Implications of Analcime Hydrothermally Formed from Na-alumino-borosilicate Glasses Containing Cs and Sr for the Stability of High-level Radioactive Waste Form

Abstract. In order to know the behaviors of radioactive elements such as cesium and strontium during a hydrothermal alteration of borosilicate glass of radioactive waste, some alumino-borosilicate glasses belonging to the systems Na₂O-Al₂O₃-B₂O₃-SiO₂-SrO, Na₂O-Al₂O₃-B₂O₃-SiO₂-Cs₂O and Na₂O-Al₂-O₃-B₂O₃-SiO₂-SrO-Cs₂O have been treated hydrothermally at 200C under a vapor pressure of 1.54 MPa. The result shows that all glasses are changed into crystalline phases with running time up to 60 days, and that analcime-type zeolite is formed as a major product. The formed zeolite is shown to contain cesium and/or strontium. Considering the fact that natural zeolite occurs in wide physicochemical conditions including hydrothermal one, the analcime-type zeolite is expected to fix stably the radioactive elements in the disposal site. Since aluminum is necessary for the formation of the analcime-type zeolite, the waste glass should have aluminum as one of major components.     

Gold Mineralization and Occurrence of Sinter in the Hoshino Area, Fukuoka Prefecture, Japan

Abstract. Several epithermal gold deposits occur in the Hoshino area, which is located in the western end of the late Cenozoic Hohi volcanic zone, north‐central Kyushu, Japan. The area is characterized by intermediate to felsic extrusive rocks of Pliocene age. In the Hoshino area, the shallow manifestation of the hydrothermal activity is exposed on the surface. Several outcrops of sinter are still preserved on the top of hydro thermally altered volcanic rocks, and high‐grade gold‐bearing quartz veins occur on the surface at lower levels. The hydrothermal alteration resulted into well‐developed alteration zones. The zonal alteration pattern, primarily of near‐neutral pH type, is characterized by the outer smectite zone of a lower temperature, and the inner mixed layer minerals zone of a higher temperature. Quartz vein‐related or fracture‐controlled alteration, is represented by the occurrence of interstratified illite/smectite and K‐feldspar, suggesting a potassium‐enriched alteration. The mineralization in the Hoshino area is recognized on the surface by the occurrence of gold‐bearing quartz veins distributed mainly in the mixed layer minerals zone. The fracture system related to the gold mineralization is mainly characterized by NW‐SE trend. The alteration pattern and the mineralogical composition of the veins suggest that the mineralizing fluids had near‐neutral pH and the mineralization is of low‐sulfidation‐type. Fluid inclusion data and textures observed in quartz veins indicate that gold precipitated during boiling. The chemical composition of quartz veins shows that high‐grade gold‐bearing quartz veins are characterized by higher content of Al₂O₃, K₂O and Rb. Several outcrops of silica‐sinters are distributed on the top of the mixed layer minerals zone. Although their structures are not very well preserved, because of later silicification, the Hoshino sinters still show characteristic textures identical to those observed in modern sinters, such as the presence of plant fossil incorporated into the sinters, the strongly developed depositional laminations and the columnar structures perpendicular to the depositional surfaces. Quartz is the only silica mineral constituting the Hoshino sinters presently. The conversion of amorphous silica into quartz was probably governed by higher temperatures resulting from later hydrothermal activity. This later hydrothermal activity is reflected by the intense silicification affecting mainly the lower parts of the sinters and also by the presence of quartz veins cutting the sinters. The distribution of sinters in the Hoshino area is very significant. The presence beneath the sinters of concealed high‐grade gold‐bearing quartz veins should be highly considered and exploration work is strongly suggested.     

Electric conductivity of Fe2SiO4–Fe3O4 spinel solid solutions

 The spinel solid solution was found to exist in the whole range between Fe₃O₄ and γ-Fe₂SiO₄ at over 10 GPa. The resistivity of Fe_{3− x} Si _x O₄ (0.0<x<0.288) was measured in the temperature range of 80∼300 K by the AC impedance method. Electron hopping between Fe³⁺ and Fe²⁺ in the octahedral site of iron-rich phases gives a large electric conductivity at room temperature. The activation energy of the electron hopping becomes larger with increasing γ-Fe₂SiO₄ component. A nonlinear change in electric conductivity is not simply caused by the statistical probability of Fe³⁺–Fe²⁺ electron hopping with increasing the total Si content. This is probably because a large number of Si⁴⁺ ions occupies the octahedral site and the adjacent Fe²⁺ keeping the local electric neutrality around Si⁴⁺ makes a cluster, which generates a local deformation by Si substitution. The temperature dependence of the conductivity of solid solutions indicates the Verwey transition temperature, which decreases from 124(±2) K at x=0 (Fe₃O₄) to 102(±5) K at x=0.288, and the electric conductivity gap at the transition temperature decreases with Si⁴⁺ substitution. Received: 15 March 2000 / Accepted: 4 September 2000     

An interactive system to assist mineral identification in ore microscopy

An interactive computer system has been developed to assist the mineral identification in ore microscopy. The reference file of the system consists of optical, mechanical, and chemical properties of about 130 ore minerals. The properties are name, chemical formula, color, bireflectance, anisotropism, internal reflection, reflectance at wavelengths of 470, 546, 589, and 650 nm, and polishing hardness and micro-indentation hardness. All the properties except reflectance and microindentation hardness are qualitative or semi-qualitative. Most of the properties are given as characters relative to the more common minerals. This implies that most of the identification processes advance on the basis of the comparison between a subject mineral and coexisting minerals. For this reason, the system asks a user at first to input already identified mineral names. This is quite different from the mineral identification procedures used in petrographic microscopy. To reduce the number of possible minerals, the system presents a series of questions to a user, and the user selects any of the prepared answers according to his observation. The user can also choose any desired question independently of the sequence. The user is expected to be able to recognize some common minerals, such as pyrite, chalcopyrite, galena, and hematite, without the assistance of the system.     

Development of partial factor design method on bending strength of piles for Japanese Specifications for Highway Bridges

ABSTRACT

This paper describes the development of a partial factor design method on the bending strength of piles for the Japanese Specifications for Highway Bridges. First, uncertainties in mobilised bending moments and yield bending moments were evaluated by Monte Carlo simulations. Second, the reliability of piles designed by the previous specifications were evaluated on the basis of reliability analysis considering uncertainties in the mobilised bending moments, yield bending moments, and other factors. Finally, a partial factor design method utilising a survey subsurface investigation method and ground type was developed to reach target reliability levels determined by the Standards.     

Formation and shortening deformation of a back-arc rift basin revealed by deep seismic profiling, central Japan

The northern Fossa Magna (NFM) basin is a Miocene rift system produced in the final stages of the opening of the Sea of Japan. It divides the major structure of Japan into two regions, with north-trending geological structures to the NE of the basin and EW trending structures to the west of the basin. The Itoigawa-Shizuoka Tectonic Line (ISTL) bounds the western part of the northern Fossa Magna and forms an active fault system that displays one of the largest slip rates (4–9 mm/year) in the Japanese islands. Deep seismic reflection and refraction/wide-angle reflection profiling were undertaken in 2002 across the northern part of ISTL in order to delineate structures in the crust, and the deep geometry of the active fault systems. The seismic images are interpreted based on the pattern of reflectors, the surface geology and velocities derived from refraction analysis. The 68-km-long seismic section suggests that the Miocene NFM basin was formed by an east dipping normal fault with a shallow flat segment to 6 km depth and a deeper ramp penetrating to 15 km depth. This low-angle normal fault originated as a comparatively shallow brittle/ductile detachment in a high thermal regime present in the Miocene. The NFM basin was filled by a thick (>6 km) accumulation of sediments. Shortening since the late Neogene is accommodated along NS to NE–SE trending thrust faults that previously accommodated extension and produce fault-related folds on their hanging wall. Based on our balanced geologic cross-section, the total amount of Miocene extension is ca. 42 km and the total amount of late Neogene to Quaternary shortening is ca. 23 km.     

Critical notch depths for failure of coastal limestone cliffs: case study at Kuro‐shima Island,Okinawa, Japan

Development of a notch at the base of a cliff reduces cliff stability and often induces a collapse. Pleistocene limestone coastal cliffs of elevation 5?m in Kuro‐shima, Ryukyu Islands, have a prominent notch with a depth of 3–4?m at their bases. Around these coastal cliffs, collapses different from previous studies of cliff collapses in the Ryukyu Islands were found; collapses in Kuro‐shima have a horizontal failure surface. The horizontal failure surface, situated at the height of the failure surface corresponding to the retreat point of the notch, is bounded by vertical joints cutting the whole cliff and the reef flat in front of the cliff. Two types of horizontal failure surface were found, triangular and quadrangular; the distinction appears to depend on the angle between the vertical joints and the front face of the cliff. Prior to collapse, these cliffs appear to have been separated from the adjacent cliffs by the development of vertical joints. Consequently, a cliff that will collapse can be identified in advance; cliff instability is strongly dependent on the development of a notch. To study the effect of notch development on cliff collapse, the notch depth at which collapse occurs was calculated using stability analysis. Instability of a cliff increases with notch depth; collapse occurs at the horizontal failure surface when the ratio of the notch depth to the seaward length of the cliff is approximately 0·5–0·7 for a triangular failure surface, and 0·7–0·9 for a quadrangular failure surface. Copyright © 2010 John Wiley & Sons, Ltd.     

A sensitivity of squall-line intensity to environmental static stability under various shear and moisture conditions

Squall lines develop in various climate regions having diverse environmental profiles of wind shear, moisture, and temperature. In order to explore the sensitivity of squall lines to these environmental profiles, we have performed an extensive set of numerical simulations under various shear and moisture conditions in midlatitude-continental and tropical–oceanic temperature environments. From the results of the sensitivity simulations and the analyses of the environmental parameters, it is found that the static stability in a convectively unstable layer is of primary importance in determining the strength of squall lines. Under temperature environments having the same static stability, convective available potential energy (CAPE) and precipitable water content (PWC) well describe the squall-line intensity. Vertical shear also plays an important role in determining the squall-line structure as well as the intensity through the interaction with surface cold pool. The combination of the static stability in a convectively unstable layer, CAPE, and PWC should be examined in diagnosing the intensity of squall lines that develop with an optimal shear for their environment.     

Seasonal variation of volatile organic iodine compounds in the water column of Funka Bay,Hokkaido, Japan

Volatile organic iodine compounds (VOIs) emitted from the ocean surface to the air play an important role in atmospheric chemistry. Shipboard observations were conducted in Funka Bay, Hokkaido, Japan, bimonthly or monthly from March 2012 to December 2014, to elucidate the seasonal variations of VOI concentrations in seawater and their sea-to-air iodine fluxes. The bay water exchanges with the open ocean water of the North Pacific twice a year (early spring and autumn). Vertical profiles of CH₂I₂, CH₂ClI, CH₃I, and C₂H₅I concentrations in the bay water were measured bimonthly or monthly within an identified water mass. The VOI concentrations began to increase after early April at the end of the diatom spring bloom, and represented substantial peaks in June or July. The temporal variation of the C₂H₅I profile, which showed a distinct peak in the bottom layer from April to July, was similar to the PO₄ ^3? variation profile. Correlation between C₂H₅I and PO₄ ^3? concentrations (r = 0.93) suggests that C₂H₅I production was associated with degradation of organic matter deposited on the bottom after the spring bloom. CH₂I₂ and CH₂ClI concentrations increased substantially in the surface and subsurface layers (0–60 m) in June or July resulted in a clear seasonal variation of the sea-to-air iodine flux of the VOIs (high in summer or autumn and low in spring).