Mechanisms and pathways of lateral flow on aspen‐forested,Luvisolic soils,Western Boreal Plains,Alberta, Canada

Rainfall simulation experiments by Redding and Devito ( 2008 , Hydrological Processes 23: 4287–4300) on two adjacent plots of contrasting antecedent soil moisture storage on an aspen‐forested hillslope on the Boreal Plain showed that lateral flow generation occurred only once large soil storage capacity was saturated combined with a minimum event precipitation of 15–20 mm. This paper extends the results of Redding and Devito ( 2008 , Hydrological Processes 23: 4287–4300) with detailed analysis of pore pressure, soil moisture and tracer data from the rainfall simulation experiments, which is used to identify lateral flow generation mechanisms and flow pathways. Lateral flow was not generated until soils were wet into the fine textured C horizon. Lateral flow occurred dominantly through the clay‐rich Bt horizon by way of root channels. Lateral flow during the largest event was dominated by event water, and precipitation intensity was critical in lateral flow generation. Lateral flow was initiated as preferential flow near the soil surface into root channels, followed by development of a perched water table at depth, which also interacted with preferential flow pathways to move water laterally by the transmissivity feedback mechanism. The results indicate that lateral flow generated by rainfall on these hillslopes is uncommon because of the generally high available soil moisture storage capacity and the low probability of rainfall events of sufficient magnitude and intensity. Copyright © 2010 John Wiley & Sons, Ltd.     

Delineation of capture zones for municipal wells in fractured dolomite, Sturgeon Bay, Wisconsin, USA

A wellhead protection study for the city of Sturgeon Bay, Wisconsin, USA, demonstrates the necessity of combining detailed hydrostratigraphic analysis with groundwater modeling to delineate zones of contribution for municipal wells in a fractured dolomite aquifer. A numerical model (MODFLOW) was combined with a particle tracking code (MODPATH) to simulate the regional groundwater system and to delineate capture zones for municipal wells. The hydrostratigraphic model included vertical and horizontal fractures and high-permeability zones. Correlating stratigraphic interpretations with field data such as geophysical logs, packer tests, and fracture mapping resulted in the construction of a numerical model with five high-permeability zones related to bedding planes or facies changes. These zones serve as major conduits for horizontal groundwater flow. Dipping fracture zones were simulated as thin high-permeability layers. The locations of exposed bedrock and surficial karst features were used to identify areas of enhanced recharge. Model results show the vulnerability of the municipal wells to pollution. Capture zones for the wells extend several kilometers north and south from the city. Travel times from recharge areas to all wells were generally less than one year. The high seasonal variability of recharge in the study area made the use of a transient model necessary. Electronic Publication     

Precambrian plate tectonics: The midcontinent gravity high

Examination of the shape of the midcontinent gravity high of central North America has led to the hypothesis that the Keweenawan rift system that caused it is the result of plate tectonic interaction. A numerical test has been carried out on the width and postulated transform fault offsets of the gravity high. The exactness of fit to a plate tectonic geometry implies that the continental lithosphere behaved as rigid plates during the Late Precambrian, about 1.1 by ago. This exactness of fit also suggests that the total amount of separation on the Keweenawan rifts is equal to the width of the gravity high. Gravity modelling studies bear out the plausibility of a major amount of rifting, up to 90 km under central Lake Superior. The midcontinent gravity high may represent an intermediate stage of continental rifting, since similar gravity highs and strong associated magnetic anomalies are found on the modern rifted margins of the Atlantic Ocean.     

Experimental cpx/melt partitioning of 24 trace elements

Cpx/melt partition coefficients have been determined by ion probe for 24 trace elements at natural levels in an alkali basalt experimentally equilibrated at 1,380°C and 3 GPa. One goal was to intercompare Ds for both high-field-strength elements and rare earth elements (REE) in a single experiment. Relative to the REE spidergram, Hf and Ti show virtually no anomaly, whereas Zr exhibits a major negative anomaly. Other incompatible elements (Ba, K, Nb) fall in the range of published values, as do elements such as Sr, Y, Sc, Cr and V. Pb shows a value intermediate between La and Ce. Values for Be, Li and Ga are reported for the first time, and show that Be is as incompatible as the light REEs whereas Li and Ga are somewhat more compatible than the heavy REE.     

Using logistic regression to merge mineral resource databases

The purpose of this project was to develop and test a methodology for determining the likelihood that mineral resource location records from two nationwide mineral resource information databases represent the same site. The long-term goal is to create a comprehensive database by merging the Mineral Resource Data System (MRDS) of the U.S. Geological Survey, and the Mineral Availability System/Mineral Industry Location System (MAS/MILS) of the U.S. Bureau of Mines (now part of the Geological Survey). Part of that process involves linking records for the same site from each database. Match probabilities were estimated using a logistic regression of mineral resource location attributes, derived from known matched (cross-referenced) and known unmatched randomly sampled mineral site pairs from within the conterminous United States (n=10,000). Model accuracy was assessed using a randomly sampled test dataset, not used in logistic model development (n=4,000). Probability distributions were similar between the development and test datasets. The overall agreement beyond chance was good for the test data set using the kappa statistic. Classification accuracy was 89.6% for known matched site pairs and 84.0% for known unmatched site pairs based on a probability threshold of 0.50 for a match. Distributions of attributes were similar between the development and test datasets. This classification method is a viable approach for estimating match probabilities between database records.     

Organic carbon and cation associations in humic material from pond water and sediment

Organic matter was isolated from the water columns and sediments of two pond systems in the south-eastern United States. Water column material was ultrafiltered to provide three fractions, i.e. <0.45 μm, but > 50,000 daltons; <50,000 daltons, but > 5000 daltons; and <5000 daltons. Sedimentary organic matter was separated into humic acid and fulvic acid fractions based on solubility criteria and the humic acid fraction was ultrafiltered to provide the same fractions as the water column isolates. All fractions were analysed for organic carbon, Al, Ca, Cu, Fe, Mg and Mn. Infra-red spectra were also measured for the sedimentary organic fractions. Organic matter isolated from the water column of the two ponds had similar organic carbon and elemental distributions, as did the organic matter isolated from the two sediments. However, significant differences in the organic carbon and elemental distributions were observed for water column and sedimentary organic matter isolated from the same pond. These studies have relevance to diagenetic alterations of organic matter and geochemical cycles of elements within lakes.