A study of the chemistry of pore fluids and authigenic carbonates in methane seep environments: Kodiak Trench, Hydrate Ridge, Monterey Bay, and Eel River Basin

Analyses of the chemical and isotopic composition of carbonates rocks recovered from methane seepage areas of the Kodiak Trench, Hydrate Ridge, Monterey Bay Clam Flats, and the Eel River Basin, coupled with the studies of the chemistry of the pore fluids, have shown that these carbonates have grown within the sediment column. Geochemical profiles of pore fluids show that, in deep water seeps (Kodiak Trench—4450 m; Monterey Bay—1000 m; Hydrate Ridge—650 m), δ¹³C (DIC) values are low (isotopically light), whereas in the Eel River area ( 350–500 m), δ¹³C (DIC) values are much higher (isotopically heavier). In all cases, the δ¹³C values indicate that processes of methane oxidation, associated with sulfate reduction, are dominant in the shallow sediments. Data on the isotopic composition of authigenic carbonates found at sites in Kodiak Trench, Eel River Basin South, and Eel River Basin North indicate a variable composition and origin in different geochemical environments. Some of the authigenic carbonates from the study sites show a trend in their δ¹³C values similar to those of the pore fluids obtained in their vicinity, suggesting formation at relatively shallow depths, but others indicate formation at greater sediment depths. The latter usually consist of high magnesium calcite or dolomite, which, from their high values of δ¹³C (up to 23‰;) and δ¹⁸O (up to 7.5‰), suggest formation in the deeper horizons of the sediments, in the zone of methanogenesis. These observations are in agreement with observations by other workers at Hydrate Ridge, in Monterey Bay, and in the Eel River Basin.     

中国以外的世界天坑概览

就中国以外已发现的26个天坑的特征和成因进行了一般性的描述和讨论.此外,对其它类型的一些特大型塌陷漏斗也与天坑进行了比较.     

Environmental applications of magnetometry profiling

Environmental impact assessment is currently a standard procedure for assessing the possible consequences of any particular activity that may cause degradation of the environment. Magnetometry profiling, which involves accurate measurements of the Earth's magnetic field at closely spaced stations is a technique that has a large number of environmental applications that can greatly improve this assessment. The technique has been applied successfully for waste disposal site evaluation, toxic waste detection, assessment of the quality of roadstone before excavations and can provide information that allows subsurface water movement models to be refined. Magnetometry profiling is inexpensive, nondestructive, and a very costeffective method of acquiring useful information about the environment.     

Peralkaline nephelinites. I. Comparative petrology of Shombole and Oldoinyo L'engai,East Africa

Shombole, a nephelinite-carbonatite volcano in south Kenya, erupted silicate lavas, carbonatite dikes and tuffs, and pyroclastic rocks similar to those at other East African alkaline centres. Shombole lavas containing cpx + nepheline + accessory minerals range from perovskite-bearing nephelinites (43% SiO₂, volatile-free) to sphene-bearing and phonolitic nephelinites (46–49% SiO₂) and phonolites (49–56% SiO₂) and have low peralkalinity ([Na+K]/Al 1.15) which does not correlate with SiO₂. Early fractionation of olivine and clinopyroxene strongly depleted Ni and Cr concentrations (10 ppm); fractionation of perovskite, melanite, sphene, and apatite produced negative correlations of all REE with SiO₂. Many lavas contain cognate intrusive xenoliths and xenocrysts and oscillatory zoning is a common feature of clinopyroxene, nepheline, and melanite crystals, indicating recycling of intrusive material. Irregular calcite-rich bodies in many samples are interpreted as quenched immiscible Ca-carbonatite liquid, and [Ca-carbonate]-silicate liquid immiscibility is observed in experiments with one nephelinite. Chemical variation in the Shombole suite can be modeled as a combination of crystal fractionation (clinopyroxene and heavy minor phases) and retention of neutral density nepheline derived from disaggregated xenoliths entrained during emplacement of dike swarms. Six newly analyzed lavas from Oldoinyo L'engai, northern Tanzania, are geochemically similar to Shombole nephelinites except that they have relatively high Na₂O+K₂O (average 18% vs 12%) and Zr (average 680 ppm vs 400 ppm). They are extremely peralkaline and are not typical of nephelinites from other centres. Three with [Na+K]/Al1.5 contain euhedral wollastonite phenocrysts; three with [Na+K]/Al2.0 contain combeite (Na₂Ca₂Si₃O₉) phenocrysts and pseudomorphs after wollastonite. Both types contain abundant sodalite phenocrysts (+nepheline+clinopyroxene+melanite+sphene). Seven other wollastonite nephelinite samples from L'engai have been described, but it is a lava type rarely seen in other centres. Combeite has been described from only two other locations (Mt. Shaheru, Zaire; Mayener Feld, Eifel). The hyperalkaline L'engai nephelinites have compositions similar to those of experimental silicate liquids immiscible with natrocarbonatite. Textural evidence for both carbonate-silicate (as carbonate globules) and silicate-silicate (as two optically discrete glasses with distinct compositions) liquid immiscibility is observed in the samples.     

Pyrite-organic matter relationships: Currant Bush Limestone,Georgina Basin,Australia

The relationship between the TOC (total organic carbon) and S (pyritic sulphur) contents of some organic-rich (TOC 3–14%) silty limestones and calcareous siltstones from the Cambrian Currant Bush Limestone of the Georgina Basin, Australia, is similar to that of euxinic sediments, but could also indicate deposition in a non-saline environment. However, such conditions are not easily reconciled with the shallow equatorial epeiric sea in which the formation is considered to have been deposited. The relationship can alternatively be explained by the relatively low Fe content of the sediment being the main limiting factor in pyrite generation, coupled with a slightly increased degree of pyritization with increased TOC. The relationship between the TOC and S contents of organic-poor (TOC 0.2–2.4%) samples from the same formation is similar to that of normal marine sediments, but the Fe content is probably also the major controlling factor on pyrite generation. These interpretations demonstrate that in using TOC and S contents to aid in reconstruction of depositional environments, it is important to check whether Fe content could have been the limiting factor in the formation of pyrite, even in sediments with only moderate carbonate contents.     

Conflicting rights to the city in New York's community gardens

In the mid-1990s, New York City initiated what would prove to be a long, highly visible struggle involving rights claims related to property, housing, and public space in the form of community gardens. The competing discourses of rights were part of a struggle over the kind of city that New York was to become, and more specifically, whether it would be one in which difference is accepted and in which access to the city and the public realm would be guaranteed. Using interviews with participants in the conflict over community gardens, we evaluate how the resolution to the gardens crisis, which in part occurred through the privatization of what are often taken to be public or community rights to land, transform not only the legal status of the gardens but also, potentially, their role as places where different `publics' can both exercise their right to the city and solidify that right in the landscape.     

Earthquake response of a multiblock nuclear reactor graphite core: Experimental model vs simulations

The complex dynamics of a quarter‐scale model of a graphite nuclear reactor core, representative of the second generation of British advanced gas‐cooled nuclear reactors, is investigated numerically and experimentally. Advanced gas‐cooled nuclear reactor cores are polygonal, multilayer, arrays of graphite bricks, with each brick allowed to rock by design relative to each other in accordance with the boundary conditions. A 35 000 DOF, nonlinear finite element model of the core created by Atkins Nuclear, was analysed on a high performance computing facility at the University of Bristol, and a corresponding 8 t physical model, equipped with 3200 data acquisition channels, was built and tested on the University of Bristol 6‐DOF shaking table. In this paper, the two models are subjected to a series of (1) synthetic earthquake and (2) idealised harmonic input motions. The experimental data are used to compare and verify the two models and explore the dynamics of the core. A kinematic model of the response is also developed based solely on geometric constraints. The results are presented in the form of response maps and graphs. Important conclusions are drawn as to the dynamics and earthquake response of such systems, which inform numerical model validation. It is found that contrary to the case of a small number of rocking blocks that exhibit highly complex response patterns, the behaviour of the model at hand is both smooth and repeatable. An analogy between the response of the core and that of dense granular matter exhibiting particle interlocking and dilatancy is highlighted.     

When to conduct an isotopic survey for lake water balance evaluation in highly seasonal climates

One‐time or short‐term lake water isotopic surveys are often employed to evaluate regional lake water balance. However, it can be difficult to determine the optimal time‐window for sampling to obtain a representative long‐term perspective of lake water balance in settings influenced by seasonal variations in precipitation, evaporative loss, glacial/snow meltwater, and larger seasonal shifts in isotopic composition of precipitation. This is especially true for areas of the Tibetan Plateau that are influenced by the summer Indian monsoon. Although high‐frequency sampling is always preferred as the most rigorous approach to characterize the water budget of lakes or watersheds, this may be impractical in remote regions and over large spatial scales. To assess the potential sensitivity of isotope balance characterization to seasonal variability, we used a weekly lake water isotope data set acquired over a period of 3 years on the Tibetan Plateau to evaluate the potential inaccuracies that might have arisen from using isotopic data collected during narrower time‐windows. For this assessment, we use weekly isotopic data collected during the study and assume that these sampling events were stand‐alone one‐time surveys. We then demonstrate the sensitivity of the isotope balance method in this setting, particularly for the rainy season that significantly underestimated the evaporation/inflow. In contrast, isotopic composition of the lake water was found to be more representative of long‐term conditions when sampled in October on the Tibetan Plateau. To broaden our evaluation of seasonality effects over a range of climatic zones, published high‐frequency isotopic data were also compiled, and a similar assessment was carried out for selected regions of the world. The synthesized data and model outputs, which confirm pronounced variations in lake water isotopic composition and evaporation/inflow across a range of seasonal climates, were used to determine optimal sampling windows for these specific regions.