碳棒涂膜式PVC膜铯离子选择电极的研制和应用

本文作者研制成功以四苯硼铯为活性物质的碳棒涂膜式PVC膜铯离子选择性电极。电极最佳膜组成:四苯硼铯5mg,邻苯二甲酸二丁酯0.4ml,硝基苯0.2ml,PVC粉0.2g。电极性能优良,制作简单,操作方便。结合大粒度磷钼酸铵和结晶形锑酸分离K~+,Na~+,巳将此电极用于卤水样中铯的测定,结果令人满意。     

从铜的地球化学行为探讨常宁铜鼓塘富铜矿床的成因

常宁铜鼓塘富铜(银铀)矿床,以Ⅵ号主矿体为代表,具有以辉铜矿为主的矿物组合。本文根据Cu、(Ag)的地球化学行为,阐述了不同条件下,Cu、Fe与S、O的亲疏倾向,从而形成各矿体独具特色的矿物共生组合特征。进而讨论了矿床的特定成矿环境和典型岩溶成因。最后,笔者综合分析了多种有利成矿因素,指出金鸡岭背斜及其以北地段,是普查同类型富铜矿床的远景地区。     

中心取样空心螺旋钻进法

中心取样空心螺旋钻进法是新发展起来的钻进工艺,阐述了螺旋钻进法的应用与发展.并论述了各种中心取样空心螺旋钻进法的钻具结构与施工方法.包括内钻杆柱式中心取样钻具、绳索升降式中心取样钻具.摩斯取样系统以及詹姆科绳索回收取样装置.     

Microseismicity and tectonics of Sinai

Five microearthquake seismographs were used at 11 sites in northern Sinai in the period February 1987 to February 1988 to study the microseismicity of the area around the Maghara coal mine for mine-development studies. A total of 270 events were recorded on 850 records. The magnitude, epicenter and depth of each event were calculated using suitable software for an Egyptian Geological Survey and Mining Authority's (EGSMA) XT computer. The interpretation of the seismic activity in the area is given in view of plate tectonics, the Sinai subplate boundary follows the Gulf of Aqaba and the Dead Sea. The plate and subplate boundaries are presently active, and there seems to be a diffuse zone of deformation between “NW Africa” and “Nubia” affecting the Cairo-Suez district.     

Dynamic response of surface foundations on layered media

The steady-state dynamic responses of both flexible and rigid massless foundations with complex geometries on layered media are studied by the finite layer method. The discussion covers both the horizontal and vertical responses including the rocking mode of vibration. The effect of various parameters, namely, the size of the domain, the number of harmonic terms and the material damping of the soil media, on the convergence and accuracy of the results is investigated. Non-homogeneous soil profiles are treated as a matter of course. The results obtained are compared with solutions by other theoretical methods.     

Oxygen diffusion rates in quartz exchanged with CO2

Oxygen self diffusion rates were determined in quartz samples exchanged with¹⁸O-enriched CO₂ between 745 and 900°C and various pressures, and the diffusion profiles were measured using an ion microprobe. The activation energy (Q) and preexponential factor (D₀) at P(CO₂) = P(tot) = 100 bar, for diffusion parallel to the c-axis are 159 ( ± 13) kJ/g atom and 2.10 (+0.75/ −0.55) × 10⁻⁸ cm²/s. This rate is approximately 100 times slower than that obtained from hydrothermal experiments and 100 times faster than a previous 1-bar quartz-O₂ exchange experiment. The oxygen diffusion rate measured at 0.6 bar, 888°C, and at 900°C in vacuum is in agreement with the previous 1-bar exchange experiments with¹⁸O₂. The effect of higher CO₂ pressures is small. At 900°C, the diffusion rate exchanged with CO₂ is = 2.35 × 10⁻¹⁵ cm²/s at 100 bar, 2.24 × 10⁻¹⁵ cm²/s at 3.45 kbar and 8.13 × 10⁻¹⁵ cm²/s at 7.2 kbar.There is probably a diffusing species, other than oxygen, that enhances the oxygen diffusion rate in these quartz-CO₂ systems, relative to that occurring at very low pressures or in a vacuum. The effect of this diffusing species, however, is not as strong as that associated with H₂O. Preserved oxygen isotope fractionations between coexisting minerals in a slowly cooled, high-grade metamorphic terrane will vary depending upon whether a water-rich phase was present or not. Closure temperatures will be approximately 100°C higher in rocks where no water-rich phase was present during cooling. The measured fractionations between coexisting minerals in metamorphic rocks may potentially be used as a sensor of water presence during retrogression.     

Time-dependent behaviour of the rock mass

Summary The strength of intact rock and the rock mass is time-dependent. For intact rock experimental verification is available, for the rock mass the scale of time-dependence is a matter of judgement. Rock mass classifications do however emphasize the effect of time on tunnel stability. This paper examines the source of time-dependence in rocks and the rock mass and suggests a technique for estimating the long term strength. The long term strength of the rock mass is controlled by the time-dependent weakening of intact rock. Frictional resistance, a major source of rock mass strength, increases rather than decreases with time. Lifetime estimation for rocks can be accomplished phenomenologically or mechanistically. The first is a statistical process of wide applicability, the second is more restrictive in usage as its applies only to materials that suffer time-dependent strain (creep). Although the mechanistic route is more appealing, it has a major drawback as it concentrates on steady state creep. There is no strong evidence for steady state creep in rocks. The technique for long term prediction is developed through the analysis of the failure rate under constant load. The failure rate for a given load and environment is established from the frequency distribution of time-to-failure data as measured in static fatigue tests. As expected, the failure rate is strongly affected by both the loading and the environmental condition. The influence, however, is systematic and predictable.     

东南亚夏季风中断、过渡与活跃期的区域能量学研究

对两次季风演变过程的能量学研究表明，季风演变具有鲜明的阶段性能量学特征。中断期，积云加热小，两个转换函数值很小；过渡期，积云加热增强明显，两个转换函数值迅速加大，边界输送作用也明显朝有利方向变化，同时，纬向平均气流变为向季风供应扰动动能；活跃期，大尺度加热变得重要，积云加热维持，两个转换函数也保持大的正值。分析表明，印度季风东传对东南亚季风活跃的触发作用是重要的，但季风活跃的维持则主要依靠区域内部能量学过程。     

BALLOON-BORNE MEASUREMENTS OF AEROSOL VERTICAL DISTRIBUTIONS OVER BEIJING DURING THE SUMMER AND AUTUMN OF 1993

The results of two balloon soundings during the summer and autumn of 1993 from the Xianghe Observation Station are being utilized in a study of the temporal and spatial distribution of the atmospheric aerosols.The balloon,gondola,instrumentation and atmospheric conditions during the observation period are described.The temporal and spatial characteristics of aerosol concentration,size ratio,mixing ratio,and size distribution for both troposphere and strato-sphere are presented and analyzed.     

研究地球化学机制的热动力学方法

章介绍了热动力学方法的研究历史，研究原理以及在研究地球化学机制中的应用，如石膏的脱水反应机制可分二步进行，ＣａＳｏ４．２Ｈ２Ｏ→ＣａＳＯ４．１／２Ｈ２Ｏ→ＣＳＯ４活化能Ｅ＝１１８．７ＫＪ／ｍｏｌ，脱水温度Ｔ＝３８０．６０，呱应速率Ｋ１＝４．４１×１０＾－４Ｓ＾－１方解石的溶解反应机制，在０－５０００Ｓ期间以溶解反应为主，嗣后，发生周期性的溶解反应，热谱图上表现为化学振荡。