A Late Cretaceous mammalian dentary from the Ashizawa Formation (Futaba Group), Fukushima,northeastern Japan

A mammalian dentary discovered in the Coniacian Ashizawa Formation (Fukushima, northeastern Japan) is described. The specimen is a fragment of the horizontal ramus of a left edentulous dentary with five alveoli, the distal four of which are plugged with broken roots. Based on the morphologies of the dentary and the roots, it is considered to be of a therian mammal. This constitutes the first discovery of a Mesozoic mammal in northeastern Japan and highlights the potential for future mammal discoveries in the Cretaceous System in northeastern Japan, which will be significant for disclosure of the mammalian faunal evolution in East Asia during the Late Cretaceous.     

Groundwater-level Changes Due to Pressure Gradient Induced by Nearby Earthquakes off Izu Peninsula, 1997

Anomalous water level changes were observed at two wells associated with seismic swarm activity off Izu Peninsula on March, 1997. These are coseismic water level drops followed by gradual postseismic water level rise at the time of large earthquakes during the swarm activity. The post-seismic water level rises, which can be fitted by an exponential function with a time constant of about six hours, are explained in terms of the horizontal pressure diffusion due to the pressure gradient in the aquifer induced by the coseismic static strain.     

Diffuse Emission of CO2 from Showa-Shinzan, Hokkaido, Japan: A Sign of Volcanic Dome Degassing

Two soil CO₂ efflux surveys were carried out in September 1999 and June 2002 to study the spatial distribution of diffuse CO₂ degassing and estimate the total CO₂ output from Showa-Shinzan volcanic dome, Japan. Seventy-six and 81 measurements of CO₂ efflux were performed in 1999 and 2002, respectively, covering most of Showa-Shinzan volcano. Soil CO₂ efflux data showed a wide range of values up to 552 g m^-2 d^-1. Carbon isotope signatures of the soil CO₂ ranged from -0.9‰ to -30.9‰, suggesting a mixing between different carbon reservoirs. Most of the study area showed CO₂ efflux background values during the 1999 and 2002 surveys (B = 8.2 and 4.4 g m^-2 d^-1, respectively). The spatial distribution of CO₂ efflux anomalies for both surveys showed a good correlation with the soil temperature, indicating a similar origin for the extensive soil degassing generated by condensation processes and fluids discharged by the fumarolic system of Showa-Shinzan. The total diffuse CO₂ output of Showa-Shinzan was estimated to be about 14.0–15.6 t d^-1 of CO₂ for an area of 0.53 km².     

Floral changes in calcareous nannofossils and their paleoceanographic significance in the equatorial Pacific Ocean during the last 500 000 years

Abstract   The late Quaternary calcareous nannofossil assemblages from Ocean Drilling Program Holes 807A and 846B, located in the western and eastern equatorial Pacific Ocean, respectively, were analyzed to clarify changes in surface-water conditions during the last 500 000 years. The uppermost Quaternary sediments in both holes contain abundant nannofossils, and their assemblages are characterized by high species diversity. The absolute abundances of coccoliths (specimens/g) and relative numbers of small reticulofenestrids decreased drastically in both holes between 0.3 and 0.2 Ma, whereas the relative abundance of warm-water species and Florisphaera profunda increased suddenly at this time. These data indicate that upwelling around the western and eastern equatorial Pacific regions weakened after 0.2 Ma, which was caused by a decrease in trade-wind strength.     

Ultrasonic measurements of Vp and Qp: relaxation spectrum of complex modulus on basalt melts

Ultrasonic compressional wave velocity V_p and quality factor Q_p have been measured in alkali basalt, olivine basalt and basic andesite melts in the frequency range of 3.4–22 MHz and in the temperature range of 1100–1400°C. Velocity and attenuation of the melts depend on frequency and temperature, showing that there are relaxation mechanisms in the melts. Complex moduli are calculated from the ultrasonic data. The results fit well a complex modulus of Arrhenius temperature dependence with log-normal Gaussian distribution in relaxation times of attenuation. The analysis yields average relaxation time, its activation energy, relaxed modulus, unrelaxed modulus and width of Gaussian distribution in relaxation times. Relaxed modulus is smaller (17.5 GPa) for basic andesite melt of high silica and high alumina contents than for the other two basalt melts (18.1–18.4 GPa). The most probable relaxation times decrease from ～ 3 × 10^?10 s for basic andesite to ～ 10^?11 s for alkali basalt at 1400°C. Activation energies of attenuation, ranging from 270 to 340 kJ mol^?1 in the three melts, are highest in basic andesite. Longitudinal viscosity values and their temperature dependences are also calculated from V_p and Q_p data. The volume viscosity values are estimated from the data using the shear viscosity values. Longitudinal, volume and shear viscosities and their activation energies are highest in the basic andesite melt of the most polymerized structure.     

A new technique for measuring diffusion coefficients of cations and anions in ionic crystals

A new technique has been developed for measuring the diffusion coefficient in ionic crystals. Based on Einstein's formula expressing the relation between diffusion coefficient and electric mobility, the electrical impedance of a diatomic ionic crystal is derived theoretically as a function of frequency of the applied electric field. In this method, the diffusion coefficients of both cations and anions are determined simultaneously by fitting the measured impedance to the theoretical relation. This method was applied to NaCl single crystals in the temperature range 370–780°C. The impedance was determined over the frequency range 0.01 Hz to 1 kHz, at constant temperature. The diffusion coefficients thus obtained for NaCl agree reasonably well with previous data by means of a radioactive isotope technique. The activation energies for Na⁺ and Cl^? obtained are 1.97±0.03 eV and 2.08±0.06 eV, respectively, in the intrinsic region, and 0.92±0.02 eV and 1.06±0.02 eV in the extrinsic region. It was discovered that there are diffusion blocks of approximately 2 μm width, which obstruct free migration of ions in a single crystal.     

Non-destructive monitoring of trace element levels in short-tailed albatrosses (Phoebastria albatrus) and black-footed albatrosses (Phoebastria nigripes) from Torishima Island, Japan using eggs and blood

Concentrations of 18 trace elements (V, Cr, Mn, Co, Cu, Zn, Se, Rb, Sr, Mo, Ag, Cd, Sb, Cs, Ba, Hg, Tl and Pb) were determined in abandoned eggs of short-tailed albatrosses and abandoned eggs and blood of black-footed albatrosses from Torishima Island, Japan in 2002. Mercury concentration was highest among the toxic elements in egg content of both the two species. In some egg contents of black-footed albatrosses, Hg concentrations were higher than the threshold level that may cause decreased hatchability and aberrant nesting behavior in some avian species. Concentrations of Cd in egg content and Ba in egg content and shell increased with an increase in egg breadth/length ratio, whereas Hg in egg content showed an opposite trend in black-footed albatrosses. Since egg breadth/length ratio is known to increase with the age of mother bird, this result may imply that concentrations of these elements in eggs vary with age of mother bird. In blood of black-footed albatross chicks, concentration of Hg was highest among the toxic elements and the Hg concentration showed an increase in the later growth stages. In contrast, concentration of Sr in blood decreased with growth stage. Since the behaviour of Sr is similar to that of Ca in animals, it is conceivable that Sr was used along with Ca for the formation of bone.     

Todorokite formation in seawater by microbial mediation

Microbial manganese oxidation in seawater was carried out in enrichment cultures which were obtained from the seawater supply system at the Marine Science Museum, Tokai University (Shimizu-shi, Japan). The manganese oxide formed was well-crystallized todorokite. The major element composition was within the range of marine manganese concretions and the O/Mn molar ratio was 1.8. The conditions for formation of manganese oxide minerals in marine environments are discussed on the basis of these results.     

Lermontovskoe Tungsten Skarn Deposit: the Oldest Mineralization in the Sikhote-Alin Orogen, Far East Russia

Abstract. Lermontovskoe tungsten skarn deposit in central Sikhote-Alin is concluded to have formed at 132 Ma in the Early Cretaceous, based on K-Ar age data for muscovite concentrates from high-grade scheelite ore and greisenized granite. Late Paleozoic limestone in Jurassic - early Early Cretaceous accretionary complexes was replaced during hydrothermal activity related to the Lermontovskoe granodiorite stock of reduced type. The ores, characterized by Mo-poor scheelite and Fe^3+- poor mineral assemblages, indicate that this deposit is a reduced-type tungsten skarn (Sato, 1980, 1982), in accordance with the reduced nature of the granodiorite stock.
The Lermontovskoe deposit, the oldest mineralization so far known in the Sikhote-Alin orogen, formed in the initial stage of Early Cretaceous felsic magmatism. The magmatism began shortly after the accretionary tectonics ceased, suggesting an abrupt change of subduction system. Style of the Early Cretaceous magmatism and mineralization is significantly different between central Sikhote-Alin and Northeast Japan; reduced-type and oxidized-type, respectively. The different styles may reflect different tectonic environments; compressional and extensional, respectively. These two areas, which were closer together before the opening of the Japan Sea in the Miocene, may have been juxtaposed under a transpressional tectonic regime after the magmatism.