Isotopic composition of dissolved inorganic carbon in subsurface sediments of gas hydrate-bearing mud volcanoes, Lake Baikal: implications for methane and carbonate origin

We report on the isotopic composition of dissolved inorganic carbon (DIC) in pore-water samples recovered by gravity coring from near-bottom sediments at gas hydrate-bearing mud volcanoes/gas flares (Malenky, Peschanka, Peschanka 2, Goloustnoe, and Irkutsk) in the Southern Basin of Lake Baikal. The δ¹³C values of DIC become heavier with increasing subbottom depth, and vary between ?9.5 and +21.4‰ PDB. Enrichment of DIC in ¹³C indicates active methane generation in anaerobic environments near the lake bottom. These data confirm our previous assumption that crystallization of carbonates (siderites) in subsurface sediments is a result of methane generation. Types of methanogenesis (microbial methyl-type fermentation versus CO₂-reduction) were revealed by determining the offset of δ¹³C between dissolved CH₄ and CO₂, and also by using δ¹³C and δD values of dissolved methane present in the pore waters. Results show that both mechanisms are most likely responsible for methane generation at the investigated locations.     

Interdecadal oscillations in the Japan Sea proper water related to the arctic oscillation

The time series of dissolved oxygen (DO) concentration in the Japan Sea Proper Water (JSPW) shows clear interdecadal oscillation with about 20-year periodicity since the 1970s. This interdecadal variation in the DO concentration is positively correlated with the Arctic Oscillation (AO) index; the DO concentration tends to be high during a positive AO phase when the East Asian winter monsoon (EAWM) is relatively weak, which is considered to be an unfavorable condition for the JSPW formation. To clarify the discrepancy, the cause of the interdecadal oscillation was investigated using the wind at Wajima and sea surface temperature (SST) in the JSPW formation area. The cold-air outbreaks determined from the wind at Wajima are synchronized with the interdecadal oscillation of the AO; during a positive AO phase the cold-air outbreaks over the Japan Sea are more active, as reported by Isobe and Beardsley (2007). Since the SST in the JSPW formation area is negatively correlated with cold-air outbreaks, the activity of cold-air outbreaks is more important to the JSPW formation than the EAWM, at least on an interdecadal timescale. Significant correlations of the indicator of low pressure migration with the AO and cold-air outbreaks confirm that atmospheric disturbances move frequently into the Japan Sea from the East China Sea in a positive AO phase. A detailed examination of cold-air outbreaks revealed that the passing of atmospheric low pressures temporarily enhances the east-west pressure gradient over the Japan Sea and effectively brings cold air into the JSPW formation area.     

Stoichiometry among bioactive trace metals in seawater on the Bering Sea shelf

The distribution of Al, Mn, Fe, Co, Ni, Cu, Zn, Cd, and Pb in seawater was investigated on the Bering Sea shelf (56–64°N, 165–169°W) in September 2000. The unfiltered and filtered seawater samples were used for determination of total dissolvable (TD) and dissolved (D) metals (M), respectively. The TD-M concentrations were generally higher than in the Pacific Ocean. TD-Cd was highest in deep water of the outer shelf domain and dominated by dissolved species. The other TD-M were highest at stations close to the Yukon River delta and had higher fractions of labile particulate (LP) species that were obtained as the difference between TD-M and D-M. Dissolved Al, Ni, and Cu were characterized by input from the Yukon River. Dissolved Mn and Co showed maximums on the bottom of the coastal domain, suggesting influence of sedimentary Mn reduction. The correlations of D-Zn, D-Cd, and macronutrients indicated their distributions were largely controlled through uptake by microorganisms and remineralization from settling particles. All these three processes (river input, sedimentary reduction, and biogeochemical cycle) had an influence on the distribution of D-Fe. D-Pb was fairly uniformly distributed in the study area. The stoichiometry of D-M in the Bering Sea shelf showed enrichment of Co and Pb and depletion of Ni, Cu, Zn, and Cd compared with that in the North Pacific. The LP-M/LP-Al ratio revealed significant enrichment of the other eight metals relative to their crustal abundance, suggesting importance of formation of Fe–Mn oxides and adsorption of trace metals on the oxides.     

Has the upper portion of the Japan Sea Proper Water formation really been enhancing?

Weakening of the upper portion of the Japan Sea Proper Water formation was detected based on the dissolved oxygen concentration and potential temperature from 1970 to 2004, unlike the suggestion of previous studies that it has been enhanced since the 1970s. The revealed warming and decreasing trends in DO concentration throughout the water column indicate that the conveyor belt system in the Japan Sea is still slowing down even in the intermediate layers, though a relatively active dissolved oxygen supply into the intermediate layers is suggested. This fact leads us to modify the previous concept about the water mass formation; though a relatively active formation of the intermediate water mass occurs, the deep water formation is not counterbalanced by the intermediate water formation, and the overall Japan Sea Proper Water formation has been stagnating since the 1970s.     

Possible variation in methane flux caused by gas hydrate formation on the northeastern continental slope off Sakhalin Island, Russia

The Sakhalin Slope Gas Hydrate Project (SSGH) is an international collaborative effort by scientists from Japan, Korea, and Russia to investigate natural gas hydrates (GHs) that have accumulated on the continental slope off Sakhalin Island, Okhotsk Sea. From 2009 to 2011, field operations of the SSGH-09, -10, and -11 projects were conducted. GH-bearing and -free sediment cores were retrieved using steel hydro- and gravity corers. The concentrations of sulfate ions in sediment pore waters were measured to investigate sulfate concentration–depth profiles. Seventeen cores showed linear depth profiles of sulfate concentrations. In contrast, eight cores and two cores showed concave-up and -down profiles plausibly explained by sudden increase and decrease in methane flux from below, respectively, presumably caused by the formation of gas hydrate adjacent to the core sampling sites.     

Determination of plastic regions around underground openings by a coupled boundary-element-characteristics method

A two-dimensional hybrid method for solving elastoplastic problems in engineering is presented by coupling two existing methods, namely, the boundary element method and the characteristics method. The formulation of this method is presented, as well as an excellent procedure for the determination of the boundary between elastic and plastic regions. It is shown not only that this method is a powerful and accurate method for evaluating the shape and extent of the plastic region around rock caverns, which is of prime importance for the construction of rock caverns, but also applicable to a given range of the initial stress field ratio where only compressive failure occurs. Then, some typical examples are solved in order to check the accuracy of the solution by this method. Furthermore, its successful applications are presented and discussed to determine the shape and the extent of the plastic regions around parallel, circular and rectangular openings.     

The upper portion of the Japan Sea Proper Water; Its source and circulation as deduced from isopycnal analysis

All of the available hydrographic station data (temperature, salinity, dissolved oxygen, phosphate and nitrate) taken in various seasons from 1964 to 1985 are analyzed to show where the upper portion of the Japan Sea Proper Water (UJSPW) is formed and how it circulates. From vertical distributions of water properties, the Japan Sea Proper Water can be divided into an upper portion and a deep water at the ₁ (potential density referred to 1000 db) depth of 32.05 kg m^–3 surface. The UJSPW in the north of 40°N increases in dissolved oxygen contents and decreases in phosphate contents in winter, while no significant seasonal variation is seen in the south of 40°N. Initial nutrient contents calculated from relationships between AOU and nutrients on isopycnal surfaces show no significant regional difference in the Japan Sea; this suggests that the UJSPW has originated from a single water mass. From depth, dissolved oxygen and phosphate distributions on ₁ 32.03 kg m^–3 surface, core thickness distribution and subsurface phosphate distribution, it is inferred that the UJSPW is formed by the wintertime convection in the region west of 136°E between 40° and 43°N, and advected into the region west of the Yamato Rise along the Continent; finally, it must enter into the Yamato Basin.     

Interannual variation of the upper portion of the Japan Sea Proper Water and its probable cause

The long-term variation of water properties in the upper portion of the Japan Sea Proper Water (UJSPW) is examined on the basis of hydrographic data at PM10, located on the northwestern Japan Sea, and at PM05, in the Yamato Basin, taken from 1965 through 1982. At PM10, located at the southern boundary of the UJSPW formation region, dissolved oxygen fluctuations on the UJSPW core showed negative correlation with phosphate variations, but showed no signficant correlation with salinity variations. At PM05 water properties fluctuated with smaller amplitudes than those at PM10 except for salinity. Dissolved oxygen variations at PM10 lead those at PM05 by 12–15 months, suggesting that the UJSPW near PM10 circulates into the Yamato Basin spending 12–15 months. Increases of dissolved oxygen contents in summer on relevant isopycnal surfaces at PM10 occurred after cold and/or windy winters except for two of eight; this suggests that larger volume of the UJSPW is formed in severa winter. Rough estimations of the formation rate and existing volume of the UJSPW are made on the basis of a climatological dataset; 1.5×10⁴ km³ yr^–1 and 27.3×10⁴ km³, respectively. The ventilation time of the UJSPW, 18.2 years, is about one tenth or less of residence time for the entire Japan Sea Proper Water. This indicates that the UJSPW is renewed about ten times as quick as the deeper water.