CHEMICAL ALTERATIONS OF THE HOLBROOK CHONDRITE RESULTING FROM TERRESTRIAL WEATHERING

The effects of chemical weathering on the Holbrook, Arizona chondrite were studied via major, minor, and trace element analysis along with noble gas measurements. Three samples of Holbrook were studied: a fresh specimen which fell in 1912, a specimen collected in 1931 and a specimen collected in 1968. The weathering of the meteorite produced changes in the Fe and Mg concentrations. The amount of metallic iron decreases with increasing degree of weathering. The MgO content decreases and the total iron content increases slightly with increasing weathering of the specimen, but these concentration differences are not necessarily due to weathering. Elemental concentrations for Ti, Ca, Al, P, Mn, Ni and Cr did not change significantly during weathering. Sodium may have been lost during weathering, whereas K showed a slight enrichment in abundance with terrestrial age. Trace elements C, Rb and Sr increased at least two-fold during weathering of the meteorite. Abundances of the radiogenic and cosmogenic noble gases decreased with increasing terrestrial age. Concentration ratios of certain cosmogenic noble gas nuclides which are commonly used as indicators of gas loss and shielding in chondrites show unpredictable behavior in the weathered chondrite.     

Seasonal fluctuations and compositions of two populations of small demersal fishes on the west coast of Scotland

The soft sediment fish communities below 20 m depth were studied at two sites on the west coast of Scotland (Irvine Bay, Firth of Clyde and the Lynn of Lorne) using small meshed beam trawls. In both cases the emphasis was on the small demersal fish (<15 cm) within these communities. The Irvine Bay community was studied between May 1978 and December 1979 and the Lynn of Lorne community between February 1975 and October 1976.Twenty-seven fish species were recorded in Irvine Bay and 32 in the Lynn of Lorne. In both communities four species constituted more than 78% of the total annual abundance, two gobies (Lesueurigobius friesii and Pomatoschistus norvegicus) were high in the dominance ranking for both sites. The species abundance lists were similar for both sites (0·62 level of similarity) but the species lists for each site were different (0·36 level of similarity). The overall mean density of small demersal fish was similar for both sites (Irvine Bay = 0·045 individuals m^?2 and the Lynn of Lorne = 0·047 individuals m^?2). There were two periods of high abundance for both communities (late autumn to winter and late spring). There was, however, a low repeatability between successive years. The species richness (D) was relatively high (Irvine Bay = 1·5-3·08, Lynn of Lorne = 1·4-3·34) as was the species diversity (H′) (Irvine Bay = 1·17-1·97, Lynn of Lorne = 1·23-1·95). The proportional representation ($\text{J′}$) of each species within the community was greater in Irvine Bay ($\text{J′}$ = 0·57-0·77) than in the Lynn of Lorne ($\text{J′}$ = 0·50-0·72). Therefore these two communities of small demersal fish appeared to be similar at the community level but the way in which this was achieved was different.     

兴文天坑的崩塌过程

四川兴文喀斯特包括小岩湾天坑和大岩湾退化天坑,以及猪槽井洞穴系统中潜在的洞穴崩塌大厅.这3个地方似乎可以说明天坑的演化顺序,即天坑从多重洞穴崩塌,到最后退化成大型漏斗的过程.     

The melt rocks of the Vredefort impact structure - Vredefort Granophyre and pseudotachylitic breccias: Implications for impact cratering and the evolution of the Witwatersrand Basin

The unique combination of its large size (250-300 km diameter), deep levels of erosion (>7 km), and widespread regional mining activity make the Vredefort impact structure in South Africa an exceptional laboratory for the study of impact-related deformation phenomena in the rocks beneath giant, complex impact craters. Two types of impact-generated melt rock occur in the Vredefort Structure: the Vredefort Granophyre - impact melt rock - and pseudotachylitic breccias. Along the margins of the structure, mining and exploration drilling in the Witwatersrand goldfields has revealed widespread fault-related pseudotachylitic breccias linked to the impact event. There, volumetrically limited melt breccia occurs in close association with cataclasite or mylonitic zones associated with bedding-parallel normal dip-slip faults that formed during inward slumping of the crater walls, and in rare subvertical faults oriented radially to the center of the structure. This association is consistent with formation of pseudotachylites by frictional melting. On the other hand, rocks in the Vredefort Dome - the central uplift of the impact structure - contain ubiquitous melt breccias that range in size from sub-millimeter pods and veinlets to dikes up to tens of meters wide and hundreds of meters long. Like fault-related pseudotachylites in the goldfields and elsewhere in the world, they display a close geochemical relationship to their wallrocks, indicating local derivation. However, although mm/cm- to, rarely, dm-scale offsets are commonly found along their margins, they do not appear to be associated with broader fault zones, are commonly considerably more voluminous than most known fault-related pseudotachylites, and show no consistent relationship between melt volumes and slip magnitude. Recent petrographic observations indicate that at least some of these melt breccias formed by shock melting, with or without frictional melting. Consequently, the non-genetic term “pseudotachylitic breccia” has been adopted for these Vredefort occurrences. These breccias formed during the impact in rocks at temperatures ranging from greenschist to granulite facies, and were subsequently annealed to varying degrees during cooling of the central uplift.In addition to the pseudotachylitic breccias, nine clast-laden impact melt dikes (Vredefort Granophyre), each up to several kilometers long, occur in vertical radial and tangential fractures in the Vredefort Dome. Unlike the pseudotachylitic breccias, they display a remarkably uniform bulk composition and clast populations that are largerly independent of their wallrocks, and they contain geochemical traces of the impactor. They represent intrusive offshoots of the homogenized impact melt body that originally lay within the crater. U-Pb single zircon and Ar-Ar dating indicates that the Vredefort Granophyre and pseudotachylitic breccias, and the Witwatersrand pseudotachylites all formed at 2020±5 Ma - the age of the impact event, making the breccias a convenient time marker in the evolution of the structurally complex Witwatersrand basin with its unique gold deposits.     

Trace-element data relevant to the origin of trachytic and pantelleritic lavas in the East African Rift system

Determination of the trace-elements Ba, Ce, La, Nb, Rb, Sr and Zr have been made on lavas from six trachytic and pantelleritic volcanoes in the Kenyan and Ethiopian Rifts. Consideration of these data shows that Ce, La, Nb and Zr have behaved as truly residual elements. In the peralkaline suites examined, plotting other chemical parameters against a residual-element such as Zr appears to be informative. The individual residual-element ratios are constant at any one volcano suggesting that the salic and basic lavas are geochemieally related and that the trachytes and pantellerites do not have an origin independent of the associated basalts.Different values of individual residual-element ratios characterize different groups of volcanic centres. In the northern part of the Kenyan Rift, progressive change in these ratios with time can be traced.In the salic lavas, Ba and Sr show patterns of extreme depletion relative to the alkali basalts and these data suggest that the salic rocks are the result of protracted crystal-fractionation.The relative volumes of the extruded lava-types are discussed and it is suggested that the trachytic and pantelleritic centres developed above cupolas of salic magma situated on top of a large basaltic reservoir. It is likely that the preponderance of salic rocks and the scarcity of lavas of intermediate composition are not criteria by which one can rule out an origin of differentiation by crystal-fractionation.     

Pantelleritic obsidians from the volcano Chabbi (Ethiopia)

Chabbi, a Quaternary volcano in the Ethiopian Rift, appears to be unique in having erupted only non-porphyritic pantelleritic obsidians showing a very restricted range in composition. Petrogenetic schemes for deriving these lavas are discussed, and it is suggested that some degree of effective superheating, followed by failure of the magmas to crystallise because of their dryness (and hence high viscosity) can account at least for the absence of phenocrysts.     

Sources of uncertainty in projections of twenty-first century westerly wind changes over the Amundsen Sea,West Antarctica,in CMIP5 climate models

The influence of changes in winds over the Amundsen Sea has been shown to be a potentially key mechanism in explaining rapid loss of ice from major glaciers in West Antarctica, which is having a significant impact on global sea level. Here, Coupled Model Intercomparison Project Phase 5 (CMIP5) climate model data are used to assess twenty-first century projections in westerly winds over the Amundsen Sea (U _AS ). The importance of model uncertainty and internal climate variability in RCP4.5 and RCP8.5 scenario projections are quantified and potential sources of model uncertainty are considered. For the decade 2090–2099 the CMIP5 models show an ensemble mean twenty-first century response in annual mean U _AS of 0.3 and 0.7 m s^?1 following the RCP4.5 and RCP8.5 scenarios respectively. However, as a consequence of large internal climate variability over the Amundsen Sea, it takes until around 2030 (2065) for the RCP8.5 response to exceed one (two) standard deviation(s) of decadal internal variability. In all scenarios and seasons the model uncertainty is large. However the present-day climatological zonal wind bias over the whole South Pacific, which is important for tropical teleconnections, is strongly related to inter-model differences in projected change in U _AS (more skilful models show larger U _AS increases). This relationship is significant in winter (r = ?0.56) and spring (r = ?0.65), when the influence of the tropics on the Amundsen Sea region is known to be important. Horizontal grid spacing and present day sea ice extent are not significant sources of inter-model spread.     

A modeling study of coastal inundation induced by storm surge,sea-level rise,and subsidence in the Gulf of Mexico

The northern coasts of the Gulf of Mexico (GoM) are highly vulnerable to the direct threats of climate change, such as hurricane-induced storm surge, and such risks are exacerbated by land subsidence and global sea-level rise. This paper presents an application of a coastal storm surge model to study the coastal inundation process induced by tide and storm surge, and its response to the effects of land subsidence and sea-level rise in the northern Gulf coast. The unstructured-grid finite-volume coastal ocean model was used to simulate tides and hurricane-induced storm surges in the GoM. Simulated distributions of co-amplitude and co-phase lines for semi-diurnal and diurnal tides are in good agreement with previous modeling studies. The storm surges induced by four historical hurricanes (Rita, Katrina, Ivan, and Dolly) were simulated and compared to observed water levels at National Oceanic and Atmospheric Administration tide stations. Effects of coastal subsidence and future global sea-level rise on coastal inundation in the Louisiana coast were evaluated using a “change of inundation depth” parameter through sensitivity simulations that were based on a projected future subsidence scenario and 1-m global sea-level rise by the end of the century. Model results suggested that hurricane-induced storm surge height and coastal inundation could be exacerbated by future global sea-level rise and subsidence, and that responses of storm surge and coastal inundation to the effects of sea-level rise and subsidence are highly nonlinear and vary on temporal and spatial scales.     

A Regional Survey of the Extent and Magnitude of Eutrophication in Mediterranean Estuaries of Southern California,USA

The magnitude and extent of eutrophication was assessed at 27 segments in 23 estuaries in the Southern California Bight (SCB) between October 2008 and 2009. We applied thresholds from the existing assessment frameworks from both the European Union and the U.S. National Eutrophication Assessment to measurements of three indicators [macroalgae biomass and cover, phytoplankton biomass, and dissolved oxygen (DO) concentration] to categorize eutrophic condition in each estuary. Based on these frameworks, a large fraction of segments had moderate or worse eutrophic condition—78 % based on macroalgae, 39 % for phytoplankton, and 63 % for DO. Macroalgal biomass exceeding 70 g dw m^?2 and 25 % cover was found at 52 % of sites during any sampling event and in 33 % of segments for 8 weeks or longer, a duration found to negatively impact benthic infauna. Duration of hypoxic events (DO?<?4 mg L^?1) was typically short, with most events less than one day; although 53 % of segments had at least one event longer than 24 h. Assessment frameworks of eutrophic condition are likely to evolve over time as the body of literature on eutrophication grows, including aspects such as the applicability of indicators in specific habitat types, indicator thresholds, and how event frequency and duration are incorporated. This paper informs this debate by discussing how eutrophic conditions in SCB estuaries are categorized using different indicators and thresholds. To this end, categorization of estuarine eutrophic condition was found to be very sensitive to the type of threshold, how data are integrated to represent duration or spatial extent, and how indicators are used as multiple lines of evidence.