Modelling the transverse behaviour of circular tunnels in structured clayey soils during earthquakes

Acta Geotechnica - The paper presents novel results from advanced numerical simulations of the transverse behaviour of shallow circular tunnels in natural clays accounting for soil structure...     

Effects of low- to high-angle normal faults on sedimentary architectures in the Eocene Wenchang Formation,Enping Sag,Pearl River Mouth Basin,South China Sea

The effects of low- to high-angle (>30°) normal faults on sedimentary architectural units in the Eocene Wenchang Formation, Enping Sag, Pearl River Mouth Basin (PRMB), South China Sea were investigated utilising a high-quality 3D seismic data set and restored paleogeomorphology. It has been shown that sequence stratigraphic units and sedimentary architecture are significantly controlled by the low- to high-angle normal faults. The Wenchang Formation, a second-order sequence, can be subdivided into two para-second-sequences (the Lower and Upper Wenchang sequences, E₂W^L and E₂W^U) and seven third-order sequences (from base to top: SQ1～SQ7). The low-angle fault confined sequence architecture of the Wenchang Formation is mainly characterised by lateral stacking with the ratio of the vertical subsidence (V) to horizontal slip (H) being reduced from 1/2 for E₂W^L to 1/6 for E₂W^U. In contrast, the high-angle fault confined sequence is characterised by vertical stacking with the ratio of V/H close to 1 for sequences SQ1 to SQ7. In the 3D seismic area, the features of sediment-dispersal pattern were interpreted based on an integrated analysis of paleogeomorphology, seismic reflection characteristics, stratal thickness distribution and multiple attribute clustering. The results show that the large-scale fan delta, belt-shape lacustrine deposit and bird-foot braided delta systems mainly developed in the low-angle fault confined sequences, whereas small-scale fan delta, rhombus-shaped lacustrine deposit and lobe-shaped braided delta systems inherited tectono-sedimentary architectures in the high-angle fault confined sequences.     

普若岗日冰原毗邻地区风沙地貌及其环境演变

冰川作用形成的大面积的冰碛物沉积及寒冻风化是高寒区风沙沉积的主要物质来源.风沙地貌的发育与高寒区环境密切相关,冻结作用使沙丘发育以加积作用为主,形成了高大的新月形沙丘.沙丘的侵蚀与移动主要发生在暖季,新月形沙丘运动速度相当缓慢,年平均水平移动量约1.8～0.5cm·a^-1,加积速率约0.3～0.08cm·a^-1.普若岗日冰原毗邻地区的环境变化主要受温度条件制约,沙丘腐殖质层沉积年代与我国东部沙区古沙丘、敦德冰芯具有一定的相关性,可以认为西南季风的强度对本区具有重要的作用.高原下垫面的变化造成太阳辐射差异,是引起西南季风强弱,造成高原腹地温度与降水随之变化的重要原因.     

An electrochemical study of pyrite oxidation in the presence of carbon coatings in cyanide medium

The anodic and cathodic behaviour of pyrite with clay and different carbon coatings of activated carbon, graphite and carbonaceous matter in cyanide medium was investigated using the potentiodynamic method. The presence of clay coating did not change the polarisation curve appearance for either the anodic oxidation of pyrite or the cathodic reduction of oxygen or the potential of the current plateau, but only decreased the plateau current especially at a higher coating thickness. The presence of the carbon coatings marginally shifted the rest potential for pyrite to a more anodic position and slightly changed the polarisation curve appearance for pyrite oxidation. The current density for pyrite oxidation largely increased in the presence of the carbon coatings, the potential at the plateau shifted to more cathodic positions, and the plateau width became smaller. These effects became more noticeable at a higher coating thickness. The activated carbon, graphite and carbonaceous matter coatings performed similarly in affecting pyrite oxidation at a similar thickness. The carbon coatings significantly increased the limiting current densities for oxygen reduction on pyrite, and the limiting current plateau became steeper at a higher coating thickness. The carbon coatings increased the limiting current density for oxygen reduction to a similar extent at a low coating thickness, but increased to varied extents at a higher coating thickness. The carbon coatings also greatly increased the cathodic current density for gold reduction on pyrite. The enhancement of pyrite oxidation and oxygen or gold reduction on pyrite by the carbon coatings was likely attributed to the electrochemical interaction between pyrite and the carbon materials with electron-rich surfaces and high conductivity. The presence of the carbon coatings significantly increased the oxidation of pyrite in aerated cyanide solutions and the preg-robbing of pyrite especially at a higher coating thickness.     

苏北榴辉岩的稀土元素地球化学及其成因讨论

江苏北部的榴辉岩出露于东海群变质岩系中，榴辉岩的产状是：１）呈似层状或透镜状产于东海群片麻岩中；２）呈不规则团块状产于超镁铁岩中，或与超镁铁岩伴生。全岩分析表明，前者相当橄榄拉斑玄琥岩或石英拉斑玄武岩，后者相当橄榄玄武岩或橄榄拉斑玄武岩。     

Zero-valent iron/persulfate(Fe0/PS) oxidation acetaminophen in water

Zero-valent iron (Fe⁰), as an alternative iron source, was evaluated to activate persulfate (PS) to degrade acetaminophen (APAP), a representative pharmaceutically active compound in water. Effects of key factors in the so-called Fe⁰/PS process, including Fe⁰ dosage, initial pH, temperatures and chelating agents, were studied. Under all the conditions tested, the APAP degradation followed a pseudo-first-order kinetics pattern. The degradation efficiency of APAP was highest when the Fe⁰ to PS molar ratio increased to 1:1, and the degradation rate constant and removal were 23.19 × 10^?3 min^?1 and 93.19 %, respectively. Comparing with Fe²⁺, Fe⁰ served as an alternative iron source that can gradually release Fe²⁺ into water, thereby consistently activating PS to produce sulfate radicals. The Fe⁰/PS system was effective in a broader pH range from 3 to 8.5. Heat could facilitate production of sulfate radicals and enhance the APAP degradation in the Fe⁰/PS system. High reaction temperature also improved the Fe²⁺/PS oxidation of APAP. Finally, sodium citrate (a chelating agent) at an appropriate concentration could improve the APAP degradation rate in the Fe²⁺/PS and Fe⁰/PS system. The optimal molar ratio of Fe⁰ to citrate depended on solution pH. Our results demonstrated that Fe⁰ was an alternative iron source to activate PS to degrade APAP in water.     

Characteristics and circulation background of extreme precipitation over East China

Natural Hazards - Using the observed daily precipitation data across East China, this paper analyzes spatiotemporal changes of annual and seasonal extreme precipitation indices during...     

昆明市地热田越流含水系统中地下热水的数值模拟

深层基岩地下（热）水水化学污染问题日趋严重,急需定量而仿真地模拟和预报天然状态和各种人为工程经济活动下地下（热）水流动及溶质（或污染物）的运移。在充分认识地质、水文地质条件的基础上,建立了考虑温压变化和越流条件的昆明市地热田深层基岩地下热水系统中水流和溶质运移的准三维非稳定流数学模型。模型用于开采条件下地热田地下热水水位及 F^－、Cl^－浓度的模拟,模拟结果具有较高的仿真性,拟合误差一般小于 2％～5％,表明模型合理、可靠。应用所建模型预测了开采条件下昆明市地热田II块段地下热水流场和溶质浓度动态的变化趋势,并提出了控制地下热水环境进一步恶化的措施。     

Circulation background of climate patterns in the past millennium: Uncertainty analysis and re-reconstruction of ENSO-like state

The question of whether or not global warming has paused since more than ten years ago, namely "warming hiatus", has attracted the attention of climate science community including the IPCC. Some authors have attributed the "warming hiatus" to the internal changes in the climate system, i.e., the recombination of ocean-atmosphere circulations. Therefore, it is necessary to propose higher requirements on reconstructing circulation background of climate change for the past millennium. However, the analyses of changes in atmospheric circulation over the last millennium as well as the conclusions of related regional climate patterns are so widely different and contradictory, bringing uncertainties to our understanding of regional even global climate change to a great extent. On the other hand, in the last 10 years the high-precision U/Th-dated stalagmite oxygen isotope ratio(δ~(18)O) sequences provided an accurate chronological frame for the paleoclimate study of the middle and late Pleistocene, in which all authors from China took the Chinese stalagmite δ~(18)O as the summer monsoon index without exception. However, this point of view misleads the climate scientists into thinking that the stalagmite δ~(18)O can be as the proxy of precipitation amount. Nevertheless, it is well known that all of these records have a lot in common in the low frequency trend. However, most sequences cannot be calibrated by instrumental precipitation records, and thus the uncertainty of the climate research framework of China and even of the world has increased. Therefore, it is imperative for climatology to clarify the origin of contradiction and to reduce the uncertainty as early as possible. On the basis of analyzing the significance of stalagmite δ~(18)O in the monsoon regions of China, the author tries to propose a new circulation proxy in this paper: integrating the Chinese stalagmite oxygen isotope sequence to reconstruct the tropical Pacific sea surface temperature gradient, i.e., the large-scale ENSO-like state over the past millennium. Furthermore, the author speculates that it was warm in the modern times and the Medieval Period, but the circulation recombination was different in both periods. And this inference could be supported by the longer record since Last Glacial Maximum. In other words, the attribution analysis of the identical low-frequency trends of Chinese stalagmite δ~(18)O on a large scale shows that the ENSO-like state controls the climate change in the monsoon regions of China at different time scales(from interannual to century or even longer time scales). Wherein the important connection of circulations is the western Pacific subtropical high(WPSH), that is to say, besides the interannual and decadal time scales, the WPSH would possess the circulation mode on longer timescales. For example, we may discuss the change of the WPSH in the whole Holocene epoch, i.e., the half precession period. These discussions could make sense to the study of not only the paleoclimate but also the modern climate.     

P-wave attenuation anisotropy in TI media and its application in fracture parameters inversion

The existence of aligned fractures in fluid-saturated rocks leads to obvious attenuation anisotropy and velocity anisotropy. Attenuation anisotropy analysis can be applied to estimate fracture density and scale, which provide important information for reservoir identification. This paper derives P-wave attenuation anisotropy in the ATI media where the symmetry axis is in the arbitrary direction theoretically and modifies the spectral ratio method to measure attenuation anisotropy in the ATI media, thus avoiding a large measurement error when applied to wide azimuth or full azimuth data. Fracture dip and azimuth can be estimated through attenuation anisotropy analysis. For small-scale fractures, fracture scale and fracture density can be determined with enhanced convergence if velocity and attenuation information are both used. We also apply the modified spectralratio method to microseismic field data from an oilfield in East China and extract the fracture dip through attenuation anisotropy analysis. The result agrees with the microseismic monitoring.