Laser Ablation in the Synthesis of Zirconium Oxide

Results of an experimental study of the oxidation of a zirconium plasma generated by laser ablation of a metallic target under low pressures of oxygen are presented. The crystallographic identification of the collected product by electronic diffraction shows metastable ZrO cubic phase. The oxidation phenomena are interpreted by thermochemical simulation suggesting a model in accordance with other cases of synthesis of metastable oxides at high temperatures, such as plasma reactors.     

Thermodynamic properties of the forsterite-fayalite (Mg2SiO4-Fe2SiO4) solid solution. determination of heat of formation

A high temperature calorimetric solution method involving the use of a sodium and lithium metaborate (NaBO₂+LiBO₂) molten bath at 1,180 K, has been developed in order to measure the enthalpy of formation of the forsterite-fayalite (Mg₂SiO₄-Fe₂SiO₄) system. The samples used for these measurements have been obtained by synthesis. They have been carefully controlled by chemical and X-ray analysis and Mössbauer spectroscopy. The results obtained for forsterite and fayalite agree closely with the data commonly found in the literature. Owing to the uncertainty of the experimental results, it is not possible to determine conclusively whether an enthalpy of mixing exists in this system.     

FIRST RESULTS FROM VIRGO,THE EXPERIMENT FOR HELIOSEISMOLOGY AND SOLAR IRRADIANCE MONITORING ON SOHO

First results from the VIRGO experiment (Variability of solar IRradiance and Gravity Oscillations) on the ESA/NASA Mission SOHO (Solar and Heliospheric Observatory) are reported. The observations started mid-January 1996 for the radiometers and sunphotometers and near the end of March for the luminosity oscillation imager. The performance of all the instruments is very good, and the time series of the first 4–6 months are evaluated in terms of solar irradiance variability, solar background noise characteristics and p-mode oscillations. The solar irradiance is modulated by the passage of active regions across the disk, but not all of the modulation is straightforwardly explained in terms of sunspot flux blocking and facular enhancement. Helioseismic inversions of the observed p-mode frequencies are more-or-less in agreement with the latest standard solar models. The comparison of VIRGO results with earlier ones shows evidence that magnetic activity plays a significant role in the dynamics of the oscillations beyond its modulation of the resonant frequencies. Moreover, by comparing the amplitudes of different components ofp -mode multiplets, each of which are influenced differently by spatial inhomogeneity, we have found that activity enhances excitation.     

More evidence that the Chicxulub impact predates the K/T mass extinction

Abstract Yaxcopoil‐1 (Yax‐1), drilled within the Chicxulub crater, was expected to yield the final proof that this impact occurred precisely 65 Myr ago and caused the mass extinction at the Cretaceous‐Tertiary (K/T) boundary. Instead, contrary evidence was discovered based on five independent proxies (sedimentologic, biostratigraphic, magnetostratigraphic, stable isotopic, and iridium) that revealed that the Chicxulub impact predates the K/T boundary by about 300,000 years and could not have caused the mass extinction. This is demonstrated by the presence of five bioturbated glauconite layers and planktic foraminiferal assemblages of the latest Maastrichtian zone CF1 and is corroborated by magnetostratigraphic chron 29r and characteristic late Maastrichtian stable isotope signals. These results were first presented in Keller et al. (2004). In this study, we present more detailed evidence of the presence of late Maastrichtian planktic foraminifera, sedimentologic, and mineralogic analyses that demonstrate that the Chicxulub impact breccia predates the K/T boundary and that the sediments between the breccia and the K/T boundary were deposited in a normal marine environment during the last 300,000 years of the Cretaceous.     

High‐resolution record of environmental changes and tephrochronological markers of the Last Glacial–Holocene transition at Lake Lautrey (Jura,France)

This paper presents the results of a multiproxy investigation including volume magnetic susceptibility (κ), mineral and pollen analyses of Late Glacial sediments from Lake Lautrey (Jura, France). Small‐scale lithological variations have been identified with high stratigraphic resolution in order to establish lithostratigraphic correlations between cores. κ measurements, combined with mineralogical analyses, provide information on past sedimentary processes. This combined approach reflects major changes in terrestrial habitats and soil processes which may relate to the climatic events characterising the Late Glacial climatic warming and cooling phases. During warm intervals, the record indicates increased lake productivity via carbonate precipitation and decreased input of detrital material. In contrast, cooler intervals show reduced lake productivity, catchment area instability and increased detrital inputs. Several short interruptions in reforestation and in soil stabilisation can be identified and linked with abrupt colder events occurring through the Bølling. A general trend of warming is recorded from the coldest part of the Younger Dryas. Three tephra layers were also detected. The mineral composition analyses show that the upper tephra layer corresponds to the Laacher See eruption (Eifel, Germany) while the lower ones may relate to the volcanic activity of the Chaîne des Puys (Massif Central, France) around 13 000 cal. yr BP. These two events, recognised for the first time outside the Massif Central region, may provide additional chronostratigraphic markers for the Late Glacial sedimentary records of the Jura mountains and northern Alps. Copyright © 2004 John Wiley & Sons, Ltd.     

Relationships between hydrosedimentary processes and occurrence of mercury-resistant bacteria (merA) in estuary mudflats (Seine, France)

The Seine estuary (France) is one of the world's macrotidal systems that is most contaminated with heavy metals. To study the mercury-resistant bacterial community in such an environment, we have developed a molecular tool, based on competitive PCR, enabling the quantification of Gram-negative merA gene abundance. The occurrence of the Gram-negative merA gene in relation with the topology (erosion/deposit periods) and the mercury contamination of three contrasted mudflats was investigated through a multidisciplinary approach and compared with a non-anthropized site (Authie, France). The higher abundance of the Gram-negative merA gene in the Seine estuary mudflats indicates a relationship between the degree of anthropization and the abundance of the merA gene in the mudflat sediments. In the Seine mudflats, the maxima of abundance are always located in fresh sediment deposits. Therefore, the abundance is closely related with the hydrosedimentary processes, which thus seem to be determining factors in the occurrence of the Gram-negative merA gene in the surface sediments of the Seine's mudflat.     

A note on algebraic potentials and Morales–Ramis theory

We present various properties of algebraic potentials, and then prove that some Morales–Ramis theorems readily apply for such potentials even if they are not in general meromorphic potentials. This allows in particular to precise some non-integrability proofs in Celestial Mechanics, where the mutual distances between the bodies appear in the potential, and thus making this analysis unavoidable.     

The landscape-unit approach applied to geology, on SPOT images, in temperate climate zones using a test-area in the Cévennes (Massif Central, France)

Classification image processing is based mainly upon spectral features but this information alone is inadequate for drawing comprehensive maps or reliably distinguishing lithological or structural targets, especially in vegetation-covered areas. It is therefore of interest to explore an approach in which subtle features of the image are matched with field data in a variety of parameters either measured or assessed qualitatively. This approach is necessarily multidisciplinary, the three basic aspects being geomorphological, botanical and geological.The Cévennes massif, in southern France, with its sedimentary margins was selected as a test area, having both varied geology, giving a variety of landscapes, and a range of climatic zones, from Mediterranean to sub-Alpine.The present work is distinguished by its use of the landscape unit, which is rarely considered in geology. Landscapes units are recognized and defined, and the spectral homogeneity of the units is then assessed. They are combined with satellite and other data in order to improve the digital processing for geological purposes.The parameters characterising each landscape unit define the various elements contributing to the landscape, the most important of which are morphology, vegetation and geology, and their interactions. Our results using these parameters show the interest of the management of both the satellite (SPOT in this case) and non-satellite (exogenous) data.     

Which variables are essential for renewable energies?

ABSTRACT

Essential Variables are defined as a minimal set of variables that explain the state of the system. They are crucial for predicting its developments, and support metrics that measure its evolution. The variables should be relevant to meet requirements of stakeholders and be technically and economically feasible for systematic observation. A definition of Essential Renewable Energies Variables is proposed linked with their identification in several domains in renewable energy using a bottom-up and user-driven approach, and spanning over several years of documented interaction with stakeholders. Lists of variables are proposed in hydropower, solar, wind, and marine energies. It does not comprise the variables relating to social and economic aspects supporting decision making in investment nor those relating to civil engineering that are needed to erect a plant or farm.