Bacterial mineralization patterns in basaltic aquifers: implications for possible life in martian meteorite ALH84001

To explore the formation and preservation of biogenic features in igneous rocks, we have examined the organisms in experimental basaltic microcosms using scanning and transmission electron microscopy. Four types of microorganisms were recognized on the basis of size, morphology, and chemical composition. Some of the organisms mineralized rapidly, whereas others show no evidence of mineralization. Many mineralized cells are hollow and do not contain evidence of microstructure. Filaments, either attached or no longer attached to organisms, are common. Unattached filaments are mineralized and are most likely bacterial appendages (e.g., prosthecae). Features similar in size and morphology to unattached, mineralized filaments are recognized in martian meteorite ALH84001.     

Parametric vertical coordinate formulation for multiscale, Boussinesq, and non-Boussinesq ocean modeling

Two physical parameters are introduced into the basic ocean equations to generalize numerical ocean models for various vertical coordinate systems and their hybrid features. The two parameters are formulated by combining three techniques: the arbitrary vertical coordinate system of Kasahara [Kasahara, A., 1974. Various vertical coordinate systems used for numerical weather prediction. Mon. Weather Rev. 102, 509–522], the Jacobian pressure gradient formulation of Song [Song, Y.T., 1998. A general pressure gradient formation for ocean models. Part I: Scheme design and diagnostic analysis. Mon. Weather Rev. 126 (12), 3213–3230], and a newly introduced parametric function that permits both Boussinesq (volume-conserving) and non-Boussinesq (mass-conserving) conditions. Based on this new formulation, a generalized modeling approach is proposed. Several representative oceanographic problems with different scales and characteristics––coastal canyon, seamount topography, non-Boussinesq Pacific Ocean with nested eastern Tropics, and a global ocean model––have been used to demonstrate the model’s capabilities for multiscale applications. The inclusion of non-Boussinesq physics in the topography-following ocean model does not incur computational expense, but more faithfully represents satellite-observed ocean-bottom-pressure data. Such a generalized modeling approach is expected to benefit oceanographers in solving multiscale ocean-related problems by using various coordinate systems on the same numerical platform.     

Draa Sfar, Morocco: A Visean (331 Ma) pyrrhotite-rich, polymetallic volcanogenic massive sulphide deposit in a Hercynian sediment-dominant terrane

Draa Sfar is a Visean, stratabound, volcanogenic massive sulphide ore deposit hosted by a Hercynian carbonaceous, black shale-rich succession of the Jebilet terrane, Morocco. The ore deposit contains 10 Mt grading 5.3 wt.% Zn, 2 wt.% Pb, and 0.3 wt.% Cu within two main massive sulphides orebodies, Tazakourt (Zn-rich) and Sidi M'Barek (Zn–Cu rich). Pyrrhotite is by far the dominant sulphide (70 to 95% of total sulphides), sphalerite is fairly abundant, chalcopyrite and galena are accessory, pyrite, arsenopyrite and bismuth minerals are rare. Pyrrhotite is monoclinic and mineralogical criteria indicate that it is of primary origin and not formed during metamorphism. Its composition is very homogeneous, close to Fe₇S₈, and its absolute magnetic susceptibility is 2.10^− 3 SI/g. Ar–Ar dating of hydrothermal sericites from a coherent rhyolite flow or dome within the immediate deposit footwall indicates an age of 331.7 ± 7.9 Ma for the Draa Sfar deposit and rhyolite volcanism.The Draa Sfar deposit has undergone a low-grade regional metamorphic event that caused pervasive recrystallization, followed by a ductile–brittle deformation event that has locally imparted a mylonitic texture to the sulphides and, in part, is responsible for the elongated and sheet-like morphology of the sulphide orebodies. Lead isotope data fall into two compositional end-members. The least radiogenic end-member, (²⁰⁶Pb/²⁰⁴Pb = 18.28), is characteristic of the Tazakourt orebody, whereas the more radiogenic end-member (²⁰⁶Pb/²⁰⁴Pb  18.80) is associated with the Sidi M'Barek orebody, giving a mixing trend between the two end-members. Lead isotope compositions at Draa Sfar testify to a significant continental crust source for the base metals, but are different than those of the Hajar and South Iberian Pyrite Belt VMS deposits.The abundance of pyrrhotite versus pyrite in the orebodies is attributed to low fO₂ conditions and neither a high temperature nor a low aH₂S (below 10^− 3) is required. The highly anoxic conditions required to stabilize pyrrhotite over pyrite are consistent with formation of the deposit within a restricted, sediment-starved, anoxic basin characterized by the deposition of carbonaceous, pelagic sediments along the flank of a rhyolitic flow-dome complex that was buried by pelitic sediments. Deposition of sulphides likely occurred at and below the seafloor within anoxic and carbonaceous muds.Draa Sfar and other Moroccan volcanogenic massive sulphide deposits occur in an epicontinental volcanic domain within the outer zone of the Hercynian belt and formed within a sedimentary environment that has a high pelagic component. In spite of the diachronous emplacement between the IPB deposits (late Devonian to Visean) and Moroccan deposits (Dinantian), all were formed around 340 ± 10 Ma following a major phase of the Devonian compression.     

Weathering rates of sandstone in a semi-arid environment (Hunter Valley,Australia)

The rate of sandstone weathering in the semi-arid climate of the Hunter Valley, New South Wales, Australia has been estimated from observations of gravestone weathering in the area. The gravestone data points to two distinct stages in the weathering process. The first stage covering the first century of exposure is characterised by a relatively low recession rate of 0.5 mm/100 years. This is followed by a second stage in which the rate of weathering increases sharply to ca 2.5 mm/100 years. The non-linear nature of the weathering trends over time suggests that during the first century of exposure, structural changes took place within the sandstone material, which lay the foundation for accelerated weathering after further exposure. Laboratory trials were also conducted to identify the effectiveness of different weathering processes in the decay of sandstone in this region. Of the four processes examined, only the freeze–thaw cycle produced a significant degree of mass loss and is therefore most likely a strong contributor to the weathering of sandstone in this region.     

Ductile-to-brittle transition in shear during thrust sheet emplacement,Southern Appalachian thrust belt

Mesoscopic structures in anchimetamorphic (T = 200–300°C) strata of the Pulaski thrust sheet, Southern Appalachian thrust belt, developed in progressive, heterogeneous simple shear near the ductile-to-brittle transition. Shear (γ≤3) was localized in weak, anisotropic pelitic rocks (Rome Formation) along the base of this 5–11 km thick thrust sheet. Folds, which vary from upright and open to isoclinal and NW-facing, developed during ductile shearing and display a correlation between tightness and axial-surface dip. Movement along brecciated thrust zones, which evolved progressively from zones of greatest ductile strain, resulted in low-angle truncation of fold axis trends, coaxial refolding of earlier structures, and imbrication of the thrust sheet.Transient variations in fluid pressure (P_f) controlled the mechanical behavior of the thrust sheet. Systematic veins imply P_f >σ₃ + T (T = tensile strength) during ductile deformation, whereas later non-systematic vein arrays in high strain zones record periods of nearly hydrostatic stress. Elevated P_f, which led to fracturing, dilation, and fault initiation, appears confined to pelitic zones within the Rome Formation. This, coupled with decreasing temperature, resulted in the transition from ductile folding to brittle thrusting. Changing physical conditions probably reflect erosional unroofing during uplift and late Paleozoic thrust sheet emplacement.