Ambiguous biogeographical patterns mask a more complete understanding of the Ordovician to Devonian evolution of Japan

Fossil assemblages of the Ordovician to Devonian successions of Japan suggest complex temporal, environmental and geographical controls on their biogeographical signature. Thus, limited similarity at the species‐level between the trilobite, brachiopod and ostracod faunas of the South Kitakami, Hida‐Gaien and Kurosegawa terranes in part reflects the sporadic stratigraphic distribution of shelly fauna within these terranes. As a result, and with the exception of corals and pan‐tropical radiolarians, species‐level similarities are greater with other regions of East Asia and Australia than amongst the Japanese terranes. The Silurian faunas of the South Kitakami Terrane have affinities with North America, Europe, Central Asia and Australia, but there is no overriding signature to support proximity either to South China or Gondwana. Notably, brachiopod and trilobite faunas of the Middle Devonian suggest strong connections with North China. Trilobite, coral and ostracod faunas of the Hida‐Gaien Terrane show affinity, including at species level, with Siluro‐Devonian faunas from westerly‐situated palaeocontinents, especially those of Central Asian and European affinity, suggesting a continuation of the Central Asian Orogenic Belt, or of its associated lithofacies. Greater diversity of groups such as ostracods and trilobites in this terrane may signal closer links with continental shelf faunas of East Asia. The dominant biogeographical signature of the Kurosegawa Terrane is from corals and trilobites, suggesting links with the Siluro‐Devonian of Central Asia, Australia and South China. The variable biogeographic signal of the Japanese faunas may reflect the lifestyles of organisms with different physiologies and larval dispersal mechanisms, as well as the relative incompleteness of the Japanese fossil record. The present state of knowledge of the faunas cautions against placing Japan in relative proximity to the North or South China plates, or of presenting the Japanese terranes as a unified island arc to the north of the South China Plate during the Early Palaeozoic.     

Onboard experiment investigating metal leaching of fresh hydrothermal sulfide cores into seawater

We observed the initial release rate of metals from four fresh (i.e., without long time exposure to the atmosphere) hydrothermal sulfide cores into artificial seawater. The sulfide samples were collected by seafloor drilling from the Okinawa Trough by D/V Chikyu, powdered under inert gas, and immediately subjected to onboard metal-leaching experiments at different temperatures (5 °C and 20 °C), and under different redox conditions (oxic and anoxic), for 1–30 h. Zinc and Pb were preferentially released from sulfide samples containing various metals (i.e., Mn, Fe, Cu, Zn, Cd, and Pb) into seawater. Under oxic experimental conditions, Zn and Pb dissolution rates from two sulfide samples composed mainly of iron disulfide minerals (pyrite and marcasite) were higher than those from two other sulfide samples with abundant sphalerite, galena, and/or silicate minerals. Scanning electron microscopy confirmed that the high metal-releasing sample contained several galvanic couples of iron disulfide with other sulfide minerals, whereas the low metal-releasing sample contained fewer galvanic couples or were coated by a silicate mineral. The experiments overall confirmed that the galvanic effects with iron disulfide minerals greatly induce the initial release of Zn and Pb from hydrothermal sulfides into seawater, especially under warm oxic conditions.     

A Simple Method for Precise Determination of 23 Trace Elements in Granitic Rocks by ICP-MS after Lithium Tetraborate Fusion

Abstract. An improved alkali fusion method followed by HF-HNO₃-HC1O₄ treatment is performed for simultaneous determination of 23 trace elements (Sr, Y, Zr, Nb, Ba, Hf, Ta, Th, U, and REE) by ICP-MS in rock reference materials: basaltic rocks (JB-2, JB-3) and granitic rocks (JG-la, JG-2, JG-3). Our improved method offers several advantages including: (1) suppression of whitish precipitates probably composed of insoluble fluorides by addition of HCIO4, (2) simple and reliable preparation procedure, (3) instrument calibration which enables straightforward simultaneous multi-elemental analysis, and (4) the very low background levels by using pure lithium tetraborate flux. We obtained the analytical results with a reproducibility of mostly <2 % (1) for the basaltic rocks and <7 % for the granitic rocks. The higher relative standard deviation (RSD) values for granitic rocks may be attributed to sample heterogeneity of coarse-grained granitic rocks. The analytical results of the granitic rocks demonstrate that Zr and Hf abundances are consistent with the compiled values and that REE concentrations agree well with recently published data, suggesting that the Li₂B₄O₇ fusion method applied in the present study is suitable for the analysis of the granitic rocks.     

Geochemical Features and Tectonic Setting of Greenstones from Kunimiyama, Northern Chichibu Belt, Central Shikoku, Japan

Abstract. We report whole‐rock chemical data for the greenstones from the Kunimiyama area in the Northern Chichibu Belt and their implications on the tectonic setting of these rocks. The Kunimiyama greenstones are associated with stratiform fer‐romanganese deposits or bedded cherts in the northern part of the study area, but are closely associated with a thick limestone block or bedded cherts in the southern part. The constituent minerals of greenstones are albitized plagioclase, clinopy‐roxene, chlorite, calcite, epidote, pumpellyite, prehnite, quartz, celadonite, sericite and opaque minerals such as iron oxyhy‐droxide and hematite. These mineral assemblages, epidote + pumpellyite + chlorite and chlorite + pumpellyite + prehnite, suggest that the metamorphic grade of greenstones from the Kunimiyama area is prehnite‐pumpellyite facies. The whole‐rock chemical compositions of greenstones associated with ferromanganese deposits are generally similar to those of normal mid‐ocean ridge basalt (N‐MORB). In contrast, the chemical compositions of the greenstones associated with the limestone block are comparable to those of ocean island alkaline basalt. Greenstones associated with bedded cherts are of enriched MORB and ocean island basalt, as well as N‐MORB origins, suggesting they probably formed as a result of plume‐related MOR volcanism in the Panthalassa Ocean in Early Permian and by tectonic mixing of ocean island basalts with oceanic ridge crustal fragments during accretion/subduction processes. These geological and geochemical lines of evidence suggest that the Kunimiyama greenstones are allochthonous blocks of accreted oceanic crust and seamounts. The ferromanganese deposits are frequently accompanied by reddish greenstones. Compared to common greenish greenstones, the reddish greenstones are characterized by high MnO and rare earth element contents and distinct negative Ce anomalies, implying a slight contribution of hydro thermal component forming the ferromanganese deposits.     

Estimation of underwater scattering radiances up to the third order

Vertical distribution of underwater scattering radiances of the first, the second and the third order is estimated by the Jerlov's method. In the estimation the volume attenuation coefficient and the volume scattering function are assumed to be constant in near surface layer, and the sky radiation separated from solar radiation to be a parallel beam and to fall into the sea in the vertical direction only.In the zenith direction the second scattering radiance is more intense than the first scattering radiance in near surface layer. As for the total radiance which is a sum of radiances up to the third order, the zenith radiation is largest, the nadir radiation is moderate and the horizontal radiation is least.     

On “A model of impulsive loop flares revisited” by Smith and Brecht

A criticism of my papers was recently presented by Smith and Brecht, that the electron distribution resulting from anomalous heat conduction is not unstable for electron plasma waves. The aim of the present letter is to show that their criticism is irrelevant.     

Distribution of fault rocks in the fracture zone of the Nojima Fault at a depth of 1140 m: Observations from the Hirabayashi NIED drill core

Abstract Characteristics of deformation and alteration of the 1140 m deep fracture zone of the Nojima Fault are described based on mesoscopic (to the naked eye) and microscopic (by both optical and scanning electron microscopes) observations of the Hirabayashi National Research Institute for Earth Science and Disaster Prevention (NIED) drill core. Three types of fault rocks; that is, fault breccia, fault gouge and cataclasite, appear in the central part of the fault zone and two types of weakly deformed and/or altered rocks; that is, weakly deformed and altered granodiorite and altered granodiorite, are located in the outside of the central part of the fault zone (damaged zone). Cataclasite appears occasionally in the damaged zone. Six distinct, thin foliated fault gouge zones, which dip to the south-east, appear clearly in the very central part of the fracture zone. Slickenlines plunging to the north-east are observed on the surface of the newest gouge. Based on the observations of XZ thin sections, these slickenlines and the newest gouge have the same kinematics as the 1995 Hyogo-ken Nanbu earthquake (Kobe earthquake), which was dextral-reverse slip. Scanning electron microscopy observations of the freeze-dried fault gouge show that a large amount of void space is maintained locally, which might play an important role as a path for fluid migration and the existence of either heterogeneity of pore fluid pressure or strain localization.     

Whole-rock Geochemistry of Basic Schists from the Besshi Area, Central Shikoku: Implications for the Tectonic Setting of the Besshi Sulfide Deposit

Abstract. Whole-rock chemical compositions of the Besshi basic schist closely associated with the Besshi massive sulfide deposit from the Sanbagawa Belt are reported. Studied samples were collected from four outcrops around the Dozan-goe, central Shikoku. Common metamorphic mineral assemblage of the basic schist is albite + epidote + actinolite + chlorite ± muscovite ± quartz. Major element contents are similar to those of typical tholeiitic basalts. Trace element patterns of the basic schist normalized to normal mid-ocean ridge basalt (N-MORB) are generally flat, although concentrations of highly mobile large-ion lithophile elements are quite variable. Chondrite-normalized rare earth element (REE) patterns are flat to slightly light REE-depleted patterns. In the Hf-Th-Ta and Nb-Zr-Y discrimination diagrams, basic schist samples closely associated with the sulfide deposit are plotted within the N-MORB field. The Th/Nb ratios of the basic schist are also comparable to those of N-MORB. These geo-chemical lines of evidence indicate that the protolith of the Besshi basic schist is N-MORB and the Besshi sulfide deposit was formed by hydrothermal activity in conjunction with MOR volcanism.