Tourmaline composition and boron isotopes record lateritic weathering during the Great Oxidation Event

Identifying evidence of oxidative weathering in the geological record is essential to trace the evolution of Earth's atmosphere oxygenation. Metamorphosed residues of lateritic weathering have been identified as two rock types in the 2.1‐Ga‐old Cercadinho Formation, Piracicaba Group, Quadrilátero Ferrífero of Minas Gerais. One is tourmaline–hematite–sillimanite–kyanite quartzite; the other is rutile–tourmaline–hematite–muscovite phyllite. Both rocks have abundant tourmaline with δ¹¹B values between about ?17‰ and ?13‰. The Cercadinho tourmaline is roughly parallel to the povondraite–“oxy‐dravite” join of meta‐evaporitic tourmaline, in its more aluminous segment, offset to higher contents of iron. These compositional and isotopic characteristics of the Cercadinho tourmaline indicate that continental evaporitic brines interacted with aluminium‐ and iron‐rich residues of lateritic weathering. The abundance of disseminated tourmaline, a mineral poorly reported from palaeosols worldwide, implies a boron‐rich brine overprint on the lateritic profile before the onset of metamorphism, reflecting a climatic change from humid to arid conditions in a continental setting. The recognition of lateritic weathering in the Cercadinho Formation contributes to the amount of evidence for increased levels of atmospheric oxygen between 2.22 and 2.06 Ga ago.     

GEOALGAR项目:地震活动性和断层面解的初步结果

2000年5月发起的GEOALGAR项目旨在致力于阿尔加维地区的地球动力学监测和地震区划. 本文简单介绍一下该项目的目标和有关1999-2000年地震记录分析的初步结果. 经过地震记录和速度模型参数的同步反演, 对两个选定区域的震源位置进行了重新定位. 区域1使用了25个1999-2000年间发生的ML≥2.0的地震, 区域2使用了125个. 结果表明, 主要有两个地区的地震较多 一个是蒙希克地区(在内陆), 另一个是瓜达尔基维尔浅滩(范围从36.4°N, 8°W～36.8°N, 7.2°W). 区域1, 震源校正的幅度相对较小, 震源比原先定位的深度稍微深一些; 而对于区域范围内其他更多的地震, 震源校正的幅度较大, 震源的位置变得更浅.对于近期发生的地震也做了断层面解的估计, 结果表明, 最优解受到走滑运动的控制, 这与NW-SE至NNW-SSE方向的水平挤压控制的应力一致, 有两个地震例外, 它们呈现的是逆冲机制, 最大水平挤压应力方向稍微转向N-S. 这与其他作者先前研究的结果也是一致的.重新定位后的震中位置在空间分布上显得更加有条理, 表明它与一些已知的构造特征可能相关. 然而, 断层面解的结果与新构造特征很难相关起来.     

Factors Affecting <Emphasis Type="Italic">Pisidium amnicum</Emphasis> (Müller, 1774; Bivalvia: Sphaeriidae) Distribution in the River Minho Estuary: Consequences for its Conservation

The bivalve Pisidium amnicum (Müller 1774) is a common species in several European freshwater ecosystems. However, few Iberian watersheds are colonized by this species, and the River Minho estuary is possibly the Iberian aquatic ecosystem with the larger population. In October 2004–2007, investigations on spatial and temporal variations in P. amnicum abundance and biomass were carried out at 16 sites along the River Minho tidal freshwater wetlands. Mean abundance and biomass per site ranged from 0 to 750 ind m⁻² and 0 to 7.42 g AFDW m⁻², respectively. A clear decrease in the spatial distribution, abundance, and biomass was observed during the 4-year assessment. Furthermore, a stepwise multiple regression model showed that organic matter and conductivity explained 50.2% of the variation in P. amnicum abundance (R ² = 0.502, F _{[2, 15]} = 7.569, p = 0.005). Ecological knowledge is essential to the implementation of future conservation plans for P. amnicum, and the results of this study are of paramount importance to identify habitats that should be protected in order to preserve this species and provide scientific reference that may be useful in the development of management and/or restoration plans.     

Extreme values and meteorology

Summary The basic ideas of univariate extremes and some applications are described in the paper; some references are made to multivariate extremes and stochastic processes of extremes.

---

Zusammenfassung Es werden einige grundlegende Ideen zu univariaten Extremen und ihren Anwendungen beschrieben. Multivariate Extreme und stochastische Prozesse von Extremen werden ebenfalls besprochen.

---

---

With 4 Figures     

Removal of chromate from aqueous solution using treated natural zeolite

This paper present the possible alternative removal options for the development of safe drinking water supply in the chromium-affected areas. The Cr (VI) state is of particular concern because of its toxicity. The mordenite has suitable mineralogical properties that enable them to be used for ion-exchange processes. This includes total cation exchange capacity. However, in the present work, the modified-natural zeolite was used as an adsorbent for the removal of Cr (VI) from aqueous solution. The ability of modified natural zeolite (mordenite) to remove inorganic anion was investigated. Laboratory experiments were conducted examining the effect of the sorption of cationic surfactants. On the basis of the results of this study, the HDTMA-HSO₄ modified zeolite appears suitable as a sorbent for hexavalent chromium whereas EHDDMA-modified zeolite were not removed with the same efficiency. The sorption of chromate on HDTMA-zeolite results from a combination of entropic, coulombic, hydrophobic effects, and HDTMA counterion.     

Bayesian inversion of synthetic AVO data to assess fluid and shale content in sand-shale media

Reservoir characterization of sand-shale sequences has always challenged geoscientists due to the presence of anisotropy in the form of shale lenses or shale layers. Water saturation and volume of shale are among the fundamental reservoir properties of interest for sand-shale intervals, and relate to the amount of fluid content and accumulating potentials of such media. This paper suggests an integrated workflow using synthetic data for the characterization of shaley-sand media based on anisotropic rock physics (T-matrix approximation) and seismic reflectivity modelling. A Bayesian inversion scheme for estimating reservoir parameters from amplitude vs. offset (AVO) data was used to obtain the information about uncertainties as well as their most likely values. The results from our workflow give reliable estimates of water saturation from AVO data at small uncertainties, provided background sand porosity values and isotropic overburden properties are known. For volume of shale, the proposed workflow provides reasonable estimates even when larger uncertainties are present in AVO data.     

Modeling flood dynamics in a temporary river draining to an eutrophic reservoir in southeast Portugal

Enxoé is a small temporary river with a flushy regime, which flash floods carry significant loads to the reservoir. As a result, the reservoir, which supplies 25,000 inhabitants, exhibits a high trophic state and cyanobacteria blooms since its construction in 1998, with water abstractions requiring extensive treatment. This study aimed to understand the contribution of flash floods to the Enxoé’s reservoir high trophic state using a modeling approach. This was the first time the river was monitored and that a modeling study was carried out. The MOHID-Land model was implemented to assess the water path in the catchment, and was integrated with field data to compute river loads. Results confirmed the importance of flash events. During flash floods, water properties were determined by soil surface and river bottom wash out, and depended mostly on the flush sequence and intensity. Model simulations showed that soil surface permeability reduction was an important factor regulating surface runoff while soil moisture was low. The first flood after the dry period contributed to 2% of the yearly discharge, 3% of yearly N load, and 7% of the yearly P loads. Winter floods contribution differed, producing 10% of both yearly discharge and loads. However, concentration of particulate matter and organic compounds in the first flood were one order of magnitude higher than in winter floods. This was due to river bottom resuspension and erosion of riparian areas, representative dynamics of a flushy regime. During subsequent winter floods, nutrient concentrations tended to remain constant as the watershed surface and respective soils were washed. Further work should link a watershed model to a reservoir model to depict the flood impact in the reservoir, and test management strategies to reduce the reservoir trophic state.     

Sediment geochemistry of the urban Lake Paulo Gorski

The objective of this study was to evaluate the concentration and distribution of heavy metals in the sediments of Paulo Gorski Lake, as well as the metals’ bioavailability and potential ecological risk, and to define the anthropogenic and natural heavy metal contributions to the lake. The chemical elements calcium (Ca), cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), iron (Fe), potassium (K), magnesium (Mg), manganese (Mn), sodium (Na), nickel (Ni), lead (Pb), and zinc (Zn) were quantified by flame atomic absorption spectrophotometry with two extraction methods to quantify the bioavailable and non-bioavailable fractions. The data were evaluated using multivariate statistics and sediment quality indices. All sediment collection points (S1, S2, S3, S4 and S5) are different in terms of the concentration of heavy metals, except for S4 and S5, which were statistically equal. The bioavailable fraction of the elements in the sediment follows the sequence Pb>Cu>Mn>Zn>Ni>Cr>phosphorus (P) for all points. The elements Co, Cr, Pb, and Zn showed moderate to considerable contamination at all points. Only points S3 and S5 had moderate ecological risk. Urbanization has been affecting Paulo Gorski Lake via the input of chemical elements, especially Co and Pb. The points most affected by heavy metal contamination are S3 and S5 when the sedimentological sensitivity factor is considered. The lake has high hydrodynamics, causing some of the contaminants that enter the system to leave it, leading to potential negative impacts downstream.     

The effect of mass-transport deposits on the younger slope morphology,offshore Brazil

The effect of Cenozoic mass-transport deposits (MTDs) on the morphology of the Late Neogene to Quaternary seafloor is investigated using a 3D seismic volume from offshore Brazil. The studied MTD shows large remnant blocks deforming the seafloor several Ma after a principal instability event marking the base of the investigated strata. Remnant blocks formed during this latter instability event were quickly buried, with differential compaction between individual blocks and adjacent debrites triggering: a) seafloor instability on the flanks of uncompacted (remnant) blocks, b) the incision of submarine channels between seafloor highs formed by buried remnant blocks, c) local uplifted areas on the seafloor that may form potential triggers for future slope instabilities. The interpreted data show that palaeo-seafloor scarps reached more than 120 m in height, with flanking strata to remnant blocks reaching angles of 15°. Angles of this magnitude caused local collapse of seafloor strata and, in some intervals, the confinement of younger MTDs sourced from the upper slope. The statistical data presented here indicate that differential compaction over heterogeneous MTDs continued well after early burial, still deforming the seafloor c. 15 Ma after the main instability event. In addition, significant structural traps are formed by forced folds on remnant blocks that not experienced substantial compaction. Therefore, we conclude that MTDs on passive margins can control seafloor topography after early burial, at the same time contributing to the formation of significant structural traps in post-MTD successions.