长江三峡地区成冰纪-埃迪卡拉纪转换时期微量元素和稀土元素地球化学特征

通过微量元素和稀土元素地球化学分析,对长江三峡地区陡山沱组层型剖面--田家园子剖面成冰系南沱组顶部和埃迪卡拉系陡山沱组下部102个岩石样品进行了地球化学研究。重点分析了氧化还原敏感元素(Zn,Co,U,Mo,Ni,V)的富集特征,并探讨其可能成因机制以及三峡地区成冰纪-埃迪卡拉纪转换时期的水体特征。结果表明:在南沱组顶部仅Zn和Co富集;在盖帽白云岩下部,氧化还原敏感元素均富集,而在盖帽白云岩上部,除Zn和V外,其他氧化还原敏感元素均亏损;在陡山沱组Ⅱ段下部,氧化还原敏感元素由最初的亏损,逐渐变为较稳定的富集。在陡山沱组下部,出现2次明显的富集峰值,分别出现在剖面的0.4m处(盖帽白云岩中间)和6.5m处(陡山沱组Ⅱ段下部)。整个剖面大部分样品具有Eu的轻微正异常(Eu/Eu^*＜1.6), 而在剖面0.4m和6.5m处,Eu具有明显的正异常,结合稀土配分类型、Y/Ho值、La异常、Ce异常等指标,推测这2次异常均可能受到深海热液流的影响,而缺氧海水的上涌造成水体缺氧,导致这些元素出现富集峰值。U/Th、V/(V+Ni)以及稀土元素指标综合指示,三峡地区南沱组顶部冰碛岩应为氧化环境下的沉积物;随着冰川消融,冰融淡水注入古海洋,陡山沱组盖帽碳酸盐的沉积受冰融淡水的影响,深部缺氧海水的上涌使沉积水体经历氧化-缺氧-氧化的转变,海水的分层性较强;而陡山沱组Ⅱ段下部沉积环境以分层性较弱的弱氧化环境为主。     

晋冀低山丘陵区人工扰动植被花粉组合特征

54个晋冀低山丘陵区人工和人工扰动植被表土花粉样品分析表明:花粉组合以草本植物花粉(74.5％)为主,乔木花粉含量低于20％。人类活动较强的农田以谷物禾本科、蒿属和藜科花粉为主,人类活动较弱的荒地以蒿属、藜科和杂草禾本科花粉为主。人类活动强度不同,指示种不同,孢粉浓度亦不同;农田指示种为谷物禾本科、葡萄科和胡桃科,孢粉浓度约4380粒/g;而蒿属、蓼科和蔷薇科则为荒地指示种,孢粉浓度约10983粒/g。农作物种植方式不同,谷物禾本科花粉含量不同,单一禾本科作物种植区谷物禾本科花粉含量(40.2％)高于多种作物混作区(18.8％)和荒地(3.8％)的含量。谷物禾本科含量的变化可以为利用化石花粉提取和检测人类活动信息提供依据,也可为利用地层中谷物禾本科花粉判断古代农业活动提供依据。     

彬长矿区煤层气储层参数及开发潜力

彬长矿区煤的变质程度低,矿井瓦斯涌出量大,瓦斯治理形势日趋严峻。根据矿区地质勘查、井下及煤层气井所获得的地质资料显示,煤层气开发的主要目标4煤层厚度大,分布稳定,煤体结构好,渗透率和气含量相对较高,气含量最高可达6.29m3/t,估算煤层气资源量为132.743×108m3。依据煤层气资源丰度划分,矿区煤层气富集区总面积为87.41km2,资源量为40.06×108m3,主要分布在大佛寺井田,相对富集区主要位于胡家河井田中南部和孟村井田东部,贫气区主要位于孟村井田西部、文家坡井田。综合分析认为研究区煤层气开发地质条件相对较好,属于可以抽采煤层,大佛寺井田为地面煤层气勘探开发最具潜力的地区。     

Occurrence modes and cleaning potential of sulfur and some trace elements in a high-sulfur coal from Pu’an coalfield,SW Guizhou,China

In this research, a float-sink test was applied to a Late Permian high-sulfur coal collected from Pu’an coalfield, Southwest in Guizhou, China. To investigate the occurrence modes and the mobility of various trace elements, as well as the cleaning potential of some harmful elements in density separation, coal quality parameters and concentrations of 46 elements of 7 density fractionated samples were determined and statistically analyzed. Results show that larger size and higher density fractions have higher total sulfur content and ash yield than the smaller and lower ones. In fact, most (74.39 %) of the total sulfur occurs in the inorganic matter. Affinity and correlation analysis show that Mo and Ni have apparently strong organic affinity, whereas Rh, Cs, Sr, Co, Nb, Zr, V, Ga, Sc, Be, Ge, Hf, Th, U, Ag, As, In, Cu, Cd, Ta, Li, TI, and Ba are mostly in the heavy fractions. Rare earth element (REE) patterns for the seven density fractions present good uniformity and show that they are of right-inclined pattern type characterized by Light REE (LREE, La ~ Eu) enrichment relative to Heavy REE (HREE, Gd ~ Lu) and pronounced negative δ _Eu anomalies. This suggests that REE was mainly derived from basalt-weathered materials. LRREE/HREE ratio variations reveal that LREE has stronger affinity with the organic matter relative to the HREE, while high LRREE/HREE in heavy fractions may be related to pyrite. Supposing the maximum sulfur content of the cleaned coal is 1.00 %, the theoretical removal ratios of Co, TI, and Ba are as high as 90.94, 93.73, and 92.29 %, respectively, while those of As, Ni and Mo are only 56.33, 48.85, and 45.05 %, respectively. As these figures change with different maximum sulfur contents required for the cleaned coal, not only the decrease of sulfur and ash in coal washing, but also the mobility of some harmful trace elements should be taken into consideration.     

青海东昆仑哈日扎多金属矿区构造活动的锆石裂变径迹定年分析

青海省哈日扎多金属矿区位于东昆仑东段,属东昆中多旋回岩浆弧带,是新的矿产勘查基地,成矿作用主要受NE和NW向两组构造蚀变带控制。本文通过不同类型样品的锆石裂变径迹定年分析,探讨区内的构造活动。所获得的10个样品年龄为116~204 Ma,并由3个组年龄构成,即204~181 Ma,142~168 Ma和116~120 Ma。第1组年龄204~181 Ma反映印支晚期三叠纪末羌塘地块与昆仑地块碰撞的地质事件及其时限;后两组年龄主要是晚侏罗世~早白垩世冈底斯地体向北与羌塘地体碰撞汇聚的响应,活动时限为168~116 Ma。第2和3组年龄同时表明本区燕山期构造活动存在强度差异,即有两个强作用期。同时,3组年龄也揭示本区具有多期次成矿活动。     

东准造山带原泥盆系的形成时代及源区：碎屑锆石U-Pb年代学证据

新疆东准地区晚古生代地层出露广泛,其沉积时限的精确限定对理解中亚造山带的增生和拼贴过程、确立该地区构造框架及油气开发具有深远意义。然而,目前的研究主要集中于岩浆岩方面,对于晚古生代地层时代及其空间展布的研究则相对缺乏,特别是石炭系和泥盆系沉积地层标定较为模糊。为此,本文选取了3个原泥盆系砂岩进行了细致的野外剖面测制、岩石学观测和碎屑锆石U-Pb年代学分析。研究显示：原泥盆纪砂岩的最年轻碎屑锆石年龄为346～312 Ma,碎屑锆石年龄谱图分为：380～310 Ma（晚泥盆世-早石炭世,71.8%）、445～385 Ma（志留纪-早-中泥盆世,11.7%）、480～450 Ma（奥陶纪,3.9%）、540～485 Ma（寒武纪,4.5%）和前寒武纪年龄段（8.1%）,碎屑锆石年龄谱图区域上具有由南向北、由西向东呈简单化趋势且晚古生代年龄比重增加。结合该区岩浆岩年代学研究成果,将研究区原泥盆系沉积时代重新厘定到晚石炭系早-中期,认为东准地区的碰撞拼贴时间应发生于晚石炭世,并非是不同期次碰撞拼贴之产物。     

陆生植物氮同位素组成与气候环境变化研究进展

近年来,由于植物氮同位素组成(δ15N)记载了气候环境变化的信息,因而被广泛应用于全球变化研究中,成为古气候环境再造和了解现代气候环境变化信息的有力工具。然而,人们对气候环境引起的δ15N变化及其指示的气候环境意义并不完全清楚,这就有可能限制植物δ15N在古气候环境变化等领域研究中的应用。在概述植物氮同位素分馏和植物不同氮源的氮同位素分布的基础上,分析了温度、降水、大气CO2浓度和海拔高度等气候环境因子对陆生植物δ15N的影响以及它们的关系。指出了目前研究中存在的问题及其研究前景,认为在全球变化研究中利用植物氮同位素技术不仅可以重建古气候环境(如重建大气CO2浓度变化),揭示历史时期温度、降水的变化,而且还可以在一定的时间和空间上综合反映生态系统氮循环的特征。     

Recent Progresses in Comparative Planetology——Summary of the Session of Comparative Planetology at the 3rd Conference of Earth System Sciences

Comparative planetology is an interdisciplinary science between Earth sciences and astronomy. It studies physical, chemical and dynamical properties of planets and satellites and their surface characteristics, interior structures and chemistry, magnetic field, climate and possible existence of life. Although the study of comparative planetary science is at its infancy stage in China, it is very encouraging to see that 25 papers were received by the session, which is much more than what we expected. It indicates that more and more scientists are interested in this research field. These papers can be classified into three categories: solar planets, extra-solar planets, and moon explorations. Scientists from both China and oversea reported their recent results.     

Research Progress in Responses of Modern Terrestrial Plant Carbon Isotope Composition to Climate Change

Global climate change has been one of the most concerned environmental problems in the world since the 1980s. Since stable carbon composition (¹³C) in plant tissues can record abundant information on climate changes, it has been widely used as an important climate proxy in global change studies and becomes a powerful tool for obtaining paleoclimate information, understanding paleoenvironment reconstruction and modern climate change, and predicting future climate trends. However, a lot of potential uncertainties have always involved in the reconstruction of paleoclimate and paleoenvironment by carbon isotope of the past period sediment or fossils. Among them, the most dominant uncertainty is due to our poor understanding of the relations between carbon isotope ratios of plants and climatic factors and the climatic and environmental significance indicated by modern plant ¹³C. This may limit the application of plant ¹³C in the study of climatic and environmental changes. Based on the Summary of plant ¹³C fractionation and carbon isotope distribution of different photosynthetic plants, the effects of environmental factors, e.g., temperature, precipitation, atmospheric CO₂ concentration, and altitude on terrestrial plant ¹³C and their relationships were reviewed in this paper, and the response mechanism of plant ¹³C to climate changes were also analyzed. Furthermore, the current existing problems and the future prospects in carbon isotope study were discussed. It is pointed out that strengthening some studies such as the response of C₄ plants ¹³C to climate environmental parameters, the transformation relation of different scale plant ¹³C, intersection and permeation of related disciplines, and various proxies and scientific method, will undoubtedly make us have a more accurate understanding of the climate history and eventually broaden the development of the field during the process of global change study by plant carbon isotope techniques.     

Characteristics of the supernova remnant G351.7+0.8 and a distance argument against its association with PSR J1721−3532

New images of the supernova remnant (SNR) G351.7+0.8 are presented based on 21-cm H  i -line emission and continuum emission data from the Southern Galactic Plane Survey. SNR G351.7+0.8 has a flux density of 8.4 ± 0.7 Jy at 1420 MHz. Its spectral index is 0.52 ± 0.25 ( S = v ^−α) between 1420 and 843 MHz, typical of adiabatically expanding shell-like remnants. H  i observations show structures possibly associated with the SNR in the radial velocity range of −10 to −18 km s⁻¹, and suggest a distance of 13.2 kpc and a radius of 30.7 pc. The estimated Sedov age for G351.7+0.8 is less than  6.8×10⁴ yr  . A young radio pulsar PSR J1721−3532 lies close to SNR G351.7+0.8 on the sky. The new distance and age of G351.7+0.8 and recent proper motion measurements of the pulsar strongly argue against an association between SNR G351.7+0.8 and PSR J1721−3532. There is an unidentified, faint X-ray point source 1RXS J172055.3−353937 which is close to G351.7+0.8. This may be a neutron star potentially associated with G351.7+0.8.