The Kellwasser events in the Upper Devonian Frasnian to Famennian transition in the Toc Tat Formation,northern Vietnam

Upper Devonian carbonates of the Toc Tat Formation in the Si Phai Pass area of Dong Van District, northern Vietnam were deposited in carbonate platform, slope, and basin environments. These carbonates yield abundant conodonts indicative of the Palmatolepis nasuta, Pa. linguiformis and Pa. triangularis zones, the Frasnian–Famennian stage boundary being identified by the first occurrence of Pa. triangularis. Two positive carbon isotope excursions are recognized, the lower excursion peaking in the interval of the lower to middle Pa. nasuta Zone, whilst the upper excursion peaks just above the local Frasnian–Famennian boundary. Based on the biostratigraphy, these excursions equate to the Lower and Upper Kellwasser events. Locally, tentaculitoid taxa (Nowakia, Styliolina, Homoctenus, and Metastyliolina?) are abundant in the interval of the Pa. nasuta Zone, but show a drastic decline in abundance before the Lower Kellwasser Event, and only two taxa survived into the Famennian.     

Mobility-dependent response of aquatic animal species richness to a wetland network in an agricultural landscape

Management of wetland connectivity is important for biodiversity conservation. In the modern agricultural landscape, the natural connections between floodplain wetlands have been greatly altered. Agricultural ditches and channelized streams are widely distributed in floodplains, which may contribute to the maintenance of wetland connectivity and biodiversity. To determine how these watercourse networks affect wetland biodiversity, we examined the relationship between the species richness of aquatic animals and wetland connectivity, with a special focus on species mobility. From July to August 2011, fish and aquatic insects were collected from 24 wetlands in northern Japan. To determine the degree of wetland connectivity, we assessed the relative importance of individual wetlands in maintaining the entire wetland network using two connectivity indices: hydrologic connectivity via watercourses and spatial connectivity defined as Euclidian distances between wetlands using graph theory. We found that only high mobility groups of both taxa could enhance species richness in either a hydrologic (fish) or spatial (insect) wetland network. The species richness of insects with high-flying ability was found to increase as spatial connectivity increased. Furthermore, the species richness of fish with high-swimming ability was positively influenced by hydrologic connectivity, most likely because highly mobile species were able to reach suitable habitats and migrate from source populations in a wetland network owing to their good mobility. Our findings indicate that hydrologic network is important for maintaining biodiversity as well as spatial connectivity. It is important to focus conservation efforts on key wetlands with high hydrologic and spatial connectivity in future wetland management.     

Evolution processes of Ordovician–Devonian arc system in the South‐Kitakami Massif and its relevance to the Ordovician ophiolite pulse

The South Kitakami Massif is one of the oldest geological domains in Japan having Silurian strata with acidic pyroclastic rocks and Ordovician–Silurian granodiorite–tonalite basement, suggesting that it was matured enough to develop acidic volcanisms in the Silurian period. On the northern and western margin of the South Kitakami Massif, an Ordovician arc ophiolite (Hayachine–Miyamori Ophiolite) and high‐pressure and low‐temperature metamorphic rocks (Motai metamorphic rocks) exhumed sometime in the Ordovician–Devonian periods are distributed. Chronological, geological, and petrochemical studies on the Hayachine–Miyamori Ophiolite, Motai metamorphic rocks, and other early Paleozoic geological units of the South Kitakami Massif are reviewed for reconstruction of the South Kitakami arc system during Ordovician to Devonian times with supplementary new data. The reconstruction suggests a change in the convergence polarity from eastward‐ to westward‐dipping subduction sometime before the Late Devonian period. The Hayachine–Miyamori Ophiolite was developed above the eastward‐dipping subduction through three distinctive stages. Two separate stages of overriding plate extension inducing decompressional melting with minor involvement of slab‐derived fluid occurred before and after a stage of melting under strong influence of slab‐derived fluids. The first overriding plate extension took place in the back‐arc side forming a back‐arc basin. The second one took place immediately before the ophiolite exhumation and near the fore‐arc region. We postulate that the second decompressional melting was triggered by slab breakoff, which was preceded by slab rollback inducing trench‐parallel wedge mantle flow and non‐steady fluid and heat transport leaving exceptionally hydrous residual mantle. The formation history of the Hayachine–Miyamori Ophiolite implies that weaker plate coupling may provide preferential conditions for exhumation of very hydrous mantle. Very hydrous peridotites involved in arc magmatism have not yet been discovered except for in the Cambrian–Ordovician periods, suggesting its implications for global geodynamics, such as the thermal state and water circulation in the mantle.     

Compression behaviors of distorted rutile-type hydrous phases, MOOH (M?=?Ga, In, Cr) and CrOOD

X-ray diffraction measurements of distorted rutile-type oxyhydroxides β-GaOOH, InOOH, β-CrOOH, and β-CrOOD were taken at a maximum pressure of up to 35 GPa under quasi-hydrostatic conditions, at ambient temperature. Anomalies in the evolution of the relative lattice constants and the axial ratios of β-GaOOH, InOOH, and β-CrOOD suggest anisotropic stiffening along the a- and/or b-axes where the hydrogen bond is formed. The changes were observed at 15 GPa in β-GaOOH and InOOH and at 4 GPa in β-CrOOD. The pressures were higher in oxyhydroxides that have longer O…O distances of the hydrogen bond at ambient pressure. In contrast, such stiffening behavior was not observed in CrOOH, which has a significant short O…O distance and strong hydrogen bond. The stiffening behaviors observed in the present study can be attributed to the symmetrization of the hydrogen bonds in oxyhydroxides, as was previously found in δ-AlOOH(D).     

Pressure and temperature dependence of the viscosity of a NaAlSi<Subscript>2</Subscript>O<Subscript>6</Subscript> melt

The viscosity of a silicate melt of composition NaAlSi₂O₆ was measured at pressures from 1.6 to 5.5 GPa and at temperatures from 1,350 to 1,880°C. We employed in situ falling sphere viscometry using X-ray radiography. We found that the viscosity of the NaAlSi₂O₆ melt decreased with increasing pressure up to 2 GPa. The pressure dependence of viscosity is diminished above 2 GPa. By using the relationship between the logarithm of viscosity and the reciprocal temperature, the activation energies for viscous flow were calculated to be 3.7 ± 0.4 × 10² and 3.7 ± 0.5 × 10² kJ/mol at 2.2 and 2.9 GPa, respectively.     

In situ observation of a garnet/perovskite transition in CaGeO<Subscript>3</Subscript>

We used an in situ measurement method to investigate the phase transition of CaGeO₃ polymorphs under high pressures and temperatures. A multi-anvil high-pressure apparatus combined with intense synchrotron X-ray radiation was used. The transition boundary between a garnet and a perovskite phase at T = 900–1,650 K and P = 3–8 GPa was determined as occurring at P (GPa) = 9.0−0.0023 × T (K). The transition pressure determined in our study is in general agreement with that observed in previous high-pressure experiments. The slope, dP/dT, of the transition determined in our study is consistent with that calculated from calorimetry data.     

Applicability of numerical models to nonlinear dispersive waves

The applicability of three different wave-propagation models in nonlinear dispersive wave fields has been investigated. The numerical models tested here are based on three different wave theories: a fully nonlinear potential theory, a Stokes second-order theory, and a Boussinesq-type theory with an improved dispersion relation. Physical experiments and computations were conducted for wave evolutions during passage over a submerged shelf under various wave conditions. As expected, the fully nonlinear solutions agree better with the measurements than do the other solutions. Although the second-order solution has sufficient accuracy for smaller-amplitude wave cases, the truncation after the third harmonics causes significant discrepancies in wave form for larger waves. In addition, the second-order model markedly overestimates the first- and second-harmonic amplitudes in transmitted waves. The Boussinesq model provides excellent predictions of wave profile over the shelf even in larger wave cases. However, this model also overestimates the magnitudes of several higher harmonics in transmitted waves. These facts may indicate that energy transfer from bound components into free waves in these higher harmonics cannot be accurately evaluated by the Boussinesq-type equations.     

Melting of iron–silicon alloy up to the core–mantle boundary pressure: implications to the thermal structure of the Earth’s core

The melting temperature of Fe–18 wt% Si alloy was determined up to 119 GPa based on a change of laser heating efficiency and the texture of the recovered samples in the laser-heated diamond anvil cell experiments. We have also investigated the subsolidus phase relations of Fe–18 wt% Si alloy by the in-situ X-ray diffraction method and confirmed that the bcc phase is stable at least up to 57 GPa and high temperature. The melting curve of the alloy was fitted by the Simon’s equation, P(GPa)/a = (T _m(K)/T ₀) ^c , with parameters, T ₀ = 1,473 K, a = 3.5 ± 1.1 GPa, and c = 4.5 ± 0.4. The melting temperature of bcc Fe–18 wt% Si alloy is comparable with that of pure iron in the pressure range of this work. The melting temperature of Fe–18 wt% Si alloy is estimated to be 3,300–3,500 K at 135 GPa, and 4,000–4,200 K at around 330 GPa, which may provide the lower bound of the temperatures at the core–mantle boundary and the inner core–outer core boundary if the light element in the core is silicon.     

Periodic activity of Comet Bradfield 1987s

A periodic brightness variation of about 6 days was found by applying maximum entropy method to the visual brightness of Comet Bradfield 1987s. This activity was clearly apparent in January of 1988. No other outstanding period was detected. This suggests that the period of the rotation or precession of the nucleus is about 6 days.