The strength of the Sun's polar fields

The magnetic field strength within the polar caps of the Sun is an important parameter for both the solar activity cycle and for our understanding of the interplanetary magnetic field. Measurements of the line-of-sight component of the magnetic field generally yield 0.1 to 0.2 mT near times of sunspot minimum. In this paper we report measurements of the polar fields made at the Stanford Solar Observatory using the Fe i line 525.02 nm. We find that the average flux density poleward of 55° latitude is about 0.6 mT peaking to more than 1 mT at the pole and decreasing to 0.2 mT at the polar cap boundary. The total open flux through either polar cap thus becomes about 3 × 10¹⁴ Wb. We also show that observed magnetic field strengths vary as the line-of-sight component of nearly radial fields.     

A former asteroidal planet as the origin of comets

The idea of a missing planet between Mars and Jupiter has been with us since the formulation of the Titius-Bode law. The discovery of the asteroid belt in that location led to speculation about a planetary breakup event. Both ideas remained conjectures until Ovenden's finding in 1972, from which it could be derived that the mass of the missing planet was about 90 Earth masses and that its breakup was astronomically recent. Apparently much of that mass was blown out of the solar system during the disruption of the planet. Because of the action of planetary perturbations, only two types of orbits of surviving fragments could remain at present-asteroid orbits and once-around very-long-period elliptical orbits. Objects in the latter type of orbit are known to exist-the very-long-period comets. A large number of these are on elliptical trajectories with periods of revolution of 5 million years; yet they are known to have made no more than one revolution in an orbit passing close to the Sun. By direct calculation it is possible to predict the distribution of the orbital elements of objects moving on long-period ellipses which might have originated in a breakup event in the asteroid belt 5 million years ago. The comet orbits have the predicted distribution in every case where a measure is possible. Some of the distribution anomalies, such as a bias in the directions of perihelion passage, are statistically strong and would be difficult to explain in any other uncontrived way. In addition, a relative deficiency of orbits with perihelia less than 1 AU indicates that the comets must have had small perihelion distances since their origin, rather than that they have been perturbed into small perihelion orbits from a distant “cloud” of comets by means of stellar encounters. The comet orbital data lead to the conclusion that all comets originated in a breakup event in the asteroid belt (5.5±0.6) × 10⁶ years ago. Asteroid and meteoritic evidence can now be interpreted in a way which not only is supportive but also provides fresh insights into understanding their physical, chemical, and dynamical properties. Particularily noteworthy are the young cosmic-ray exposure ages of meteorites, evidence of a previous high-temperature/pressure environment and of chemical differentiation of the parent body, and compositional similarities among comets, asteroids, and meteorites. Certain “explosion signatures” in asteroid orbital element distributions are likewise indicative. Tektites may also have originated in the same event; but if so, there are important implications regarding the absolute accuracy of certain geological dating methods. Little is known about possible planetary breakup mechanisms of the requisite type, though some speculations are offered. In any case, the asteroid belt is an existing fact; and the arguments presented here that a large planet did disintegrate 5 million years ago must be judged on their merits, even in the absence of a suitable theory of planetary explosions.     

Upper limits to trace constituents in Jupiter's atmosphere from an analysis of its 5-μm spectrum

A high-resolution (0.6 cm^?1) spectrum of Jupiter at 5 μm recorded at the Kuiper Airborne Observatory is used to determine upper limits to the column density of 19 molecules. The upper limits to the mixing ratios of SiH₄, H₂S, HCN, and simple hydrocarbons are discussed with respect to current models of Jupiter's atmosphere. These upper limits are compared to expectations based upon the solar abundance of the elements. This analysis permits upper limit measurements (SiH₄), or actual detections (GeH₄), of molecules with mixing ratios with hydrogen as low as 10^?9. In future observations at 5 μm the sensitivity of remote spectroscopic analyses should permit the study of constituents with mixing ratios as low as 10^?10, which would include the hydrides of such elements as Sn and As as well as numerous organic molecules.     

Dynamics of coronal hole regions

The hydrodynamic properties of a steadily expanding corona are explored for situations in which departures from spherically symmetric outflow are large, in the sense that the geometrical cross section of a given flow tube increases outward from the Sun faster than r ² in some regions. Assuming polytropic flow, it is shown that in certain cases the flow may contain more than one critical point. We derive the criterion for determining which of these critical points is actually crossed by the transonic solution which begins at the Sun and extends continuously outward. Next, we apply the theory to geometries which exhibit rapid spreading of the flow tubes in the inner corona, followed by more-or-less radial divergence at large distances. This is believed to be the type of geometry found in coronal hole regions. The results show that, if this initial divergence is sufficiently large, the outflow becomes supersonic at a critical point encountered low in the corona in the region of high divergence, and it remains supersonic at all greater heights in the corona. This feature strongly suggests that coronal hole regions differ from other open-field regions of the corona in that they are in a fast, low density expansion state over much of their extent. Such a dynamical configuration makes it possible to reconcile the low values of electron density observed in coronal holes with the large particle fluxes in the associated high speed streams seen in the solar wind.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

The spectral reflectivity of select areas on Europa

The July 12, 1973, occultation of Europa by Io was observed in 30 wavelength channels in the spectral region λλ3200-11, 000 Å with the 200-inch Hale telescope and a multichannel spectrometer. The data are presented in absolute units above the Earth's atmosphere. The data are analyzed to obtain the spectral reflectivity of seven localized areas on the disk of Europa centered on 324°W longitude. The equatorial material is confirmed to be darker than the eastward-skewed bright north polar cap and a hint is evident that the darker material as well may be somewhat redder than the cap material.     

Observations of Jupiter at 26.3 MHz using a large array

A 640 element phase-steerable dipole array has been used to make highly sensitive observations of the planet Jupiter during the 1973 apparition. The satellite Io is found to have very little influence at the low flux levels, whereas the definition of sources A and B appears to be relatively flux independent. A two-dimensional analysis of the data in the Jupiter-Io plane has revealed considerable source B activity at low intensities which is not influenced by Io.     

Production of organic molecules in the outer solar system by proton irradiation: Laboratory simulations

In the past few years considerable attention has been given to the determination of likely compounds that could account for the various colors observed in the outer solar system: and to possible formation mechanisms for these compounds. Many experiments have been done using electrical discharges (Chadha, M. S., et al., 1971, Icarus15, 39) and ultraviolet light (Khare, B. N., and Sagan, C., 1973, Icarus20, 311) on mixtures of CH₄, NH₃, and H₂S, which are most likely the dominant minor constituents of the atmospheres of Jupiter, Saturn, Titan, and possibly the other satellites early in their histories. Colored polymers, usually brownish-red, have been produced in these experiments. With the passage of Pioneer 10 around Jupiter, there is another source of energy worthy of consideration, energetic protons (and electrons). Preliminary experiments to investigate the formation of colored polymers and other interesting molecules by the irradiation of gas mixtures by protons are discussed. Two to four Mev protons were used, with corresponding beam fluxes (as measured at 6R_J from the planet) equivalent to approximately 80 Earth years at Jupiter per hour of exposure. As in the other types of experiments, colored polymers have been produced. An important feature of this work is the presence or absence of absorption at 5 μm in the different materials produced; Titan is quite dark at this wavelength and Io is fairly bright. Such features may provide criteria for accepting or rejecting various materials produced in these experiments as reasonable coloring agents for the outer solar system.     

Restructuring of polygalacturonate on alumina upon hydration—Effect on phosphate sorption kinetics

Hydration of organic coatings in soils is expected to affect the sorption of oxyanions onto hydrous Fe and Al oxides. We hypothesized that the hydration of polygalacturonate (PGA) coatings on alumina (Al₂O₃) increases their permeability for phosphate. Pure and PGA-coated alumina were equilibrated in deionized water for 2 and 170 h at pH 5 and 20 °C before studying (i) their porosity with N₂ gas adsorption and ¹H NMR relaxometry, (ii) structural changes of PGA-coatings with differential scanning calorimetry (DSC), and (iii) the kinetics of phosphate sorption and PGA desorption in batch experiments. Scanning electron micrographs revealed that PGA molecules formed three-dimensional networks with pores ranging in size from <10 to several hundred nanometers. Our NMR results showed that the water content of intraparticle alumina pores decreased upon PGA sorption, indicating a displacement of pore water by PGA. The amount of water in interparticle alumina pores increased strongly after PGA addition, however, and was attributed to water in pores of PGA and/or in pores at the PGA-alumina interface. The flexibility of PGA molecules and the fraction of a PGA gel phase increased within one week of hydration, implying restructuring of PGA. Hydration of PGA coatings increased the amount of phosphate defined as instantaneously sorbed by 84%, showing that restructuring of PGA enhanced the accessibility of phosphate to external alumina surfaces. Despite the fact that the efficacy of phosphate to displace PGA was higher after 170 h than after 2 h, a higher phosphate surface loading was required after 170 h to set off PGA desorption. Our findings imply that the number of PGA chain segments directly attached to the alumina surface decreased with time. We conclude that hydration/dehydration of polymeric surface coatings affects the sorption kinetics of oxyanions, and may thus control the sorption and transport of solutes in soils.     

Calcium-isotope fractionation in selected modern and ancient marine carbonates

The calcium-isotope composition (δ^44/42Ca) was analyzed in modern, Cretaceous and Carboniferous marine skeletal carbonates as well as in bioclasts, non-skeletal components, and diagenetic cements of Cretaceous and Carboniferous limestones. In order to gain insight in Ca²⁺_aq-CaCO₃-isotope fractionation mechanisms in marine carbonates, splits of samples were analyzed for Sr, Mg, Fe, and Mn concentrations and for their oxygen and carbon isotopic composition. Biological carbonates generally have lower δ^44/42Ca values than inorganic marine cements, and there appears to be no fractionation between seawater and marine inorganic calcite. A kinetic isotope effect related to precipitation rate is considered to control the overall discrimination against ⁴⁴Ca in biological carbonates when compared to inorganic precipitates. This is supported by a well-defined correlation of the δ^44/42Ca values with Sr concentrations in Cretaceous limestones that contain biological carbonates at various stages of marine diagenetic alteration. No significant temperature dependence of Ca-isotope fractionation was found in shells of Cretaceous rudist bivalves that have recorded large seasonal temperature variations as derived from δ¹⁸O values and Mg concentrations. The reconstruction of secular variations in the δ^44/42Ca value of seawater from well preserved skeletal calcite is compromised by a broad range of variation found in both modern and Cretaceous biological carbonates, independent of chemical composition or mineralogy. Despite these variations that may be due to still unidentified biological fractionation mechanisms, the δ^44/42Ca values of Cretaceous skeletal calcite suggest that the δ^44/42Ca value of Cretaceous seawater was 0.3-0.4‰ lower than that of the modern ocean.     

The transition from peraluminous to peralkaline granitic melts: Evidence from melt inclusions and accessory minerals

Fractional crystallization of peraluminous F- and H₂O-rich granite magmas progressively enriches the remaining melt with volatiles. We show that, at saturation, the melt may separate into two immiscible conjugate melt fractions, one of the fractions shows increasing peraluminosity and the other increasing peralkalinity. These melt fractions also fractionate the incompatible elements to significantly different degrees. Coexisting melt fractions have differing chemical and physical properties and, due to their high density and viscosity contrasts, they will tend to separate readily from each other. Once separated, each melt fraction evolves independently in response to changing T/P/X conditions and further immiscibility events may occur, each generating its own conjugate pair of melt fractions. The strongly peralkaline melt fractions in particular are very reactive and commonly react until equilibrium is attained. Consequently, the peralkaline melt fraction is commonly preserved only in the isolated melt and mineral inclusions.

We demonstrate that the differences between melt fractions that can be seen most clearly in differing melt inclusion compositions are also visible in the composition of the resulting ore-forming and accessory minerals, and are visible on scales from a few micrometers to hundreds of meters.