Fission track and fault kinematics analyses for new insight into the Late Cenozoic tectonic regime changes in West-Central Sulawesi (Indonesia)

A 3-D density model for the Cretan and Libyan Seas and Crete was developed by gravity modelling constrained by five 2-D seismic lines. Velocity values of these cross-sections were used to obtain the initial densities using the Nafe–Drake and Birch empirical functions for the sediments, the crust and the upper mantle. The crust outside the Cretan Arc is 18 to 24 km thick, including 10 to 14 km thick sediments. The crust below central Crete at its thickest section, has values between 32 and 34 km, consisting of continental crust of the Aegean microplate, which is thickened by the subducted oceanic plate below the Cretan Arc. The oceanic lithosphere is decoupled from the continental along a NW–SE striking front between eastern Crete and the Island of Kythera south of Peloponnese. It plunges steeply below the southern Aegean Sea and is probably associated with the present volcanic activity of the southern Aegean Sea in agreement with published seismological observations of intermediate seismicity. Low density and velocity upper mantle below the Cretan Sea with ρ  3.25 × 10³ kg/m³ and V_p velocity of compressional waves around 7.7 km/s, which are also in agreement with observed high heat flow density values, point out at the mobilization of the upper mantle material here. Outside the Hellenic Arc the upper mantle density and velocity are ρ ≥ 3.32 × 10³ kg/m³ and V_p = 8.0 km/s, respectively. The crust below the Cretan Sea is thin continental of 15 to 20 km thickness, including 3 to 4 km of sediments. Thick accumulations of sediments, located to the SSW and SSE of Crete, are separated by a block of continental crust extended for more than 100 km south of Central Crete. These deep sedimentary basins are located on the oceanic crust backstopped by the continental crust of the Aegean microplate. The stretched continental margin of Africa, north of Cyrenaica, and the abruptly terminated continental Aegean microplate south of Crete are separated by oceanic lithosphere of only 60 to 80 km width at their closest proximity. To the east and west, the areas are floored by oceanic lithosphere, which rapidly widens towards the Herodotus Abyssal plain and the deep Ionian Basin of the central Mediterranean Sea. Crustal shortening between the continental margins of the Aegean microplate and Cyrenaica of North Africa influence the deformation of the sediments of the Mediterranean Ridge that has been divided in an internal and external zone. The continental margin of Cyrenaica extends for more than 80 km to the north of the African coast in form of a huge ramp, while that of the Aegean microplate is abruptly truncated by very steep fractures towards the Mediterranean Ridge. Changes in the deformation style of the sediments express differences of the tectonic processes that control them. That is, subduction to the northeast and crustal subsidence to the south of Crete. Strike-slip movement between Crete and Libya is required by seismological observations.     

The impact of the nitrogen-to-oxygen ratio on ionized nebula diagnostics based on [N ii] emission lines

We study the relation between nitrogen and oxygen abundances as a function of metallicity for a sample of emission-line objects for which a direct measurement of the metallicity has been possible. This sample is representative of the very different conditions in ionization and chemical enrichment that we can find in the Universe. We first construct the N/O versus O/H ratio diagram, and discuss its large dispersion at all metallicity regimes. Using the same sample and a large grid of photoionization models covering very different values of the N/O ratio, we then study the most widely used strong-line calibrators of metallicity based on [N  ii ] emission lines, such as N2 and O3N2. We demonstrate that these parameters underestimate the metallicity at low N/O ratios and vice versa. We also investigate the effect of the N/O ratio on different diagnostic diagrams used to discriminate narrow-line active galactic nuclei from star-forming regions, such as the [O  iii ]/Hβ versus [N  ii ]/Hα, and show that a large fraction of the galaxies catalogued as composite in this diagram can be, in fact, star-forming galaxies with a high value of the N/O ratio. Finally, using strong-line methods sensitive to the N/O abundance ratio, like N2O2 and N2S2, we investigate the relation between this ratio and the stellar mass for the galaxies of the Sloan Digital Sky Survey. We find, as in the case of the mass–metallicity relation, a correlation between these two quantities and a flattening of the relation for the most massive galaxies, which could be a consequence of the enhancement of the dispersion of N/O ratio in the high-metallicity regime.     

Meridional distribution of CH3C2H and C4H2 in Saturn’s stratosphere from CIRS/Cassini limb and nadir observations

Limb and nadir spectra acquired by Cassini/CIRS (Composite InfraRed Spectrometer) are analyzed in order to derive, for the first time, the meridional variations of diacetylene (C₄H₂) and methylacetylene (CH₃C₂H) mixing ratios in Saturn’s stratosphere, from 5 hPa up to 0.05 hPa and 80°S to 45°N. We find that the C₄H₂ and CH₃C₂H meridional distributions mimic that of acetylene (C₂H₂), exhibiting small-scale variations that are not present in photochemical model predictions. The most striking feature of the meridional distribution of both molecules is an asymmetry between mid-southern and mid-northern latitudes. The mid-southern latitudes are found depleted in hydrocarbons relative to their northern counterparts. In contrast, photochemical models predict similar abundances at north and south mid-latitudes. We favor a dynamical explanation for this asymmetry, with upwelling in the south and downwelling in the north, the latter coinciding with the region undergoing ring shadowing. The depletion in hydrocarbons at mid-southern latitudes could also result from chemical reactions with oxygen-bearing molecules.Poleward of 60°S, at 0.1 and 0.05 hPa, we find that the CH₃C₂H and C₄H₂ abundances increase dramatically. This behavior is in sharp contradiction with photochemical model predictions, which exhibit a strong decrease towards the south pole. Several processes could explain our observations, such as subsidence, a large vertical eddy diffusion coefficient at high altitudes, auroral chemistry that enhances CH₃C₂H and C₄H₂ production, or shielding from photolysis by aerosols or molecules produced from auroral chemistry. However, problems remain with all these hypotheses, including the lack of similar behavior at lower altitudes.Our derived mean mixing ratios at 0.5 hPa of (2.4 ± 0.3) × 10⁻¹⁰ for C₄H₂ and of (1.1 ± 0.3) × 10⁻⁹ for CH₃C₂H are compatible with the analysis of global-average ISO observations performed by Moses et al. (Moses, J.I., Bézard, B., Lellouch, E., Gladstone, G.R., Feuchtgruber, H., Allen, M. [2000a]. Icarus 143, 244-298). Finally, we provide values for the ratios [CH₃C₂H]/[C₂H₂] and [C₄H₂]/[C₂H₂] that can constrain the coupled chemistry of these hydrocarbons.     

Direct Determination of Lead Isotope Ratios by Laser Ablation-Inductively Coupled Plasma-Quadrupole Mass Spectrometry in Lake Sediment Samples

A direct method for the determination of lead isotopic ratios by laser ablation-inductively coupled plasma-quadrupole mass spectrometry (LA-ICP-QMS) is presented. Samples of lake sediments were ground and pressed as pellets before being analysed. Mass bias was corrected by analysing an external calibration sample manufactured with pure silica doped with NIST SRM 981 solution. The efficiency of the mass bias correction was checked by comparing the ICP-MS data with lead isotopic ratios determined by thermal ionisation mass spectrometry (TIMS). The average long term reproducibilities were 0.40%, 0.40%, 0.20% and 0.30% (RSD) respectively for the ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, ²⁰⁶Pb/²⁰⁷Pb and ²⁰⁸Pb/²⁰⁶Pb ratios. The method was applied to the study of lake sediment samples, in order to determine the amount and origin of historical contamination by lead.     

Which variables are essential for renewable energies?

ABSTRACT

Essential Variables are defined as a minimal set of variables that explain the state of the system. They are crucial for predicting its developments, and support metrics that measure its evolution. The variables should be relevant to meet requirements of stakeholders and be technically and economically feasible for systematic observation. A definition of Essential Renewable Energies Variables is proposed linked with their identification in several domains in renewable energy using a bottom-up and user-driven approach, and spanning over several years of documented interaction with stakeholders. Lists of variables are proposed in hydropower, solar, wind, and marine energies. It does not comprise the variables relating to social and economic aspects supporting decision making in investment nor those relating to civil engineering that are needed to erect a plant or farm.     

Radiation-induced paramagnetic defects in natural kaolinites: Alpha dosimetry with ion beam irradiation

Three types of paramagnetic radiation-induced defects (RID), namely A, A′ (Si-O^?-centers) and B (Al-O^?-Al center), had been identified in natural kaolinites by means of electron paramagnetic resonance spectroscopy. The A-center, stable at the scale of geological periods, was thought to be of particular relevance to quantify past transits of radionuclides in the geosphere. Alpha radiation being likely the main source of RID in kaolinite, the objective of this paper is to define the role of α-particles on the creation of RID and to test the use of A-centers for an α-dosimetry. Three kaolinites with different crystalline order and containing other clays as impurities were irradiated with He⁺ ion beams. The radiation dose range (0–750 MGy) was consistent with natural radioactivity in environments from the Earth's surface. Irradiation drastically enhanced the original signals due to RID. An important increase of concentration of the unstable B-center, partly due to unrealistic dose rate provided by accelerator ion beam, was observed from the lower doses. The most stable defects remained of the Atype all along experimental irradiations. The contribution of ancillary phyllosilicates to EPR spectra was negligible. The concentration of the three types of RID was related to radiation doses up to 30 MGy. Dosimetry growth curves for the A-centers exhibited variable efficiencies and saturation levels that were related to the structural order and the chemical purity of the kaolinites: the more ordered and purer the kaolinite, the higher the efficiency and the lower the saturation plateau. Moreover, these results are of geochemical significance: dosimetry based on A-centers could be directly used to quantify past migrations of radioelements in the geosphere, by determination of the naturally-cumulated doses (paleodose) of kaolinites.     

Turbulence intensities and bulk coefficients in the surface layer above the sea

The structure of the atmospheric surface layer above the sea is analysed from aircraft turbulence measurements. The data are issued from two experiments performed in 1990 above the Mediterranean sea: Crau and PYREX, and correspond to moderately unstable conditions and to wind velocities ranging from 6 to 20 m/s. Low-altitude straight and level runs were used to compute the variances of the wind components, as well as of the temperature and moisture. Their dependence on the stability index —z/L is analysed. The turbulent fluxes of momentum, sensible heat and latent heat, calculated by the eddy-correlation technique, are used to estimate the neutral bulk coefficients: drag coefficient, Stanton number and Dalton number. The neutral drag coefficient clearly exhibits a dependence on the windspeed, which could be well fitted by the Charnock relation, with a constant of 0.012.     

Thermodynamic properties of the forsterite-fayalite (Mg2SiO4-Fe2SiO4) solid solution. determination of heat of formation

A high temperature calorimetric solution method involving the use of a sodium and lithium metaborate (NaBO₂+LiBO₂) molten bath at 1,180 K, has been developed in order to measure the enthalpy of formation of the forsterite-fayalite (Mg₂SiO₄-Fe₂SiO₄) system. The samples used for these measurements have been obtained by synthesis. They have been carefully controlled by chemical and X-ray analysis and Mössbauer spectroscopy. The results obtained for forsterite and fayalite agree closely with the data commonly found in the literature. Owing to the uncertainty of the experimental results, it is not possible to determine conclusively whether an enthalpy of mixing exists in this system.