Mechanisms for anhydrite and gypsum formation in the Kuroko massive sulfide–sulfate deposits,north Japan

The Sr, Ba, and rare earth elements (REEs) concentrations and Sr isotopic composition of anhydrite and gypsum have been determined for samples from the Matsumine, Shakanai, and Hanaoka Kuroko-type massive sulfide–sulfate deposits of northern Japan to evaluate the mechanisms of sekko (anhydrite and gypsum) ore formation. The Sr isotopic compositions of the samples fall in the range of 0.7077–0.7087, intermediate between that for middle Miocene (13–15 Ma) seawater (0.7088) (Peterman et al., Geochim Cosmochim Acta, 34:105–120, 1970) and that for country rocks (e.g., 0.7030–0.7050) (Shuto, Assn Geol Collab Japan Monograph 18:91–105, 1974). The Kuroko anhydrite samples exhibit two types of chondrite-normalized REE patterns: one with a decrease from light REEs (LREEs) to heavy REEs (HREEs) (type I), and another with a LREE-depleted pattern (type II). Based on the Sr content and isotopic ratio (assuming an Sr/Ca (mM/M) of 8.7 for seawater), anhydrite is considered to have formed by mixing of preheated seawater with a hydrothermal solution of Sr/Ca (mM/M) = ca. 0.59–1.36 under the condition in which the partition coefficient (Kd) ranges between ca. 0.5 and 0.7. This results in the formation of anhydrite with higher Sr content with an Sr isotopic value close to that of seawater under seawater-dominant conditions. Larger crystals of type II anhydrite are partly replaced by smaller ones, indicating that anhydrite dissolution and recrystallization occurred after or during the formation of sekko ore. Gypsum, which partially replaces anhydrite in the Kuroko deposits, also exhibits two distinct chondrite-normalized REE patterns. Because LREEs are likely to be more readily mobilized during dissolution and recrystallization, it is hypothesized that LREEs are leached from type I anhydrite, resulting in the formation of type II anhydrite with LREE-depleted profiles.     

Climate simulations for 1880–2003 with GISS modelE

We carry out climate simulations for 1880–2003 with GISS modelE driven by ten measured or estimated climate forcings. An ensemble of climate model runs is carried out for each forcing acting individually and for all forcing mechanisms acting together. We compare side-by-side simulated climate change for each forcing, all forcings, observations, unforced variability among model ensemble members, and, if available, observed variability. Discrepancies between observations and simulations with all forcings are due to model deficiencies, inaccurate or incomplete forcings, and imperfect observations. Although there are notable discrepancies between model and observations, the fidelity is sufficient to encourage use of the model for simulations of future climate change. By using a fixed well-documented model and accurately defining the 1880–2003 forcings, we aim to provide a benchmark against which the effect of improvements in the model, climate forcings, and observations can be tested. Principal model deficiencies include unrealistically weak tropical El Nino-like variability and a poor distribution of sea ice, with too much sea ice in the Northern Hemisphere and too little in the Southern Hemisphere. Greatest uncertainties in the forcings are the temporal and spatial variations of anthropogenic aerosols and their indirect effects on clouds. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Geochemical Changes in Spring Water Associated with the 2000 Eruption of the Miyakejima Volcano, Japan

Water was sampled from eight springs and a lake in volcanic Miyakejima Island of Japan after the 2000 eruption. Major chemical and isotopic compositions of the water were analyzed. Significant increases of sulfate ion are observed in several springs where the thickness of ejecta exceeds 32 mm. A good relationship of Cl/S mole ratios between spring water and leachate of the ejecta is observed. Sulfur isotopic compositions of the spring water become close to that of leachate of the ejecta as time elapses after the eruption. Consequently the sources of the added sulfate ion in the spring water after the eruption are interpreted to be anhydrite and adhered sulfur of the ejecta.     

Las Matras Block, Central Argentina (37°S-67°W): the Southernmost Cuyania Terrane and its Relationship with the Famatinian Orogeny

The Las Matras Block in Central Argentina constitutes the southernmost part of the Cuyania terrane, which was accreted to the southwestern margin of Gondwana during the Early to Mid Ordovician Famatinian orogeny. The Grenville-aged rocks of the Las Matras Block are represented by the tonalitic to trondhjemitic Las Matras pluton. A new U-Pb conventional zircon age of 1244±42 Ma confirms previous Sm-Nd and Rb-Sr isochron ages of this pluton. Mineral composition data are consistent with the tonalitic-trondhjemitic character of the pluton, and constrain its emplacement level to 1.9 to 2.6 kb. This shallow level of emplacement and the undeformed character of the pluton are distinctive features of this southernmost basement. A regional comparison indicates that the igneous-metamorphic evolution of the Grenville-aged basement rocks of the Cuyania terrane occurred over a period of more than 200 million years, with ages older than 1200 Ma up to those close to 1000 Ma. The shallowest crustal level is found in Las Matras, suggesting a southward shallowing of the exposed level of basement. The deformation and metamorphism associated with the collisional Famatinian orogeny affect both the Cuyania terrane and the adjacent western margin of Gondwana, and the Gondwana margin was also the locus of the related arc magmatism, but the compressive effects of the collision decrease in intensity toward the south. The Famatinian metamorphism and magmatism continue even further south into the Patagonia region, but the southern continuity of the Cuyania terrane into this region remains uncertain.     

The examination of fracturing process subjected to triaxial compression test in Inada granite

The behavior of a granite subject to a triaxial compression test ranging from the prefailure stage to the postfailure stage was studied using a fluorescent technique from the geological point of view. Microscopic observations of the specimens at different stages showed changes in the failure process. The start of formation of new microcracks paralleled the compression direction through their propagation until the onset of faulting and ended with the failure of shear zones after the strength failure point. Pores chiefly identified in the feldspar increased in length and width in the early stages, but not in number. It seems that the effect of pore spaces did not have any effect of failure. The microcracks generated on angular edges of quartz or feldspar grains and around biotite grains with increasing compression force. The phenomenon appearing on the crystal boundaries among biotite and quartz or feldspar agrees with the result calculated based on the theory on stress fields with ellipsoidal inhomogeneity suggested by Eshelby.     

Origin of some calc-alkalic andesites in the Japanese Islands

Origin of calc-alkalic andesite in the Japanese Islands is reviewed on the basis of the recent trace element data and new experimental results. It is suggested that calc-alkalic andesites in the Japanese Islands have at least four different origins; (1) fractional crystallization with separation of magnetite of high-alumina basalt magma, (2) partial melting of hydrous upper mantle peridotite (for magnesian andesite), (3) fractional crystallization with separation of olivine and/or orthopyroxene of magnesian andesite magma and (4) mixing of dacitic and basaltic magmas. Emphasis is placed on the possible generation of primary magnesian calc-alkalic andesite magmas by direct partial melting of the upper mantle peridotite under hydrous conditions at depths between 40 and 60 km.