Effect of grain scale alignment on seismic anisotropy and reflectivity of shales

The elastic properties and anisotropy of shales are strongly influenced by the degree of alignment of the grain scale texture. In general, an orientation distribution function (ODF) can be used to describe this alignment, which, in practice, can be characterized by two Legendre coefficients. We discuss various statistical ODFs that define the alignment by spreading from a mean value; in particular, the Gaussian, Fisher and Bingham distributions. We compare the statistical models with an ODF resulting from pure vertical compaction (no shear strain) of a sediment. The compaction ODF may be used to estimate how the elastic properties and anisotropy evolve due to burial of clayey sediments. Our study shows that the three statistical ODFs produce almost identical correspondence between the two Legendre coefficients as a function of the spreading parameter, so that the spreading parameter of one ODF can be converted to the spreading parameter of another ODF. In most cases it is then sufficient to apply the spreading parameter for the ODF instead of the two Legendre coefficients. The effect of compaction on the ODF gives a slightly different correspondence between the two Legendre coefficients from that for the other models. In principle, this opens up the possibility of distinguishing anisotropy effects due to compaction from those due to other processes. We also study reflection amplitudes versus angle of incidence (AVA) for all wave modes, where shales having various ODFs overlie an isotropic medium. The AVA responses are modelled using both exact and approximation formulae, and their intercepts and gradients are compared. The modelling shows that the S‐wave velocity is sensitive to any perturbation in the spreading parameter, while the P‐wave velocity becomes increasingly sensitive to a perturbation of a less ordered system. Similar observations are found for the AVA of the P‐P and P‐SV waves. Modelling indicates that a combined use of the amplitude versus offset of P‐P and P‐SV reflected waves may reveal certain grain scale alignment properties of shale‐like rocks.     

Relationships between morphological and sedimentological parameters in source‐to‐sink systems: a basis for predicting semi‐quantitative characteristics in subsurface systems

The study of source‐to‐sink systems relates long‐term variations in sediment flux to morphogenic evolution of erosional–depositional systems. These variations are caused by an intricate combination of autogenic and allogenic forcing mechanisms that operate on multiple time scales – from individual transport events to large‐scale filling of basins. In order to achieve a better understanding of how these mechanisms influence morphological characteristics on different scales, 29 submodern source‐to‐sink systems have been investigated. The study is based on measurements of morphological parameters from catchments, shelves and slopes derived from a ∼1 km global digital elevation model dataset, in combination with data on basin floor fans, sediment supply, water discharge and deposition rates derived from published literature. By comparing various morphological and sedimentological parameters within and between individual systems, a number of relationships governing system evolution and behaviour are identified. The results suggest that the amount of low‐gradient floodplain area and river channel gradient are good indicators for catchment storage potential. Catchment area and river channel length is also related to shelf area and shelf width, respectively. Similarly to the floodplain area, these parameters are important for long‐term storage of sediment on the shelf platform. Additionally, the basin floor fan area is correlative to the long‐term deposition rate and the slope length. The slope length thus proves to be a useful parameter linking proximal and distal segments in source‐to‐sink systems. The relationships observed in this study provide insight into segment scale development of source‐to‐sink systems, and an understanding of these relationships in modern systems may result in improved knowledge on internal and external development of source‐to‐sink systems over geological time scales. They also allow for the development of a set of semi‐quantitative guidelines that can be used to predict similar relationships in other systems where data from individual system segments are missing or lacking.     

Levels of Organohalogenated Pollutants in Human Milk Samples from Konya City,Turkey

This study reports the levels of organochlorine pesticides (OCPs, α‐, β‐, γ‐ and Δ‐HCHs, p,p′‐DDE, p,p′‐DDD and p,p′‐DDT), polychlorinated biphenyls (PCBs, PCB 28, 52, 101, 153, 138 and 180 congeners) and polybrominated diphenyl ethers (PBDEs, PBDE 47, 99, 100, 153 and 154 congeners) in 45 individual human milk samples collected from Konya City, Turkey. Average concentrations of ΣHCHs, ΣDDTs, ΣPCBs and ΣPBDEs were 22.62, 37.10, 104.95 and 67.34 ng/g lipid wt., respectively. No significant differences in investigated pollutants were found between primiparous and multiparous mothers. There was no correlation between levels of each group of pollutants in human milk and the age of mothers. Moreover, there was no significant difference in the levels of ΣDDTs, between mothers who have eaten fish more than once a week and those who consumed fish less than once. An analysis of the infant exposure to DDTs, HCHs and PCBs via mother's milk indicated that the estimated daily intakes of these pollutants were below the guideline proposed by the World Health Organization (WHO) and the Health Canada which means that there is definitely no concern on children health.     

Species-dependent sensitivity to contaminants: an approach using primary hepatocyte cultures with three marine fish species

There is limited knowledge about the sensitivity of different fish species to environmental pollutants. Such information is pivotal in risk assessment and to understand why some species appear to be more tolerant to contaminants than others. The aim of the current study was to evaluate whether primary hepatocyte cultures of three marine fish species could be established in the field and whether their sensitivity to selected contaminants would differ. Primary hepatocyte cultures of three marine fish species (plaice, long rough dab, Atlantic cod) were established and exposed for 24 h to copper (20-2500 mg L?1) and statins (1-200 mg L?1). Endpoints were esterase activity, metabolic activity and reduced glutathione (GSH) content, all using fluorescent probes. Flatfish hepatocytes were more susceptible to copper and statin exposure than hepatocytes from cod. This study has shown that species-dependent differences in contaminant sensitivity can be investigated using primary hepatocyte cultures.     

Source‐to‐sink analysis of ancient sedimentary systems using a subsurface case study from the Møre‐Trøndelag area of southern Norway: Part 1 – depositional setting and fan evolution

In this study, we use seismic reflection, well and core data to investigate the role that basin physiography and sediment routing systems played on the distribution, geometry and stratigraphic architecture of Upper Cretaceous submarine fans (SF) offshore Norway. The Late Cretaceous Møre‐Trøndelag margin of western Norway was characterised by steep submarine slopes (gradient of ~0.3°–3°). Mudstones dominate the Upper Cretaceous slope succession, although a few regionally extensive, sandstone‐dominated units are developed. We focus on the most regionally extensive sandstone unit, which is of Late Turonian‐to‐Early Coniacian age. Mapping and visualisation of 2D and 3D seismic reflection data and analysis of well data indicates that the sandstone unit comprises a total of 11 SF, which were fed by sand‐rich sediment gravity flows routed through multiple upper slope canyons. Based on the internal organisation of seismic facies, four fan types have been identified: (i) Type Ia fans, which are characterised by <10 erosional channel complexes at their bases and aggradational to landward‐stepping lobes in their upper parts; (ii) Type Ib fans, which are characterised by >10 erosional channel complexes at their bases and aggradational to landward‐stepping lobe and mass‐transport deposits near the fan apex in their upper parts; (iii) Type II fans, which are dominated by aggradational lobe deposits; and (iv) Type III fans, which are dominated by a single channel complex that passes downdip into a small terminal lobe. The different fan types are interpreted to reflect variable stratigraphic responses to source proximity and basin physiography, which is principally related to the degree of local fault reactivation and differential compaction. This variability highlights the diversity of fan types that may occur over short distances along continental margins, and demonstrates the importance of local controls in understanding the internal stratigraphic variability that may be present in deep‐marine successions.     

The combined effect of copper and hydrocarbons on the length growth of Mytilus edulis

The combined effect of copper and North Sea crude oil is tested on juvenile Mytilus edulis. Dissolved CuSO₄ x 5H₂O is added to the seawater in concentrations of 3 and 6 μg Cu litre^-1. Crude oil, microencapsulated in a gelatine/acacia structure, is added in concentrations of 1·5 and 3·0 mg oil litre^-1. The shell length growth is measured every 24 h with laser diffraction. Linear effects were observed for single components within 24 h of exposure and significant antagonistic interaction appeared within 48 h. Reduced growth rate coincided with reduced filtering and defaecation, and reduced byssus production.     

Element concentrations and variations along a 120-km transect in southern Norway – Anthropogenic vs. geogenic vs. biogenic element sources and cycles

Rock samples and the C-, B- and O-horizons of soils developed on these rocks were collected in forested areas along a 120-km south–north transect in southern Norway, passing through the city of Oslo. Forty samples (1 site/3 km) were analysed for 37 chemical elements (Ag, Al, As, Au, B, Ba, Bi, Ca, Cd, Co, Cr, Cu, Fe, Ga, Hg, K, La, Mg, Mn, Mo, Na, Ni, P, Pb, S, Sb, Sc, Se, Sr, Te, Th, Ti, Tl, U, V, W and Zn) following an aqua regia digestion; pH (water extract) and loss on ignition were also determined. The O-horizon soils were additionally analysed for Pt. Gold is the only element that shows a clear anthropogenic peak in the O-horizon soils collected from the city of Oslo. Silver, Au, Bi, Cd, Hg, Pb, S, Sb, Se and Sr all show a strong enrichment in the O-horizon when compared to the underlying C-horizon or the bedrock along the full length of the transect. Neither geology nor anthropogenic input of elements dominate the observed patterns. The most important factors for the observed element concentrations in the O-horizon are weathering, uptake (or rejection) of elements by plants and the kinetics of decay of the organic material in the O-horizon. Climate, especially temperature and precipitation, has an important influence on the formation and decay rates of the organic soil layer. Acid precipitation will delay the decomposition of the organic layer and lead to a natural enrichment of several metals in the O-horizon. Land use change, deforestation and liming can all increase the decay kinetics of organic matter and thus result in a release of the stored element pool.     

Optimization of sub-band coding method for seismic data compression

Seismic data volumes, which require huge transmission capacities and massive storage media, continue to increase rapidly due to acquisition of 3D and 4D multiple streamer surveys, multicomponent data sets, reprocessing of prestack seismic data, calculation of post‐stack seismic data attributes, etc. We consider lossy compression as an important tool for efficient handling of large seismic data sets. We present a 2D lossy seismic data compression algorithm, based on sub‐band coding, and we focus on adaptation and optimization of the method for common‐offset gathers. The sub‐band coding algorithm consists of five stages: first, a preprocessing phase using an automatic gain control to decrease the non‐stationary behaviour of seismic data; second, a decorrelation stage using a uniform analysis filter bank to concentrate the energy of seismic data into a minimum number of sub‐bands; third, an iterative classification algorithm, based on an estimation of variances of blocks of sub‐band samples, to classify the sub‐band samples into a fixed number of classes with approximately the same statistics; fourth, a quantization step using a uniform scalar quantizer, which gives an approximation of the sub‐band samples to allow for high compression ratios; and fifth, an entropy coding stage using a fixed number of arithmetic encoders matched to the corresponding statistics of the classified and quantized sub‐band samples to achieve compression. Decompression basically performs the opposite operations in reverse order. We compare the proposed algorithm with three other seismic data compression algorithms. The high performance of our optimized sub‐band coding method is supported by objective and subjective results.     

Chromatographic Separation and Analytic Procedure for Priority Organic Pollutants in Urban Air

A separation procedure was developed for analysis of polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs) in urban air, while simultaneously eliminating the interfering compounds. This was carried out by optimization of a column chromatograph with regard to the eluent type (n‐hexane and n‐pentane), volume of eluent, type of sorbent material (silica gel and florisil) and activation level of the sorbent material. The determination of the level of PCBs and PAHs was carried out using gas chromatography (GC) equipped with a mass selective detector (MSD), while determination of the OCPs was carried out by GC equipped with an electron capture detector (μ‐ECD). The use of a silica gel column (10 g, 5% deactivated with H₂O) with 70 mL of n‐hexane gave satisfactory separation of PCBs from PAHs and OCPs. After collecting the PCBs with 70 mL of n‐hexane, 3·20 mL of n‐hexane:ethyl acetate, (1:1, v:v) was adequate for elution of the PAHs and OCPs from the column. The primary aim of this study was to develop a multimethod for analyses of PCBs, PAHs, and OCPs in urban air as well as reducing solvent and sorbent consumption and analysis time during the clean‐up procedure compared to the US EPA standard methods (EPA methods TO‐13A for PAHs and TO‐4A for both PCBs and OCPs).