Production of a molybdophore during metal-targeted dissolution of silicates by soil bacteria

Although many bioessential metals are scarce in natural water and rock systems, microbial secretion of high-affinity ligands for metal extraction from solid phases has only been documented for Fe. However, we have discovered that Mo is extracted from a silicate by a high-affinity ligand (a possible “molybdophore”) secreted by an N₂-fixing soil bacterium. The putative molybdophore, aminochelin, is secreted as a siderophore under Fe-depleted conditions, but is also secreted under Fe-sufficient, Mo-depleted conditions. Presumably, molybdophore production facilitates uptake of Mo for use in Mo enzymes. In contrast, an Fe-requiring soil bacterium without a special Mo requirement only enhances the release of Fe from the silicate. Fractionation of Mo stable isotopes during uptake to cells may provide a “fingerprint” for the importance of chelating ligands in such systems. Many such metal-specific ligands secreted by prokaryotes for extraction of bioessential metals, their effects on Earth materials, and their possible utility in the recovery of economic metals remain to be discovered.     

The stratigraphy of Ordovician volcanic rocks on the southern and eastern flanks of the Harlech Dome in Merionethshire

The stratigraphy of nine areas of Ordovician volcanic rocks flanking the Harlech Dome is dcscribed and a correlation of the Ordoyician volcanic succession from Arenig to Cader Idris proposed. Nine formations are distinguished which together form a distinct lithostratigraphic unit termed the Aran Volcanic Group. At least six disconformities can bc recognised within the Group.     

Beobachtungsergebnisse der Berliner Arbeitsgemeinschaft für veränderliche Sterne e. V. (BAV)

In this 8th compilation, the following results of observations are given: 207 observed minima of 56 eclipsing binaries, 100 maxima of 21 RR Lyrae- and δ Cephei-stars, 82 results of 32 Mira stars and long period variables, and 47 results of 9 RV Tauri stars, semiregular, and irregular variables, from the years 1966 up to 1968.     

The ordovician and other post-rosslare series Rocks in Southeast Co. Wexford

Ordovician sediments at Tagoat and Rosslare Harbour are re-described and their relationship to the underlying Rosslare Series discussed. A brief outline of their petrology is given, but it is shown that the fauna is in need of revision before reliable correlations can be made. Similar rocks are recorded near Tomhaggard; amongst these, spotted mudstones imply Ordovician or later intrusions. Undeformec dykes intrusive into the Rosslare Series are believed to be representatives of this phase.     

Copper(II) humate mobility in kaolinite soil

An investigation of the influence of humate on the mobility of copper(II) ions in a kaolinite soil using leaching tests and electrokinetic experiments is reported. The data are interpreted in terms of humate–copper–clay interactions and humate electrical charge. Humate is mostly immobile below pH8 but is more mobile in alkaline conditions (sorption to kaolinite reduces its mobility in neutral conditions). Copper humate complexes are mobile in both acidic and alkaline conditions, but not in neutral conditions where they are sorbed. The dissolved copper humate complexes that form in acidic conditions are positively charged. The net effect of humate is to increase cupric ion mobility in kaolinite soil, especially in alkaline conditions.