小体积液液萃取气相色谱-质谱法测定地下水中的克百威与3-羟基克百威

克百威和3-羟基克百威是一对典型的农药母体及其代谢产物,由于其水溶性高、毒性大,可通过地表水或地下水进行长距离迁移,对人类健康和环境安全造成危害.以往通常采用液相萃取或固相萃取的方式提取样品中的克百威和3-羟基克百威,但这些方法操作繁琐、耗时较长,不利于室内模拟实验中多组样品的检测.为实现克百威与3-羟基克百威在地下水...     

新元古代沂沭海峡地震引发的软沉积物变形及其微量元素信息*

新元古代沂沭海峡位于郯庐断裂带昌邑—大店断层西侧宽60~90,km、长300,km的区域内,其分布范围基本与郯庐断裂带中段一致。新元古代,该海峡盆地先后沉积了青白口系、南华系及震旦系的滨—浅海相陆源碎屑、泥质及碳酸盐沉积物,其岩石地层称之为土门群。本次研究从该海峡盆地土门群佟家庄组(由石英砂岩、泥灰岩和页岩组成,属南华系)、浮来山组(由细—粉砂岩夹页岩组成,属震旦系)及石旺庄组(主要由碳酸盐岩组成,下部夹页岩,属震旦系)中鉴别出了一系列地震触动软沉积物形成的变形构造,包括液化砂墙和砂脉、负载构造、火焰构造、球枕构造、软布丁构造、底辟构造、滑塌褶曲和同沉积断层等。它们是地震事件的记录——震积岩。新元古代中晚期(约800—600,Ma)沂沭海峡盆地拉张裂陷是它们形成的动力机制。根据石旺庄组中的微亮晶方解石脉与地震成因的变形构造(如负载、火焰、软布丁及同沉积断层等)共(伴)生的事实,并结合模拟地震试验结果分析,认为微亮晶方解石脉很可能是地震引发的饱和灰泥(方解石微粒)液化脉。微量化学元素分析结果表明,这些震积岩中的w(La)/w(Sc)和 w(La)/w(Th)值高于上地壳平均值和正常沉积层,而w(Th)/w(Sc)值则较低,深源微量元素Ni和Cr的含量也高于上地壳平均值及正常沉积层。这些微量元素特征是当时的盆地基底不稳定、快速沉积且伴有深部物质元素混入的反映,强地震很可能是快速沉积和促进深源物质混入的主要动力。土门群中发育的一系列地震引起的软沉积物变形(震积岩),再次证明了古郯庐断裂带的存在,由它们记录的地震事件也是晋宁运动乃至Rodinia超大陆的裂解的响应。     

熊耳山地区太古宙超镁铁质岩的地球化学特征及成因探讨

熊耳山地区太古宙超镁铁质岩在空间分布上具有不均一性、成带性和多方向性特征 ,岩石以橄榄岩、辉石岩、角闪石岩为主 ,蚀变强烈。岩石贫钙、镁 ,低铝、K2 O Na2 O,稀土总量较高 ,轻重稀土分馏显著。地球化学特征表明大部分超镁铁质岩体为岩浆侵入成因     

Exfoliation of kaolinite by urea-intercalation precursor and microwave irradiation assistance process

A type of exfoliated kaolinite was produced by urea-intercalation and original microwave irradiation assisted method. The product was investigated by Fourier transformation infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), scanning electronic microscopy (SEM), Brunauer-Emmett-Teller (BET) and laser particle analysis techniques. FT-IR spectra show that NHCO molecule exists in the intercalated kaolinite. XRD analyses indicate that the kaolinite sheet-like structure was disordered after microwave irradiation. The urea decomposition process and explosion effect between the sheet-like structures of kaolinite under microwave irradiation were discussed. The SEM and BET analyses reveal that the end product is exfoliated kaolinite with thin particles and increased surface area. Size and zeta potential analyses show that the particle size distribution is between 250 nm and 550 nm with normal distribution and the particle is negatively charged. In comparison with the conventional grind method, the process adopted appears to be economic and the exfoliated kaolinite end product may display a significantly enhanced performance in industrial applications.     

Synthesis and characterisation of a multifunctional oil-based drilling fluid additive

An oil-based drilling fluid additive H-DEA (or humic acid-cocamide diethanolamine) was synthesised using humic acid and cocamide diethanolamine as raw materials. The rheological behaviors of H-DEA showed that the synthesised product has the good properties in both decreasing the filtrate loss and improving rheology property of oil-based drilling fluids compared with other commercially available additives. Under the optimal additive amount of 3%, both API filtrate loss and yield point changed remarkably from 5.40 to 0.41 mL and 9.0 to 25.6 Pa, respectively. Furthermore, differential scanning calorimetry (DSC) showed that H-DEA has good thermal stability in a wide temperature range up to 170 °C. Infrared spectroscopy (IR) and rheological analysis revealed that the possible mechanism of the multifunctional effects may be attributed to the existing of high density of strong polar groups, hydrogen bonds, electrostatic forces, and intermolecular association on H-DEA molecular structure. The results of the study showed that the synthesised H-DEA can be potentially used as a multifunctional oil-based drilling fluid additive in oil-drilling excavation.     

生态地球化学预测预警若干问题探讨

回顾了生态地球化学危害效应的作用机理,提出了区域地球化学调查-地球化学环境监测-机理研究相结合的生态地球化学预测预警基本思路。根据当前中国多目标区域地球化学调查和生态地球化学评价工作的现状,举例说明了土壤重金属元素累积、土壤环境变化、生态效应机理的若干研究方法,提出了预测预警成果体现的若干建议。     

油田开发中后期岩相单元的细分研究

油田开发中后期建立在原小层对比和沉积微相基础上的储层地质模型已不能适应调整挖潜和剩余油分布研究的要求,需要在小层划分的基础上,进一步细分到岩相单元。本文以大庆长垣南部葡北油田葡I组油层为例提出岩相单元的概念,通过现代沉积研究论证岩相单元细分的可行性,结合密井网测井曲线分析旋回性、隔夹层分布的稳定性及目前经济技术和采油工艺等,探讨细分单元的基本原则。最后提出岩相单元细分的基本方法。     

普若岗日冰原毗邻地区风沙地貌及其环境演变

冰川作用形成的大面积的冰碛物沉积及寒冻风化是高寒区风沙沉积的主要物质来源.风沙地貌的发育与高寒区环境密切相关,冻结作用使沙丘发育以加积作用为主,形成了高大的新月形沙丘.沙丘的侵蚀与移动主要发生在暖季,新月形沙丘运动速度相当缓慢,年平均水平移动量约1.8～0.5cm·a^-1,加积速率约0.3～0.08cm·a^-1.普若岗日冰原毗邻地区的环境变化主要受温度条件制约,沙丘腐殖质层沉积年代与我国东部沙区古沙丘、敦德冰芯具有一定的相关性,可以认为西南季风的强度对本区具有重要的作用.高原下垫面的变化造成太阳辐射差异,是引起西南季风强弱,造成高原腹地温度与降水随之变化的重要原因.     

电偶源瞬变电磁测深研究(四)--瞬变电磁测深视电阻率

给出了由电偶源垂直磁场Ｈｚ（ｔ）计算全区（期）视电阻率的数值计算方法;将时间范围扩展到几十秒,以满足大偏移距（ｒ）探测大深度的需要。模拟计算结果显示,全区视电阻率能清晰地反映地电断面的结构,有助于定性定量解释     

Study on the Global Carbon Assimilation System Based on Multisource Remote Sensing Data

The Paris agreement signed in April, 2016 aims to balance global anthropogenic carbon emissions and terrestrial carbon sinks by the middle of the 21^st century. To fulfill this goal, it is necessary to calculate carbon fluxes of different regions reliably. The global carbon assimilation system is an effective technique for achieving this goal. The Ministry of Science and Technology of China supports the project entitled as study on the global carbon assimilation system based on multisource remote sensing data through the national key research and development programs for global change and adaptation during the thirteen-five period. This project will develop synergic inversion techniques for retrieving key parameters of biological and atmospheric cycles and for assimilating multisource remote sensing and ground based data. Then, the high resolution global carbon assimilation system coupled with an ecological model will be constructed. This system is able to assimilate jointly multisource observation data and to optimize key model parameters, photosynthesis and respiration carbon fluxes of global terrestrial ecosystems, and anthropogenic carbon emission fluxes of key regions. This system will be used to study quantitatively the spatial and temporal patterns of carbon fluxes of global terrestrial ecosystems and anthropogenic carbon emission fluxes of key regions and to identify the mechanisms driving the global terrestrial carbon sinks and sources. The outputs of this study will be helpful for the fulfillment of the key research and development programs for global change and adaptation and provide valuable data and technical support for the decision-making in China.