Mercury emission from terrestrial background surfaces in the eastern USA. Part I: Air/surface exchange of mercury within a southeastern deciduous forest (Tennessee) over one year

This study focused on the development of a seasonal data set of the Hg air/surface exchange over soils associated with low Hg containing surfaces in a deciduous forest in the southern USA. Data were collected every month for 11 months in 2004 within Standing Stone State Forest in Tennessee using the dynamic flux chamber method. Mercury air/surface exchange associated with the litter covered forest floor was very low with the annual mean daytime flux being 0.4 ± 0.5 ng m⁻² h⁻¹ (n = 301). The daytime Hg air/surface exchange over the year oscillated between emission (81% of samples with positive flux) and deposition (19% of samples with negative flux). A seasonal trend of lower emission in the spring and summer (closed canopy) relative to the fall and winter (open canopy) was observed. Correlations were found between the air/surface exchange and certain environmental factors on specific days sampled but not collectively over the entire year. The very low magnitude of Hg air/surface exchange as observed in this study suggests that an improved methodology for determining and reporting emission fluxes is needed when the values of fluxes and chamber blanks are both very low and comparable. This study raises questions and points to a need for more research regarding how to scale the Hg air/surface exchange for surfaces with very low emissions.     

Mercury emission from terrestrial background surfaces in the eastern USA. II: Air/surface exchange of mercury within forests from South Carolina to New England

Mercury air/surface exchange was measured over litter-covered soils with low Hg concentrations within various types of forests along the eastern seaboard of the USA. The fieldwork was conducted at six forested sites in state parks in South Carolina, North Carolina, New Jersey, Pennsylvania, New York and Maine from mid-May to early June 2005. The study showed that the Hg air/surface exchange was consistently very low and similar (overall daytime mean flux = 0.2 ± 0.9 ng m⁻² h⁻¹, n = 310, for all six sites monitored) with the various forest types. These flux values are comparable with those found in a year-long study in Tennessee (yearly daytime mean = 0.4 ± 0.5 ng m⁻² h⁻¹), but lower than many previous flux results reported for background soils. The Hg fluxes at all sites oscillated around zero, with many episodes of deposition (negative fluxes) occurring in both daytime and nighttime. While there were particular days showing significant correlations among the Hg air/surface exchange and certain environmental parameters, perhaps because of the low fluxes encountered, few significant correlations were found for any particular day of sampling between the Hg flux and environmental parameters such as solar radiation, soil temperature, air temperature (little variability seen), relative humidity, and ambient air Hg concentrations. Factors driving the Hg exchange as previously found for enriched soils may not hold for these background litter-covered forest soils. The results suggest that spatial variations of the Hg air/surface exchange were small among these different forest types for this particular time of year.     

Preliminary availability assessment to support single-frequency SBAS development in the Korean region

Satellite-Based Augmentation Systems (SBASs) enhance the global navigation satellite system (GNSS) to support all phases of flight by providing required accuracy, integrity, continuity, and availability. The Korean SBAS program was recently initiated to develop a single-frequency SBAS aiming to provide Approach Procedure with Vertical guidance (APV)-I Safety-of-Life (SoL) service to aviation users by 2022 within the Korean region. We assess the preliminary availability of the single-frequency SBAS which will be deployed in the Korean peninsula. The resulting system performance shall be used as a baseline to design system components and specifications. The fundamental components of SBAS architecture, SBAS monitor network, geostationary earth orbiting satellite parameters, and ionospheric grid point mask, are defined and their effects on system performance are investigated. Ionospheric correction and integrity algorithm parameters including an ionospheric irregularity threat model are determined using data collected from the Korean GNSS network. The coverage of 99.9 % availability for APV-I service increases from approximately 70 % for the baseline case to 100 % when SBAS monitor stations are expanded to overseas. Even with the expanded monitor network, however, 90 % and less than 95 % availability for LPV-200 service can be achieved only in a very limited region.     

Tropical cyclone Ivan’s tornado cluster in the Mid-Atlantic region of the United States on 17–18 September 2004

This paper presents a case study of a cluster of tornadoes produced by tropical cyclone (TC) Ivan in the Mid-Atlantic region of the United States on 17–18 September 2004. Ivan produced 118 tornadoes between 15 and 18 September, but 57 of these occurred in a period of only 10 h on the last two days. The number of tornadoes that occurred in this event is anomalous when compared to regional tornado climatology and to other TC tornado events. Furthermore, a significantly large number of the tornadoes, when compared to other TC tornadoes, were rated strong according to the Fujita Scale, and they were anomalously long- and wide-tracked. Ivan was in a synoptically favorable environment when these tornadoes were produced, and the tornadoes occurred in a favorable local-scale environment near a front with spatially overlapping shear and buoyancy.     

A tale of two wave trains

The present study is an investigation into the transfer of the wave energy as it propagates through the surf zone and the consequent evolution of the wave trains and the corresponding envelope of the wave trains. The generation of long wave energy is investigated and one approach to developing the nonlinear transfer function for the transformation process is attempted. A nondimensionalized format for expressing the data is suggested for clarifying future studies of this type.     

The distributions of uranium, radium and thorium isotopes in two anoxic fjords: Framvaren Fjord (Norway) and Saanich Inlet (British Columbia)

Depth profiles of the naturally-occurring radionuclides ²³⁸U, ²³⁴U, ²²⁶Ra, ²²⁸Ra and ²²⁸Th were obtained in two diverse anoxic marine environments; the permanently anoxic Framvaren Fjord in southern Norway and the intermittently anoxic Saanich Inlet in British Columbia. Concentrations of total H₂S were over three orders of magnitude greater in the anoxic bottom waters of Framvaren Fjord compared to those in Saanich Inlet.In Framvaren Fjord, the O₂/H₂S interface was located at 17 m. While dissolved ²³⁸U behaved conservatively throughout the oxic and anoxic water columns, concentrations based on the ²³⁸U/salinity ratio in oxic oceanic waters were almost 30% lower. Dissolved ²²⁶Ra displayed a sharp maximum just below the O₂/H₂S interface, coinciding with dissolved Mn (II) and Fe (II) maxima in this zone. It is suggested that reductive dissolution of Fe-Mn oxyhydroxides remobilizes ²²⁶Ra in this region.In Saanich Inlet, the O₂/H₂S interface was located at 175 m. Dissolved ²³⁸U displayed a strongly nonconservative distribution. The depth profiles of dissolved ²²⁶Ra and ²²⁸Th correlated well with the distribution of dissolved Mn (II) in the suboxic waters above the O₂/H₂S interface, suggesting that reduction of particulate Mn regulates the behavior of ²²⁶Ra and ²²⁸Th in this region.Removal residence times for dissolved ²²⁸Th in the surface oxic waters of both systems are longer than those generally reported for particle-reactive radionuclides in coastal marine environments. In the anoxic waters of Framvaren Fjord and Saanich Inlet, however, the dissolved ²²⁸Th removal residence times are quite similar to values reported for dissolved ²¹⁰Pb in the anoxic waters of the Cariaco Trench and the Orca Basin. This implies that the geochemistries of Th and Pb may be similar in anoxic marine waters.