Calcium-isotope fractionation in selected modern and ancient marine carbonates

The calcium-isotope composition (δ^44/42Ca) was analyzed in modern, Cretaceous and Carboniferous marine skeletal carbonates as well as in bioclasts, non-skeletal components, and diagenetic cements of Cretaceous and Carboniferous limestones. In order to gain insight in Ca²⁺_aq-CaCO₃-isotope fractionation mechanisms in marine carbonates, splits of samples were analyzed for Sr, Mg, Fe, and Mn concentrations and for their oxygen and carbon isotopic composition. Biological carbonates generally have lower δ^44/42Ca values than inorganic marine cements, and there appears to be no fractionation between seawater and marine inorganic calcite. A kinetic isotope effect related to precipitation rate is considered to control the overall discrimination against ⁴⁴Ca in biological carbonates when compared to inorganic precipitates. This is supported by a well-defined correlation of the δ^44/42Ca values with Sr concentrations in Cretaceous limestones that contain biological carbonates at various stages of marine diagenetic alteration. No significant temperature dependence of Ca-isotope fractionation was found in shells of Cretaceous rudist bivalves that have recorded large seasonal temperature variations as derived from δ¹⁸O values and Mg concentrations. The reconstruction of secular variations in the δ^44/42Ca value of seawater from well preserved skeletal calcite is compromised by a broad range of variation found in both modern and Cretaceous biological carbonates, independent of chemical composition or mineralogy. Despite these variations that may be due to still unidentified biological fractionation mechanisms, the δ^44/42Ca values of Cretaceous skeletal calcite suggest that the δ^44/42Ca value of Cretaceous seawater was 0.3-0.4‰ lower than that of the modern ocean.     

An integrated object-based image analysis and CA-Markov model approach for modeling land use/land cover trends in the Sarab plain

The present paper is an attempt to integrate a semi-automated object-based image analysis (OBIA) classification framework and a cellular automata-Markov model to study land use/land cover (LULC) changes. Land use maps for the Sarab plain in Iran for the years 2000, 2006, and 2014 were created from Landsat satellite data, by applying an OBIA classification using the normalized difference vegetation index, salinity index, moisture stress index, soil-adjusted vegetation index, and elevation and slope indicators. The classifications yielded overall accuracies of 91, 93, and 94% for 2000, 2006, and 2014, respectively. Finally, using the transition matrix, the spatial distribution of land use was simulated for 2020. The results of the study revealed that the number of orchards with irrigated agriculture and dry-farm agriculture in the Sarab plain is increasing, while the amount of bare land is decreasing. The results of this research are of great importance for regional authorities and decision makers in strategic land use planning.     

Comparison of 15 evaporation methods applied to a small mountain lake in the northeastern USA

Few detailed evaporation studies exist for small lakes or reservoirs in mountainous settings. A detailed evaporation study was conducted at Mirror Lake, a 0.15 km² lake in New Hampshire, northeastern USA, as part of a long-term investigation of lake hydrology. Evaporation was determined using 14 alternate evaporation methods during six open-water seasons and compared with values from the Bowen-ratio energy-budget (BREB) method, considered the standard. Values from the Priestley–Taylor, deBruin–Keijman, and Penman methods compared most favorably with BREB-determined values. Differences from BREB values averaged 0.19, 0.27, and 0.20 mm d⁻¹, respectively, and results were within 20% of BREB values during more than 90% of the 37 monthly comparison periods. All three methods require measurement of net radiation, air temperature, change in heat stored in the lake, and vapor pressure, making them relatively data intensive. Several of the methods had substantial bias when compared with BREB values and were subsequently modified to eliminate bias. Methods that rely only on measurement of air temperature, or air temperature and solar radiation, were relatively cost-effective options for measuring evaporation at this small New England lake, outperforming some methods that require measurement of a greater number of variables. It is likely that the atmosphere above Mirror Lake was affected by occasional formation of separation eddies on the lee side of nearby high terrain, although those influences do not appear to be significant to measured evaporation from the lake when averaged over monthly periods.     

Channel precipitation dynamics in a forested Pennsylvania headwater catchment (USA)

Seasonal and event variations in stream channel area and the contributions of channel precipitation to stream flow were studied on a 106‐ha forested headwater catchment in central Pennsylvania. Variations in stream velocity, flowing stream surface width and widths of near‐stream saturated areas were periodically monitored at 61 channel transects over a two‐year period. The area of flowing stream surface and near‐stream saturated zones combined, ranged from 0·07% of basin area during summer low flows to 0·60% of total basin area during peak storm flows. Near‐stream saturated zones generally represented about half of the total channel area available to intercept throughfall and generate channel precipitation. Contributions of routed channel precipitation from the flowing stream surface and near‐stream zones, calculated using the Penn State Runoff Model (PSRM, v. 95), represented from 1·1 to 6·4% of total stream flow and 2·5–29% of total storm flow (stream flow–antecedent baseflow) during the six events. Areas of near‐stream saturated zones contributed 35–52% of the computed channel precipitation during the six events. Channel precipitation contributed a higher percentage of stream flow for events with low antecedent baseflow when storm flow generated by subsurface sources was relatively low. Expansion of channel area and consequent increases in volumes of channel precipitation with flow increases during events was non‐linear, with greater rates of change occurring at lower than at higher discharge rates. Copyright © 1999 John Wiley & Sons, Ltd.     

Offshore-windenergienutzung in Europa und vor deutschen Küsten

Ocean Dynamics - Nachdem mehrere europäische Länder, insbesondere Dänemark und die Niederlande, Offshore-Windparks mit mehreren 100 MW planen, sind auch in Deutschland Initiativen...     

Towards continuous long-term measurements of suspended particulate matter (SPM) in turbid coastal waters

The dynamics of sediment transport in the East Frisian Wadden Sea are important for the coastal zone and for ecosystem functioning. The tidal inlets between the East Frisian islands connect the back-barrier intertidal flats to the North Sea. Here, concentrations of suspended particulate matter (SPM) in the water column are highly variable, depending on weather conditions and tides. In order to estimate the nature and quantity of sediment transport, in situ measurements were carried out at a Time Series Station in the tidal inlet between the islands of Spiekeroog and Langeoog. This study shows the suitability of multispectral transmissometry (MST) for obtaining long-term SPM measurements with high resolution. The comparability of this technique to the standard filter method and the laser diffraction method [laser in situ scattering and transmissometry (LISST)] is demonstrated. In addition, the Junge coefficients derived from both MST and LISST measurements are compared. A time series of SPM data covering nearly 4 months is presented. As a major result, the data reveal that a single storm surge can have less impact on SPM dynamics than longer-lasting gales. This high-resolution long-term data set is very valuable for modelling suspended matter flux. It also provides background information for studying the influence of SPM dynamics on coastal sediments.