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251.
We derive a macroscopic model for single-phase, incompressible, viscous fluid flow in a porous medium with small cavities called vugs. We model the vuggy medium on the microscopic scale using Stokes equations within the vugular inclusions, Darcy's law within the porous rock, and a Beavers–Joseph–Saffman boundary condition on the interface between the two regions. We assume periodicity of the medium and obtain uniform energy estimates independent of the period. Through a two-scale homogenization limit as the period tends to zero, we obtain a macroscopic Darcy's law governing the medium on larger scales. We also develop some needed generalizations of the two-scale convergence theory needed for our bimodal medium, including a two-scale convergence result on the Darcy–Stokes interface. The macroscopic Darcy permeability is computable from the solution of a cell problem. An analytic solution to this problem in a simple geometry suggests that: (1) flow along vug channels is primarily Poiseuille with a small perturbation related to the Beavers–Joseph slip, and (2) flow that alternates from vug to matrix behaves as if the vugs have infinite permeability. 相似文献
252.
James C. Mills IV John T. Wilson Barbara H. Wilson Todd H. Wiedemeier David L. Freedman 《Ground Water Monitoring & Remediation》2018,38(2):57-67
Bacteria that degrade natural organic matter in groundwater contain oxygenase enzymes that can co‐oxidize trichloroethene (TCE). This degradation pathway is promising for large dilute plumes, but its evaluation is limited because the density of the bacteria with oxygenase enzymes has not been correlated to field scale rates of degradation. A 14C–TCE assay was developed to determine pseudo first‐order rate constants for the aerobic co‐oxidation of TCE in groundwater. The assay involved incubating 14C–TCE in samples of groundwater contained in 160 mL serum bottles, and monitoring the accumulation of radiolabel in degradation products. A first‐order rate constant for co‐oxidation was extracted from the rate of accumulation of 14C in products, accounting for volumetric changes in the serum bottles due to sampling and subsequent changes to the distribution of TCE between the aqueous and gaseous phases. Of the groundwater samples evaluated from 19 wells at five sites, eight samples at three sites had 14C product accumulation rates that exceeded the accumulation rate in filter‐sterilized groundwater controls. First‐order rate constants ranged from 2.65 to 0.0066 year?1, which is equivalent to half‐lives of 0.26 to 105 years. Groundwater samples from a few of the wells in which co‐oxidation occurred had volatile organic contaminants in addition to TCE; their presence may have induced the oxygenase enzymes that are needed for TCE co‐oxidation. 14CO2 represented ~37% to 97% of the 14C products that accumulated; the balance of the products was soluble and non‐volatile. 相似文献
253.
Todd H. Wiedemeier Barbara H. Wilson Mark L. Ferrey John T. Wilson 《Ground Water Monitoring & Remediation》2017,37(2):25-34
Magnetite is a natural component of many aquifers. Abiotic degradation of chlorinated solvents by magnetite can be an important mechanism for natural attenuation of these contaminants. The quantity of magnetite in aquifer materials can be estimated by measuring the magnetic susceptibility of the materials. This is most commonly done by determining the magnetic susceptibility of core samples in an analytical laboratory using a magnetic susceptibility meter. Unfortunately, the cost of acquiring core samples often makes an evaluation of abiotic degradation by magnetite economically unrealistic. Downhole sondes (probes) are available for the determination of magnetic susceptibility. In this study, a downhole sonde was evaluated as an affordable alternative to acquiring and analyzing core samples. The sonde was introduced into 10 monitoring wells. The data from the sonde were then compared to data from core samples that were collected from the same elevation as the sonde data. The core samples analyzed in the laboratory were used as the standard against which the sonde data were compared. The downhole sonde reported values that were similar to values reported on core samples. At most wells, the means of the two measurements could not be distinguished at the 95% confidence interval. When the means could be distinguished, they still agreed within a factor of two. 相似文献
254.
To determine body and tissue compartment-specific burdens (mg) of total mercury (THg), tissues were weighed and analyzed for THg concentration (microg/g fw) in Pacific harbor seal (Phoca vitulina richardii) pups from central California in 2006. THg concentrations were related as follows: hair > liver = kidney = pelt > muscle > other = heart > brain > blubber > bone. THg burden, however, was related as: pelt = muscle > liver = other > kidney = blubber > brain = heart > bone. THg concentration and burden in muscle were strongly associated with delta(15)N. delta(13)C and delta(15)N values were significantly greater in muscle than liver, and delta(13)C was significantly lesser the longer animals were in rehabilitation. Because THg concentration and burden in muscle correlated most significantly with other tissue compartments, we recommend that muscle from the specific sites we sampled be used instead of liver or hair for biomonitoring THg in harbor seals. Assessment of proportional THg burdens within each tissue compartment for harbor seals pups included use of a conceptual model, allowing for more complete visual characterization of THg body burden. 相似文献
255.
Glibert PM Azanza R Burford M Furuya K Abal E Al-Azri A Al-Yamani F Andersen P Anderson DM Beardall J Berg GM Brand L Bronk D Brookes J Burkholder JM Cembella A Cochlan WP Collier JL Collos Y Diaz R Doblin M Drennen T Dyhrman S Fukuyo Y Furnas M Galloway J Granéli E Ha DV Hallegraeff G Harrison J Harrison PJ Heil CA Heimann K Howarth R Jauzein C Kana AA Kana TM Kim H Kudela R Legrand C Mallin M Mulholland M Murray S O'Neil J Pitcher G Qi Y Rabalais N Raine R Seitzinger S Salomon PS Solomon C 《Marine pollution bulletin》2008,56(6):1049-1056
The proposed plan for enrichment of the Sulu Sea, Philippines, a region of rich marine biodiversity, with thousands of tonnes of urea in order to stimulate algal blooms and sequester carbon is flawed for multiple reasons. Urea is preferentially used as a nitrogen source by some cyanobacteria and dinoflagellates, many of which are neutrally or positively buoyant. Biological pumps to the deep sea are classically leaky, and the inefficient burial of new biomass makes the estimation of a net loss of carbon from the atmosphere questionable at best. The potential for growth of toxic dinoflagellates is also high, as many grow well on urea and some even increase their toxicity when grown on urea. Many toxic dinoflagellates form cysts which can settle to the sediment and germinate in subsequent years, forming new blooms even without further fertilization. If large-scale blooms do occur, it is likely that they will contribute to hypoxia in the bottom waters upon decomposition. Lastly, urea production requires fossil fuel usage, further limiting the potential for net carbon sequestration. The environmental and economic impacts are potentially great and need to be rigorously assessed. 相似文献
256.
Vector magnetic field synoptic charts from the Helioseismic and Magnetic Imager (HMI) are now available for each Carrington Rotation (CR) starting from CR 2097 in May 2010. Synoptic charts are produced using 720-second cadence full-disk vector magnetograms remapped to Carrington coordinates. The vector field is derived from the Stokes parameters (\(I, Q, U, V\)) using a Milne–Eddington-based inversion model. The \(180^{\circ}\) azimuth ambiguity is resolved using the minimum energy algorithm for pixels in active regions and for strong-field pixels (the field is greater than about 150 G) in quiet-Sun regions. Three other methods are used for the rest of the pixels: the potential-field method, the radial acute-angle method, and the random method. The vector field synoptic charts computed using these three disambiguation methods are evaluated. The noise in the three components of the vector magnetic field is generally much higher in the potential-field method charts. The component noise levels are significantly different in the radial-acute charts. However, the noise levels in the random-method charts are lower and comparable. The assumptions used in the potential-field and radial-acute methods to disambiguate the weak transverse field introduce bias that propagates differently into the three vector-field components, leading to unreasonable pattern and artifacts, whereas the random method appears not to introduce any systematic bias. The current sheet on the source surface, computed using the potential-field source-surface model applied to random-method charts, agrees with the best solution (the result computed from the synoptic charts with the minimum energy algorithm applied to each and every pixel in the vector magnetograms) much better than the other two. Differences in the synoptic charts determined with the best method and the random method are much smaller than those from the best method and the other two. This comparison indicates that the random method is better for vector field synoptic maps computed from near-central meridian data. The vector field synoptic charts provided by the Joint Science Operations Center (JSOC) are therefore produced with the random method. 相似文献
257.
The impact of a non-rigid seafloor on the wave climate at Cassino Beach, Brazil, May–June 2005 is studied using field measurements and a numerical wave model. The measurements consist of wave data at four locations; rheology and mud thickness from grab samples; and an estimate of the horizontal distribution of mud based on echo-soundings. The dissipation of waves by a non-rigid bottom is represented in the wave model by treating the mud layer as a viscous fluid. Applied for 431 time periods, the model without this type of dissipation has a strong tendency to overpredict nearshore wave energy, except during a period of large storm waves. Two model variations which include this dissipation have a modest tendency to underpredict the nearshore wave energy. An inversion methodology is developed and applied to infer an alternate mud distribution which, when used with the wave model, yields the observed waveheights. 相似文献
258.
259.
Siti M. Yaakub Eugene Chen Tjeerd J. Bouma Paul L.A. Erftemeijer Peter A. Todd 《Marine pollution bulletin》2014
Seagrasses have substantial capacity to survive long periods of light reduction, but how acclimation to chronic low light environments may influence their ability to cope with additional stress is poorly understood. This study examines the effect of temporal light reduction by adding two levels of shading to Halophila ovalis plants in two meadows with different light histories, one characterized by a low light (turbid) environment and the other by a relatively high light (clear) environment. Additional shading resulted in complete mortality for both shading treatments at the turbid site while the clear site showed a pattern of decreased shoot density and increased photochemical efficiency (Fv/Fm) with increased shading. These contrasting results for the same species in two different locations indicate that acclimation to chronic low light regimes can affect seagrass resilience and highlights the importance of light history in determining the outcome of exposure to further (short-term) stress. 相似文献
260.
Comments and Corrections to: “The Emperor's Old Clothes: An Inconvenient Truth About Currently Accepted Vapor Intrusion Assessment Methods,” and “Emperor's Old Clothes Revisited,” Two Recent Editorials by Mark Kram 总被引:1,自引:0,他引:1 下载免费PDF全文