玩具业中重金属的等离子体发射光谱分析

为了支持玩具业,许多实验室需要分析各种复杂基体中的金属含量。人们关心的主要元素是铅,但很多其他有毒元素也具有潜在的威胁,尤其对于儿童。这些重金属元素包括锑、砷、钡、镉、铬、硒、汞和铅,累积在人体中将产生不利的影响。一些塑料和木制玩具,特别是表面色彩鲜艳的玩具被证实含有更高水平的铅和其他元素,儿童因接触易摄入,相关法规对产品表面含有这些元素的材料作了一些限制。为了保证玩具和其他物品的生产、流通和销售,有必要检测其中的重金属含量。不同的管理机构对各类样品中的元素提供了限量要求。在玩具安全性的欧洲标准EN71第3部分(已纳入ISO8124-3),其中在“特定元素的迁移”一节给出了玩具材料中元素迁移的     

Groundwater recharge in arid regions: Review and critique of estimation methods

Arid-site recharge, while generally low, can be highly variable. Recharge under similar climate and soil conditions but with different plant cover and topography can vary from zero to more than the annual precipitation. Simple estimates of recharge based on fixed fractions of annual precipitation are misleading because they do not reflect the plant and soil factors controlling recharge. Detailed water balance models, successful for irrigated agriculture, fail to predict evapotranspiration accurately under conditions where plants suffer seasonal water stress and cover is sparse. Recharge, when estimated as a residual in water balance models, may be in error by as much as an order of magnitude. Similar errors can occur when soil water flow models are used with measured or estimated soil hydraulic conductivities and tension gradients. Lysimetry and tracer tests offer the best hope for evaluating recharge at arid sites, particularly in siting waste disposal facilities, where reliable recharge estimates are needed. Quantification of drainage using lysimetry over several years under a given set of soil, plant, and climate conditions for a specific site can provide a basis for calibrating models for recharge prediction. Tracer tests using such long-lived tracers as ³⁶Cl or perhaps stable isotopes (¹⁸0, deuterium) can provide qualitative estimates of recent recharge at a given site.     

Collating Historic Weather Observations for the East Asian Region:Challenges,Solutions,and Reanalyses

正1.Introduction Historic instrumental weather observations,made on land or at sea from as early as the 17th century(e.g.,Camuffo et al.,2010),are integral to extending our understanding of the decadal and centennial variations of Earth’s climate and for comparison with paleo-proxy data.The potential of such data is shown to best effect when used in dynamical 4D global     

Geology of the Severnaya Zemlya Archipelago and the North Kara Terrane in the Russian high Arctic

The Severnaya Zemlya Archipelago is located at 80°N near the continental shelf break, between the Kara and Laptev seas. Sedimentary successions of Neoproterozoic and Palaeozoic age dominate the bedrock geology. Together with Northern Tajmyr, Severnaya Zemlya constitutes the main land areas of the North Kara Terrane (NKT), which is inferred here to have been a part of the Timanide margin of Baltica, i.e. an integral part of Baltica at least since the Vendian. Vendian turbidites derived from the Timanide Orogen are inferred to have been deposited on Neoproterozoic greenschist facies, granite-intruded basement. Shallow-water siliclastic deposition in the Early to Mid-Cambrian was followed by highly organic-rich shales in the Late Cambrian and influx of more turbidites. An episode of folding, the Kan’on River deformation, separates these formations from the overlying Tremadocian conglomerates and sandstones. In the Early Ordovician, rift-related magmatic rocks accompanied the deposition of variegated marls, sandstones, carbonates and evaporites. Dark shales and gypsiferous limestones characterise the Mid-Ordovician. Late Ordovician quartz-sandstones mark a hiatus, followed by carbonate rocks that extend up into and through most of the Silurian. The latter give way upwards into Old Red Sandstones, which are inferred to have been deposited in a Caledonian foreland basin. Deformation, reaching the area in the latest Devonian or earliest Carboniferous and referred to as the Severnaya Zemlya episode, is thought to be Caledonian-related. The dominating E-vergent structure was controlled by décollement zones in Ordovician evaporite-bearing strata; detachment folds and thrusts developed in the west and were apparently impeded by a barrier of Ordovician igneous rocks in the east. Below the décollement zones, the Neoproterozoic to Early Ordovician succession was deformed into open to close folds. The exposed strata in the lower structural level have been juxtaposed with those in the upper structural level along the major N-trending Fiordovoe Lake Fault Zone, which involved several kilometres of dextral strike-slip movement and downthrow to the west. A major Early Carboniferous unconformity separates the folded Mid-Palaeozoic and older rocks from overlying Carboniferous formations, as on Franz Joseph Land and Svalbard. Subsequent latest Palaeozoic to Early Mesozoic orogeny, as on Taimyr, apparently had little influence on the Severnaya Zemlya successions.     

《坤輿万国全图》与《利玛窦中国札记》中外译本考疑

金尼阁编译的《利玛窦中国札记》多种欧洲文字版本之间存在翻译差异,而300年后出版的英译本和中译本与原文存在严重错漏。600页的札记,利玛窦只用不到两页的篇幅叙述测绘《坤輿万国全图》一事,连实际比例尺的描述也不清楚。利玛窦承认没有见过其他的版本,"六幅版"地图出现在南京或北京,个别欧洲文字翻译版本不一,《坤輿万国全图》究竟是在南京还是北京完成的也有疑问。《利玛窦中国札记》用的是中国传统的测绘术语,指出地图的错误是针对西方地图而不是中国地图。《坤輿万国全图》中一半的中文地名,当时欧洲地图没有对应。1593年,利玛窦尚未制作《坤輿万国全图》,"六幅版"中文世界地图已出现在南京。因此,《坤輿万国全图》原本早已存在,《坤輿万国全图》应是郑和时代(1405—1433)大航海的成果,中国的地图学,不是西学东渐,甚至有可能是中国的世界地理与地图学流传到西方。世界地图史应该还原中国对地理大发现与地图学的贡献。     

Cloud Radiative Effects and Changes Simulated by the Coupled Model Intercomparison Project Phase 5 Models

Using 32 CMIP5(Coupled Model Intercomparison Project Phase 5) models, this study examines the veracity in the simulation of cloud amount and their radiative effects(CREs) in the historical run driven by observed external radiative forcing for 1850–2005, and their future changes in the RCP(Representative Concentration Pathway) 4.5 scenario runs for2006–2100. Validation metrics for the historical run are designed to examine the accuracy in the representation of spatial patterns for climatological mean, and annual and interannual variations of clouds and CREs. The models show large spread in the simulation of cloud amounts, specifically in the low cloud amount. The observed relationship between cloud amount and the controlling large-scale environment are also reproduced diversely by various models. Based on the validation metrics,four models—ACCESS1.0, ACCESS1.3, Had GEM2-CC, and Had GEM2-ES—are selected as best models, and the average of the four models performs more skillfully than the multimodel ensemble average.All models project global-mean SST warming at the increase of the greenhouse gases, but the magnitude varies across the simulations between 1 and 2 K, which is largely attributable to the difference in the change of cloud amount and distribution. The models that simulate more SST warming show a greater increase in the net CRE due to reduced low cloud and increased incoming shortwave radiation, particularly over the regions of marine boundary layer in the subtropics. Selected best-performing models project a significant reduction in global-mean cloud amount of about-0.99% K~(-1)and net radiative warming of 0.46 W m~(-2)K~(-1), suggesting a role of positive feedback to global warming.     

A SUGGESTION OF A NEW METHOD FOR GEOLOGICAL SURVEY OF IGNEOUS INTRUSIONS

It may be safely presumed that few of us who have worked in the field as a geological surveyor would dissent in making an open confession of our unfortunate attitude towards igneous rocks particularly those of a massive form. These obstacles, as one is apt to regard them, are the unruly bodies