湘西南高涧群的地球化学特征及其意义

湘西南高涧群主要是一套浅变质沉积碎屑岩系,由变质泥岩、板岩和变质粉砂岩组成,原岩颗粒小。变质作用对岩石化学成分没有大的改变,岩石具有相近的风化蚀变指数（平均CIA＝75）风化蚀变矿物主要为伊利石－白云母－蒙脱石组合。主要化学成分反映沉积物来源于中性和基性火成岩区。浅变质沉积岩中大多数微量元素亏损,元素Cu,Zn,Co,Ti,Cr等在研究区的南部和北部具有相似的共生组合。并且稀土元素的分布模式基本相同,稀土的总量与岩性有关。上述特点显示了高涧群沉积物来源相同,亲石元素共生组合相似;Au,Ag,As,Sb,Sr,Ba等存在一定的分异,Ba/Co比值,Sr/Ba比值和δCe值表明,它是主要在浅深海－深海相还原环境下的产物。     

西大别浒湾高压变质带变沉积岩锆石U-Pb年龄及地质意义

西大别山浒湾高压变质带是研究秦岭-大别山-苏鲁造山带演化的关键区域, 但是该地区榴辉岩相变质时间还存在较大争议.本文通过对浒湾变质带熊店附近的一个变沉积岩样品进行LA-ICPMS锆石U-Pb定年和微量元素分析, 来确定该地区榴辉岩相变质作用和碎屑锆石的年龄, 并确定该变质带的演化历史.该样品的变质锆石具有弱分带或无分带、低Th/U比值、重稀土含量低且相对平坦以及无明显的Eu负异常等特征.反映这些变质锆石形成时有石榴石, 而缺乏长石, 其形成对应于榴辉岩相变质作用条件.该样品中变质锆石的206Pb/238U加权平均值为310±3Ma, 这一年龄代表了该地区榴辉岩相峰期变质作用的时间, 因此浒湾地区榴辉岩相变质作用时间为石炭纪.碎屑岩浆锆石得到了3组近谐和的U-Pb年龄, 其206Pb/238U年龄变化范围分别为: 400±5Ma~419±5Ma、426±5Ma~449±5Ma以及496±5Ma~524±7Ma, 还有1个颗粒给出了580±7Ma的较老年龄.这些结果表明变沉积岩中的碎屑锆石可能大部分来自于华北板块南缘, 少量来自于扬子板块.      

中缅毗邻区金腊Pb-Zn-Ag多金属矿田元素、稳定同位素和流体包裹体地球化学

跨越中缅边境的金腊铅-锌-银多金属矿田包括南腊和金厂两处铅锌银矿床, 大地构造上处于保山-掸泰地块东缘, 勐统-耿马-西盟元古宙-古生代被动大陆边缘活动带南段.通过对容矿围岩、与矿化有关的花岗岩和矿石元素地球化学以及矿石硫、铅同位素和流体包裹体的研究, 结论如下: (1) 与同类岩石相比, 与矿化有关的花岗岩普遍富集Pb、Zn、Cu、Au、Sn、W等成矿元素, 其中钾长花岗斑岩与Pb-Zn-Ag矿化关系最密切. (2) 铅同位素表明, 矽卡岩型致密块状矿石铅同位素比值(206Pb/204Pb、207Pb/204Pb和208Pb/204Pb) 皆低于热液充填型角砾状矿石和似层状硅化白云岩型矿石, 意味着形成于岩体接触带的矽卡岩型矿石相对形成于远离岩体的热液充填型角砾状矿石和似层状硅化白云岩型矿石含有更低的放射性成因铅. (3) 铅-锌-银矿化主要经历了两个成矿期: 矽卡岩化成矿期和中低温热液成矿期, 前者主要形成铅-锌-铜(金) 矿化, 后者主要形成铅-锌-银矿化; 中低温热液成矿期又可划分为两个成矿阶段: 中温成矿阶段(200~290℃) 和低温成矿阶段(140~200℃), 前者主要形成交代充填型硅化角砾岩矿体, 后者主要形成层间破碎带充填型硅化矿体. (4) 金腊铅锌矿床、保山-镇康地块某些铅锌矿床和昌宁-孟连火山岩带的铅锌矿床, 虽然产于不同的地质构造单元, 但矿石铅同位素组成却具有类似的特征, 而且矿化皆与喜马拉雅期侵位的花岗岩密切相关.这表明: 虽然上述矿床产出于不同的地质构造单元, 但成矿皆与喜马拉雅期构造岩浆活动具有某种内在联系.      

Effect of Fly Ash on Frost-Resistance and Chloride Ions Diffusion Properties of Marine Concrete

It is necessary to pay more attention to the durability of concrete undergoing freeze-thaw cycles and seawater attack simultaneously.Investigated are the effects of water-binder ratio,fly ash (FA) contents and air-entraining agent on resistance to frost and chloride diffusion of marine concrete blended with FA in natural seawater.The results show that fly ash does not improve the frost resistance of concrete but can improve its resistance to chloride diffusion by addition of less than 30%.The resistance to frost and chloride diffusion of FA concrete can be improved with the decrease of water-binder ratio,and FA may improve both of them simultaneously only being mixed with air-entraining agent.A ratio (named as R) of the frost-resisting durability factor to chloride diffusion coefficient can be used to evaluate the durability of marine concrete.Scanning electron microscope (SEM) analyses are consistent with the evaluations by the value of R.     

青城子小佟家堡子、林家金矿成矿流体特征及成矿机制

小佟家堡子、林家金矿是青城子铅锌、金、银矿集区的中-大型金矿床,金矿床与沉积-变质期硅化岩关系密切。通过与矿区尖山岩体、新岭岩体中流体包裹体对比研究表明,金矿床与尖山岩体中主要发育水溶液包裹体,极少量的CO2包裹体、含CO2三相包裹体,而新岭岩体除发育以上包裹体外,还发育含子矿物多相包裹体。测温结果显示金矿床成矿流体温度为110～335℃,盐度3．9％～16．2％NaClrq拉曼光谱分析表明金矿床流体成分以H2O为主,少量的CO2、CH4等气体,表明成矿流体属NaCl-H2O体系。金矿床与尖山岩体中流体包裹体温度、盐度及成分相近,推断成矿流体主要来自沉积-变质期。     

Ridge subduction and porphyry copper-gold mineralization:An overview

Many large porphyry Cu-Au deposits are connected to adakitic rocks known to be closely associated with ridge subduction. For example, there are several subducting ridges along the east Pacific margin, e.g., in Chile, Peru, and South America, most of which are associated with large porphyry Cu-Au deposits. In contrast, there are much fewer ridge subductions on the west Pacific margin and porphyry Cu-Au deposits are much less there, both in terms of tonnage and the number of deposits. Given that Cu and Au are...     

累托石制备润滑脂的初步研究

累托石是一种具有独特的结构组成和性质的粘土矿物,其既具有象蒙脱石一样的阳离子交换性,吸水膨胀性,制浆性等,又具有象云母一样的耐高温性和光滑性等性能。经提纯和有机改性后的累托石吸油速度快,膨胀率高,是一种较好的稠化剂,用它制备的润滑脂滴点〉６３３．１５Ｋ,远高于膨润土润滑脂的指标要求,研究表明,累托石是制备润肖脂稠化剂的好原料,累托石润滑脂是一种新型高温润滑脂。     

A Study of the Accompanying Relationships between Uranium and Oil

It is not occasional that uranium deposits and oil accumulation occur in the same depression in the Erlian basin, Inner Mongolia. Some evidences show certain relations between uranium and oil in origin. This paper discusses and analyses the evidence for the relations between uranium deposits and oil and gas accumulation in terms of spatial distribution, geology, hydrochemistry and geochemistry. The paper also deals with the mechanism of the formation of uranium deposits and points out that it is of significance to use uranium as an indicator to search for oil and vice versa.     

导水裂隙带高度预测途径探讨

导水裂隙带高度是设计防水煤（岩）柱尺寸的主要技术参数，是煤矿防治水工作的重要内容。详细论述了其研究现状及发展趋势，并提出了履岩体地质环境，履岩体力学环境和数值模拟技术三位一体的综合预测评价方法。