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排序方式: 共有116条查询结果,搜索用时 15 毫秒
111.
Tomohiko Isobe Karri Ramu Yuko Tajima Masao Amano Shin Takahashi 《Marine pollution bulletin》2009,58(3):396-401
Organohalogen contaminants including PCBs, DDTs, CHLs, HCHs, HCB, PBDEs and HBCDs were determined in striped dolphins (Stenella coeruleoalba) found stranded at Gogo-shima (n = 6, 2003) and collected from Taiji (n = 15, 1978-1992) in Japan. All target compounds were significantly detected in all the specimens, indicating ubiquitous contamination of oceanic cetaceans in northwest Pacific Ocean. Examination of body distribution of organohalogens in the six specimens from Gogo-shima showed no significant difference in concentrations among the analyzed tissues, except for brain, which had lower levels possibly due to the existence of blood-brain barrier. For evaluating temporal trends, archived blubber samples of adult male stripped dolphins collected in 1978, 1979, 1986 and 1992 were analyzed. Concentrations of PCBs, DDTs and HCHs did not change significantly during 1978-2003. In contrast, remarkable increasing trends of PBDEs and HBCDs were observed, suggesting growing consumption in Japan and surrounding countries in recent years. 相似文献
112.
Ying-Ya Hsu Tung-Li Hsiung H. Paul Wang Yasuhiro Fukushima Yu-Ling Wei Juu-En Chang 《Marine pollution bulletin》2008,57(6-12):873
The nitrogen-doped TiO2 nanotube (N-TNT) thin films were synthesized using ZnO nanorods as the template and doped with urea at 623 K. Under ultraviolet (UV) and visible light irradiation, the efficiencies for photocatalytic degradation of methylene blue is as high as 30%. About 10% of toluene (representing aromatics in the spill oils) in sea water can be photocatalytically degraded under visible light radiation for 120 min. The aliphatic model compound (1-hexadecene) has, on the contrary, a less efficiency (8%) on the N-TNT photocatalyst. On the average, under visible light radiation, the effectnesses of the N-TNT for photocatalytic degradation of model compounds in the spill oils in sea water are 0.38 mg toluene/gN-TNT h and 0.25 mg 1-hexadecene/gN-TNT h. It is expected that spill oils in the harbors or seashores can be adsorbed and photocatalytically degraded on the N-TNT thin films that are coated onto levee at the sea water surface level. 相似文献
113.
Toshio Fukushima 《Celestial Mechanics and Dynamical Astronomy》1994,60(1):57-68
A new canonical transformation of freedom two was found. By using this, we derived three new sets of canonical variables for the orbital motion and two for the rotational motion. New canonical variables have clear physical meanings and remain well-defined in the case when the classical sets become ill-defined, for example, when the eccentricity and/or the inclination is small for the elliptic orbital motion. 相似文献
114.
Log-irradiance fluctuations of He-Ne laser light were simultaneously measured at three different points in the receiving plane. The cumulative probability distributions of log-irradiance show excellent agreement with the Rice-Nakagami distribution in the region of weak fluctuations. The irradiance distributions strongly depend upon the locations of the observing points with respect to the center of the beam, as expected from recent theory. 相似文献
115.
116.
Investigating the Influence of Non‐Spectral Matrix Effects in the Determination of Twenty‐Two Trace Elements in Rock Samples by ICP‐QMS 下载免费PDF全文
Tetsuya Yokoyama Yuichiro Nagai Yu Hinohara Tomohiko Mori 《Geostandards and Geoanalytical Research》2017,41(2):221-242
The influence of non‐spectral matrix effects on the determination of twenty‐two trace elements (Rb, Sr, Y, Cs, Ba, lanthanides, Pb, Th and U) in rock samples using ICP‐MS was investigated. Three types of multi‐element solutions were synthesised containing the twenty‐two trace elements, In, Tl and ten major rock‐forming elements with varying mass fractions mimicking the compositions of basalt, peridotite and dolomite. The synthetic solutions were conditioned to have dilution factors (DF) of 1000–10000. The extent of sensitivity suppression relative to the DF = 10000 solution became more significant for smaller DF solutions, which was not constant across different elements in a single solution but displayed general dependence on m/z. This indicates that at least two internal standards (e.g., In and Tl) are required for the correction of sensitivity variation. On the basis of the results, a new isotope dilution‐internal standardisation method for the determination of twenty‐two trace elements with ICP‐MS was developed, in which the sensitivity variation was corrected by monitoring two enriched isotopes, 113In and 203Tl. This method, coupled with the quantitative correction of interference from oxides and hydroxides, achieved precise determination of twenty‐two trace elements in some rock reference materials with reproducibilities of ±2% for basaltic to andesitic samples. 相似文献