production curve and non-gravitational changes of the orbit (focusing on changes of the orbital period and in the longitude of perihelion), constraints are placed on several properties of the nucleus. The simulations suggest that the mass of Comet 81P/Wild 2 is , resulting in a rather low bulk density, (depending on the assumed nucleus volume), and that the nucleus rotation is prograde rather than retrograde. The active area fraction is difficult to constrain, but at most 60% of the nucleus is likely to have near-surface ice.     

Oxygen-enhanced biodegradation of phenoxy acids in ground water at contaminated sites

The effects of adding oxygen to anaerobic aquifer materials on biodegradation of phenoxy acid herbicides were studied by laboratory experiments with aquifer material from two contaminated sites (a former agricultural machinery service and an old landfill). At both sites, the primary pollutants were phenoxy acids and related chlorophenols. It was found that addition of oxygen enhanced degradation of the six original phenoxy acids and six original chlorophenols. Inverse modeling on 14C 4-chloro-2-methylphenoxypropanoic acid (MCPP) degradation curves revealed that increasing the oxygen concentrations from <0.3 mg/L up to 7 to 8 mg/L shortened the lag phases (from approximately 150 d to 5 to 25 d) and increased first-order degradation rate constants by 1 order of magnitude (from approximately 5 x 10(-2) d(-1) to up to 30 x 10(-2) d(-1)). Additionally, the degree of MCPP mineralization was increased (30% to 50% mineralized at low oxygen concentrations and 50% to 70% mineralized at high oxygen concentrations, based on 14CO2 recovery). These positive effects on degradation were observed even at relatively low oxygen concentrations (2 mg/L). Furthermore, effects related to the addition of oxygen on the general geochemistry were studied. An oxygen consumption of 2.2 to 2.6 mg O2/g dw was observed due to oxidation of solid organic matter and, to some extent (0.5% to 11% of the total oxygen consumption), water-soluble compounds such as Fe2+, dissolved Mn, nonvolatile organic carbon, and NH4+. Overall, the results suggest that stimulated biodegradation by addition of oxygen might be a feasible remediation technology at herbicide-contaminated sites, although oxygen consumption by the sediment could limit the applicability.     

A Mixed Spectral-Integration Model for Neutral Mean Wind Flow Over Hills

A linear model for neutral surface-layer flow over orography is presented. The Reynolds-Averaged Navier-Stokes and E– turbulence closure equations are expressed in a terrain-following coordinate system created from a simple analytical expression in the Fourier domain. The perturbation equations are solved spectrally horizontally and by numerical integration vertically. Non-dimensional solutions are stored in look-up tables for quick re-use. Model results are compared to measurements, as well as other authors’ flow models in three test cases. The model is implemented and tested in two-dimensional space; the equations for a full three-dimensional version are presented.