Trace element geochemistry and Sr-Nd characteristics of Mesoproterozoic mafic intrusive rocks from Rondonia, Brazil, SW Amazonian Craton： Petrogenetic and tectonic inferences

The Amazonian Craton comprises an Archean domain surrounded by four successively younger Proterozoic tectonic provinces. Within the Rio-Negro-Juruena province the Serra da Providencia Intrusive Suite （1.60 and 1.53 Ga） consists of A-type rapakivi gran- ites, charnockites and mangerites genetically associated with diabase dikes, gabbros and amphibolites. The original mafic melts were derived from a depleted mantle source （εN（T） ＋2.5 to ＋2.8;εSr（T） -12.1）. Underplated mafic magma induced melting of a short-lived felsic crust, thus originating coeval felsic-mafic magmatism in a conti- nental intraplate setting. The Colorado Complex, assigned to the Rondonian-San Ignacio province, comprises 1.35-1.36 Ga intrusive bimodal magmatism represented by monzonite gneisses associated with amphibolite, gabbro and metadiabase dikes intercalated with metasediments with detrital zircon that yield U- Pb ages of 1.35 to 1.42 Ga. Mafic samples dis- play juvenile signatures （εNd（T） 0.0 to ＋5.2; εSr（T） --5.0 to --30.7） and are less contaminated than the Serra da Previdencia and Nova Brasilandia ones. The generation of the basaltic magma is related to the subduction of an oceanic slab below the peridotite wedge （intraoceanic arc setting）. Fluids and/or small melts from the slab impregnated the mantle. The Nova Brasilandia Sequence （Sunsas-Aguapef province） comprises a metasedimentary sequence intruded by 1.10-1.02 Ga metadia- bases, gabbros, meta-gabbros, and amphibolites associated with granitic plutons （bimodal mag- matism）. The original tholeiitic magmas, derived from a depleted source （εNd（T） = ＋3.1 to ＋5.0）, in a proto-oceanic setting, underwent subsequent contamination by the host rocks, as indicated by the isotopic and trace element data.     

High-resolution seismic imaging of gas accumulations and seepage in the sediments of the Ria de Aveiro barrier lagoon (Portugal)

Methane is a powerful greenhouse gas and an important energy source. The global significance and impact in coastal zones of methane gas accumulation and seepage in sediments from coastal lagoon environments are still largely unknown. This paper presents results from four high-resolution seismic surveys carried out in the Ria de Aveiro barrier lagoon (Portugal) in 1999, 2002 and 2003. These comprise three chirp surveys (RIAV99, RIAV02, RIAV02A) and one boomer survey (RIAV03). Evidence of extensive gas accumulation and seepage in tidal channel sediments from the Ria de Aveiro barrier lagoon is presented here for the first time. This evidence includes: acoustic turbidity, enhanced reflections, acoustic blanking, domes, and acoustic plumes in the water column (flares). The stratigraphy and structural framework control the distribution and extent of gas accumulations and seepage in the study area. In these shallow systems, however, tidal altitude variations have a significant impact on gas detection using acoustic methods, by changing the raw amplitude of the enhanced seismic reflections, acoustic turbidity, and acoustic blanking in gas-prone areas. Direct evidence of gas escape from drill holes in the surrounding area has shown that the gas present in the Ria de Aveiro consists of biogenic methane. Most of the gas in the study area was probably generated mainly in Holocene lagoon sediments. Evidence of faults affecting the Mesozoic limestones and clays underlying some of the shallow gas occurrences, and the presence of high-amplitude reflections in these deeper units raise the possibility that some of this gas could have been generated in deeper sedimentary layers, and then migrated upward through the fractured Mesozoic strata.     

Impact of trace metals on denitrification in estuarine sediments of the Douro River estuary,Portugal

Denitrification influences the nitrogen budget in estuaries by removing fixed nitrogen from the inorganic pool; rates are dependent on both geological and geographic conditions as well as increasing anthropogenic impacts. In this study the effects of copper (Cu), chromium (Cr), zinc (Zn), cadmium (Cd) and lead (Pb), on the denitrification pathway were evaluated in subtidal and intertidal sediments of the Douro River estuary. Dinitrogen, N₂O and NO₂⁻ production rates were measured in triplicate slurries of field samples under different treatments of metal concentrations. Results demonstrated that similar metal amendments led to different site responses for denitrification, suggesting that variations in sediment properties (metal concentrations, grain size, organic matter content, etc.) and/or differences in denitrifying community tolerance modulate the level of metal toxicity. Denitrifying communities in subtidal muddy sediments were not affected by increasing concentrations of metals. In contrast, intertidal sandy sites revealed high sensitivity to almost all trace metals tested; almost complete inhibition by Cr (95%) and Cu (85%) was observed for 98 and 79 μg per gram of wet sediment respectively, and by Zn (92%) at the highest concentration added (490 μg per gram of wet sediment). Moreover, the addition of trace metals stimulated N₂O and NO₂⁻ accumulation in intertidal sandy (Zn, Cu, Cr and Cd) and muddy sediments (Cu and Zn), demonstrating a pronounced inhibitory effect on specific steps within the denitrification enzymatic system. In summary, the results obtained suggest that, according to the type of estuarine sediment, trace metals cannot only reduce total N removal from an estuary via denitrification but also can enhance the release of N₂O, a powerful greenhouse gas.     

Parametric calibration of the Hargreaves–Samani equation for use at new locations

The Hargreaves–Samani (HS) evapotranspiration equation is very useful for the on‐site irrigation management in data‐short situations such as small and midsize farms and landscaped areas. Although much work has been performed to improve the precision of the evapotranspiration (ET_o) estimates for use at new locations, the results have not been consistent and many have not been confirmed by other works. The purpose of this study was to review and to evaluate the seven most promising parameters used for the calibration of the HS evapotranspiration equation, using two different regions: California and Bolivia. The results of this study show that annual correlations between HS and Penman–Monteith can be misleading because the correlation is poor in the humid months and improves progressively along the dry season until the first rains. The average monthly wind speed can be used for both spatial and seasonal calibration of the HS equation, especially during the irrigation season. Elevation and precipitation can be used to calibrate the HS equation when no reference ET_o values are available at nearby stations. The monthly value of K_T calculated from solar radiation follows a parabolic function along the year and should not be used for improving the estimates of the HS equation because the clearness index produces better results than actual solar radiation measurements. The results also indicate that the use of distance to coast, temperature range and temperature parameter does not improve the precision of the HS equation. Copyright © 2012 John Wiley & Sons, Ltd.     

Depuration dynamics of oysters (Crassostrea gigas) artificially contaminated by Salmonella enterica serovar Typhimurium

The State of Santa Catarina produces the greatest quantity of edible mollusks in Brazil. To guarantee sanitary qualify, mollusk cultures should be monitored for contamination by pathogenic microorganisms. A self-purification or "depuration" system that eliminates Salmonella enterica serovar Typhimurium contamination from oysters has been developed and evaluated. The depuration process occurred within a closed system, in which 1000 L of water was recirculated for 24 h. The water was sterilized with ultraviolet (UV) light, chlorine, or both together. Oysters (Crassostrea gigas) artificially contaminated with S. typhimurium were harvested every 6 h. Samples of oyster tissue were excised and both the presence and numbers of bacteria were determined. Combined UV light and chlorine treatments resulted in total elimination of bacteria within 12 h. Polymerase chain reaction detected bacteria in water exposed to the three treatments. This pioneering study is the first of its kind in Brazil and represents a major contribution to commercial mollusk culture in this country.     

Rhyacian (2.23–2.20 Ga) juvenile accretion in the southern São Francisco craton,Brazil: Geochemical and isotopic evidence from the Serrinha magmatic suite,Mineiro belt

The Serrinha magmatic suite (Mineiro belt) crops out in the southern edge of the São Francisco craton, comprising the Brito quartz-diorite, Brumado de Cima and Brumado de Baixo granodiorites, granophyres and felsic sub-volcanic and volcanic rocks, part of which intruded into the Nazareno greenstone belt. The suite rocks have petrographic features that are consistent with magma supercooling due to the low water content combined with volatile loss, leading to crystallization of quartz and alkaline feldspar at the rims of plagioclase phenocrysts (granophyric intergrowth). The investigated rocks are sub-alkaline, calc-alkaline and show low content in rare earth elements. The U–Pb zircon crystallization ages for the Brumado de Cima granodiorite [2227 ± 22 (23) Ma] and a coeval granophyre [2211 ± 22 (23) Ma], coupled with available single-zircon Pb evaporation ages for the Brito and Brumado de Baixo plutons, are significantly older than the “Minas orogeny” (ca. 2100–2050 Ga) of Quadrilátero Ferrífero area, eastward from the Serrinha suite. Our data establish an early Rhyacian event tectonically linked with the evolution of the Mineiro belt. The bulk Nd isotopic signature [low negative to positive ε_Nd(t) values] of the Serrinha samples are consistent with the important role of Paleoproterozoic mantle components in the magma genesis. The integrated geologic, geochemical and isotopic information suggests that Paleoproterozoic evolution of the Mineiro belt initiated in a passive continental margin basin with deposition of the Minas Supergroup at ca. 2500 Ma. This stage was succeeded by outboard rupture of the oceanic lithosphere with development and coalescence of progressively younger magmatic arcs during Rhyacian time. One of the earliest arcs formed the Serrinha suite. The tectonic collage of the Serrinha and Ritápolis (2190–2120 Ma) arcs produced the NE–SW Lenheiro shear zone, resulting in mylonitization and recrystallization of both the granitoid intrusions and host rocks. As a matter of fact juxtaposition of distinct magmatic units in age and origin took place along the Lenheiros structure in this sector of the Mineiro belt.     

Sediment hosted lead–zinc deposits of the Neoproterozoic Bambuí Group and correlative sequences, São Francisco Craton, Brazil: A review and a possible metallogenic evolution model

The Proterozoic sediment-hosted Zn–(Pb) sulfide and non-sulfide deposits of the São Francisco Craton, Brazil, are partially syn-diagenetic and epigenetic and were probably formed during extensional events. The majority of the deposits occur within shallow water dolomites. The Pb isotopic data of sulfides are relatively homogeneous for individual deposits and plot above the upper crust evolution curve of the Plumbotectonic model. Some of the deposits are characterized by highly radiogenic lead (²⁰⁶Pb/²⁰⁴Pb ≥ 21) originating from the highly radioactive crust of the São Francisco Craton. Pb and S isotopic data suggest the sources of metal and sulfur for the deposits to be the basement rocks and seawater sulfates in the sediments, respectively. The relatively high temperatures of formation (100 to 250 °C) and moderate salinity (3% to 20% NaCl equiv.) of the primary fluid inclusions in the sphalerite crystals suggest the participation of basinal mineralizing fluids in ore formation. The steep paleo-geothermal gradient generated by the radioactively enriched basement rocks probably assisted in heating up the circulating mineralizing fluids.     

The origin of diamonds in western Minas Gerais,Brazil

Important diamond mineralized alluvium/colluvium occurs in western Minas Gerais (WMG) in the Brasília Orogenic Belt (700-450 my). Diamonds are geographically related to glacial and periglacial sediments (Upper Proterozoic and Permo-Carboniferous), wadi and debris flow conglomerates (Lower Cretaceous and Upper Cretaceous), and ultramafic alkaline rocks (intrusive and extrusive, including kimberlites, leucitites, kamafugites, carbonatites, etc.) of Cretaceous age. Petrological data indicate that the rocks originally petrographically classified as kimberlites present mineralogical, chemical, and isotopical differences with Group I and II kimberlites and more closely resemble kamafugites. The Brasília Orogenic Belt presents features of a Wilson Cycle implying that WMG does not fulfil the geotectonic and geothermometric requisites to host primary diamond sources. An analysis of field relations and sedimentology in WMG shows that the majority of the diamonds have been transported by glacial events from the São Francisco Craton further east.     

Grenvillian thermal event and remnant charnockite: Isotopic evidence from the Chilka Lake granulite-migmatite suite in the Eastern Ghats belt, India

Spectacular exposures of granulite-migmatite occur in the Chilka Lake area of the Eastern Ghats belt. The garnetiferous granite gneiss of peraluminous granitic composition, often contains restitic metapelite inclusions and is demonstrably a product of biotite-dehydration melting in pelitic rocks. On the other hand, older layers and bands of charnockitic rocks frequently occur as dismembered patches within the peraluminous granite, thus imparting a measled appearance of the granite exposures. The partial melting and emplacement of the peraluminous granite represent the Grenvillian thermal event, as evidenced by Rb-Sr whole rock and Pb-Pb zircon dating. On the other hand, minor patches of charnockite represent migmatized relict, as evidenced by some older zircons, in addition to those of Grenvillian age.