OPA 90's impact at reducing oil spills

OPA 90 set out stringent requirements and liabilities for tankers operating in US national waters. OPA 90 was in response to the public concern caused by the grounding of the Exxon Valdez in 1989. It made ship owners responsible for the cost of pollution incidents and required all tank ships/barges operating in US waters have double hulls by 2015. We model factors influencing oil spills and test whether OPA 90 helped reduce the number of those spills. After accounting for causal factors, both increased liability and double hulls were statistically significant factors in reducing the number of spills.     

Method‐dependent influence of environmental variables on reef fish assemblages when comparing trap and video surveys

Despite substantial survey effort and a large body of literature on abiotic and biotic factors in temperate reef ecosystems, knowledge of the complex and interactive effects of environmental variables on those communities is limited. Various survey methods have been developed to study environmental predictors of biodiversity, but there remains a gap in our understanding of how survey results are influenced by environmental factors. Here, we surveyed the fish assemblage associated with southeastern U.S. temperate marine reefs with simultaneous, paired trap, and camera gears throughout a ~50,000 km² area during 2011–2013 and assessed the influence of environmental variables on the trap‐ and video‐surveyed assemblages. Predictor variables in the multivariate general linear models included depth, temperature, month, year, location, substrate relief, percent sessile biota, biota type, and turbidity. Depth and latitude had the greatest influence on the fish assemblage for both gears. The influence of habitat variables differed between methods and percent biota explained more variation in the fish assemblage when assessed by traps, while substrate relief and biota type explained more variation in the fish assemblage when assessed by video. In general, habitat complexity was positively related to the abundance of fishes in the video survey, but there was a negative relationship in the trap survey. Differences between gears were species‐specific and the influences of environmental variables were similar for some species such as Haemulon plumierii and Hyporthodus niveatus. The methods presented here can be used to assess method‐dependent differences in fish assemblages, which is a necessary precursor to assess the effect of environmental variables on the accuracy of surveys.     

GIS Course Planning: A Comparison of Syllabi at US College and Universities

Despite the enormous growth of college courses dealing with spatial information, curriculum planning involving geographic information science (GIS) courses and programs has received little attention within the GIS literature. As the number and variety of GIS courses expands, so too does the importance of both systematic and inclusive planning and campus‐wide coordination. In this article we explore course planning through an exploration of 312 GIS course syllabi used at US colleges and universities with the goal of characterizing the degree to which learning resources, student evaluation methods, and course topics have become standardized across institution types, academic levels, and disciplines. Our findings reveal a consensus in the use of GIS software across courses but no similar agreement in the use of textbooks. Hands‐on activities were used as evaluation methods in nearly every course in the sample regardless of institution type or academic level. However, quizzes, tests and final exams were used more often in community colleges while papers and projects were used more frequently in four‐year and comprehensive research universities. The frequency of topic categories listed on syllabi was relatively consistent across institutions, academic levels and disciplines with a few topics such as vector analytic operations, data models, and data creation/acquisition/editing included on more than 50% of syllabi.     

The characterization of axenic culture systems suitable for plant propagation and experimental studies of the submersed aquatic angiospermPotamogeton pectinatus (Sago Pondweed)

Clonal lines of the submersed aquatic angiospermPotamogeton pectinatus were grown in three culture systems. The first, which used sucrose as a carbon source in a liquid medium, supported vigorous vegetative growth and can be used to propagate large numbers of plants in axenic conditions. In this culture system, plants were responsive to increasings photosynthetically active radiation (PAR) photon flux density (PFD) and were photosynthetically competent. However, their growth was heterotrophic and root development was poor. When these plants were transferred to a second nonaxenic culture system, which used 16-1 buckets containing artificial sediments and tap water, growth was autotrophic and plants were morphologically identical to field-harvestedP. pectinatus. The last culture system which consisted of a sand substrate and inorganic nutrient bathing solution aerated with 135 ml min^?1 ambient air enhanced to 3.0% CO₂ was axenic and supported autotrophic growth by plants that were also morphologically normal.     

A discontinuous Galerkin method for two-phase flow in a porous medium enforcing H(div) velocityand continuous capillary pressure

We consider the slightly compressible two-phase flow problem in a porous medium with capillary pressure. The problem is solved using the implicit pressure, explicit saturation (IMPES) method, and the convergence is accelerated with iterative coupling of the equations. We use discontinuous Galerkin to discretize both the pressure and saturation equations. We apply two improvements, which are projecting the flux to the mass conservative H(div)-space and penalizing the jump in capillary pressure in the saturation equation. We also discuss the need and use of slope limiters and the choice of primary variables in discretization. The methods are verified with two- and three-dimensional numerical examples. The results show that the modifications stabilize the method and improve the solution.     

Seasonal Forecasting for Climate Hazards: Prospects and Responses

One of the most promising developments for early warning of climate hazards is seasonal climate forecasting. Already forecasts are operational in many parts of the tropics and sub-tropics, particularly for droughts and floods associated with ENSO events. Prospects for further development of seasonal forecasting for a range of climatichazards are reviewed, illustrated with case studies in Africa, Australia, the U.S.A. and Europe. A critical evaluation of the utility of seasonal forecasts centres on vulnerability, communicationchannels, and effective responses. In contrast to short-term prediction, seasonal forecasts raise new issues of preparedness and the use of information.     

Surface oxidation of pyrite under ambient atmospheric and aqueous (pH = 2 to 10) conditions: electronic structure and mineralogy from X-ray absorption spectroscopy

The nature of the surface oxidation phase on pyrite, FeS₂, reacted in aqueous electrolytes at pH = 2 to 10 and with air under ambient atmospheric conditions was studied using synchrotron-based oxygen K edge, sulfur L_III edge, and iron L_II,III edge X-ray absorption spectroscopy. We demonstrate that O K edge X-ray absorption spectra provide a sensitive probe of sulfide surface oxidation that is complementary to X-ray photoelectron spectroscopy. Using total electron yield detection, the top 20 to 50 Å of the pyrite surface is characterized. In air, pyrite oxidizes to form predominantly ferric sulfate. In aqueous air-saturated solutions, the surface oxidation products of pyrite vary with pH, with a marked transition occurring around pH 4. Below pH = 4, a ferric (hydroxy)sulfate is the main oxidation product on the pyrite surface. At higher pH, we find iron(III) oxyhydroxide in addition to ferric (hydroxy)sulfate on the surface. Under the most alkaline conditions, the O K edge spectrum closely resembles that of goethite, FeOOH, and the surface is oxidized to the extent that no FeS₂ can be detected in the X-ray absorption spectra. In a 1.667 × 10⁻³ mol/L Fe³⁺ solution with ferric iron present as FeCl₃ in NaCl, the oxidation of pyrite is autocatalyzed, and formation of the surface iron(III) oxyhydroxide phase is promoted at low pH.     

Lithostratigraphy and structure of the old red sandstone of the Northern Dingle Peninsula,Co. Kerry,Southwest Ireland

The lower part of the Old Red Sandstone in the Dingle Penisula has been previously assigned to one lithostratigraphic group (Dingle Group) despite marked variations in sedimentary facies. However the apparently oldest non-marine sequence in the northwest of the peninsula has sedimentary and lithological attributes that contrast strongly with those of the late Silurian-early Devonian Dingle Group to the south. This northern sequence, here renamed the Smerwick Group, evolved independently of the Dingle Group in a separate basin of deposition. Field relationships between the two groups in the north of the peninsula are interpreted as indicating that the Smerwick Group overlies, with angular unconformity, a normal Dingle Group succession. Similarly, it is argued that the Smerwick Group overlies, with angular unconformity, the Dingle Group in the northwest of the peninsula, but there the Dingle Group is attenuated, represented only by a conglomerate unit some 10 m thick. In the absence of biostratigraphic evidence the age of the Smerwick Group is poorly constrained. Nevertheless, we propose a tectonic model that suggests that the Smerwick Group evolved within a small extensional half-graben on the northern margin of the Munster Basin. This model accounts for the stratigraphic and structural relationships observed, and implies that the Smerwick Group is of Late Devonian age.     

Glacier fluctuations in the southern Peruvian Andes during the late‐glacial period,constrained with cosmogenic 3He

The occurrence of pronounced climate reversals during the last glacial termination has long been recognised in palaeoclimate records from both hemispheres and from high to low latitudes. Accurate constraint of both the timing and magnitude of events, such as the Younger Dryas and Antarctic Cold Reversal, is vital in order to test different hypotheses for the causes and propagation of abrupt climate change. However, in contrast to higher‐latitude regions, well‐dated records from the Tropics are rare and the structure of late‐glacial tropical climate remains uncertain. As a step toward addressing this problem, we present an in situ cosmogenic ³He surface exposure chronology from Nevado Coropuna, southern Peru, documenting a significant fluctuation of the ice margin during the late‐glacial period. Ten tightly clustered ages from a pair of moraines located halfway between the modern glacier and the Last Glacial Maximum terminus range from 11.9 to 13.9 ka and give an arithmetic mean age of 12.8 ± 0.7 ka (1σ). These data constitute direct evidence for a readvance, or prolonged stillstand, of glaciers in the arid Andes of southwestern Peru. Copyright © 2011 John Wiley & Sons, Ltd.     

A computational method for approximating a Darcy–Stokes system governing a vuggy porous medium

We develop and analyze a mixed finite element method for the solution of an elliptic system modeling a porous medium with large cavities, called vugs. It consists of a second-order elliptic (i.e., Darcy) equation on part of the domain coupled to a Stokes equation on the rest of the domain, and a slip boundary condition (due to Beavers–Joseph–Saffman) on the interface between them. The tangential velocity is not continuous on the interface. We consider a 2-D vuggy porous medium with many small cavities throughout its extent, so the interface is not isolated. We use a certain conforming Stokes element on rectangles, slightly modified near the interface to account for the tangential discontinuity. This gives a mixed finite element method for the entire Darcy–Stokes system with a regular sparsity pattern that is easy to implement, independent of the vug geometry, as long as it aligns with the grid. We prove optimal global first-order L ² convergence of the velocity and pressure, as well as the velocity gradient in the Stokes domain. Numerical results verify these rates of convergence and even suggest somewhat better convergence in certain situations. Finally, we present a lower dimensional space that uses Raviart–Thomas elements in the Darcy domain and uses our new modified elements near the interface in transition to the Stokes elements.