The stability and equation of state for the cotunnite phase of TiO2 up to 70 GPa

The stability and equation of state for the cotunnite phase in TiO₂ were investigated up to a pressure of about 70 GPa by high-pressure in situ X-ray diffraction measurements using a laser-heated diamond anvil cell. The transition sequence under high pressure was rutile → α-PbO₂ phase → baddeleyite phase → OI phase → cotunnite phase with increasing pressure. The cotunnite phase was the most stable phase at pressures from 40 GPa to at least 70 GPa. The equation of state parameters for the cotunnite phase were established on the platinum scale using the volume data at pressures of 37–68 GPa after laser annealing, in which the St value, an indicator of the magnitude of the uniaxial stress component in the samples, indicates that these measurements were performed under quasi-hydrostatic conditions. The third-order Birch-Murnaghan equation of state at K ₀′ = 4.25 yields V ₀ = 15.14(5) cm³/mol and K ₀ = 294(9), and the second-order Birch-Murnaghan equation of state yields V ₀ = 15.11(5) cm³/mol and K ₀ = 306(9). Therefore, we conclude that the bulk modulus for the cotunnite phase is not comparable to that of diamond.     

Elemental abundances in the Milky Way stellar disk(s), bulge,and halo

We present a review of elemental abundances in the Milky Way stellar disk, bulge, and halo with a focus on data derived from high-resolution stellar spectra. These data are fundamental in disentangling the formation history and subsequent evolution of the Milky Way. Information from such data is still limited and confined to narrowly defined stellar samples. The astrometric Gaia satellite will soon be launched by the European Space Agency. Its final data set will revolutionize information on the motions of a billion stars in the Milky Way. This will be complemented by several ground-based observational campaigns, in particular spectroscopic follow-up to study elemental abundances in the stars in detail. Our review shows the very rich and intriguing picture built from rather small and local samples. The Gaia data deserve to be complemented by data of the same high quality that have been collected for the solar neighborhood.     

Formation of the Galactic Stellar Halo: Origin of the Metallicity-Eccentricity Relation

Motivated by the recently improved knowledge on the kinematic and chemical properties of the Galactic metal-poor stars, we present the numerical simulation for the formation of the Galactic stellar halo to interpret the observational results. As a model for the Galaxy contraction, we adopt the currently standard theory of galaxy formation based on the hierarchical assembly of the cold dark matter fluctuations. We find, for the simulated stars with &sqbl0;Fe&solm0;H&sqbr0;相似文献   

Genesis of magmas producing pumice flow and fall deposits of towada caldera,Japan

Towada caldera, lying near the northern end of Honsyu, Japan was constructed by eruptions of lavas and pyroclastic materials in three separate periods. At the ends of the first and second periods, great amounts of pumice were erupted in the form of pumice flow and fall respectively. Each pumice cruption was followed by collapse of the center of the cones resulting in double calderas. The lavas of these three periods and the pumice of the first and second periods were chemically analysed. The result was plotted in several different types of variation diagrams. The points for the lavas and pumice lie generally on smooth curves, indicating that the magmas which caused the pumice cruptions belong to the same general differentiation series as do the lavas. If SiO₂/FeO+Fe₂O, is plotted against sodification index (MgO x 100/MgO+FeO+Fe₂O, +Na₂O+K₂O), points for the lavas lie on a straight line, whereas those for the pumice lie on another straight line branching from the former at some point in the middle stage of differentiation. The rate of increase of this ratio in the pumice is greater than in the lavas, implying that less SiO₂ and more iron were subtracted from the magmas producing the pumice than from those producing the lavas. This was probably caused by crystallization of a greater amount of magnetite in the former magmas possibly due to higher oxygen partial pressure which may be in turn related to higher water content. It is not necessary to postulate melting of the crust in order to generate magmas of the pumice eruptions of the central type.     

Development of density measurement for metals at high pressures and high temperatures using X-ray absorption imaging combined with externally heated diamond anvil cell

A technique for density measurement under high pressure and high temperature was developed using the X-ray absorption imaging method combined with an externally heated diamond anvil cell. The densities of solid and liquid In were measured in the pressure and temperature ranges of 3.2–18.6 GPa and 294–719 K. The densities obtained through the X-ray absorption imaging method were in good agreement (less than 2.0% difference) with those obtained through X-ray diffraction. Based on the measured density, the isothermal bulk modulus of solid In is determined as 48.0 ± 1.1?40.9 ± 0.8 GPa at 500 K, assuming K′ = 4 to 6. The compression curve of liquid In approaches that of solid In at higher pressures and does not cross over the solid compression curve in the measurement range. The present technique enables us to determine the densities of both solids and liquids precisely in a wide pressure and temperature range.     

Iron-water reaction at high pressure and temperature, and hydrogen transport into the core

We observed a direct reaction of metallic iron with water to form iron hydride and iron oxide, 3Fe + H₂O–>2FeH_x + FeO, at pressures from 6 GPa to 84 GPa and temperatures above 1,000 K in diamond anvil cell (DAC). Iron hydride is dhcpFeH_x or -FeH_x, and iron oxide has the rhombohedral or B1 structure at pressures at least up to 37 GPa. The formation of an assembly composed of dhcpFeH_x and FeO with the B8 structure was observed at 84 GPa. In primordial Earth, water formed by dehydration of the low temperature primitive materials reacts with metallic iron in the high temperature component to form iron hydride FeH_x and iron oxide FeO. The former would be incorporated in the iron forming the core. Thus hydrogen could be an important element of the Earths core. This reaction would be essential for transport of hydrogen into the core in the accretion stage of the Earth.     

A note on the height dependence of the skewness and the kurtosis of the vertical turbulent velocity in the neutral surface layer

Several experimental results indicate that S _w (the skewness of the vertical turbulent velocity) increases with height, and K _w (the kurtosis) decreases with height in the neutral surface layer. The measured behavior of S _w and K _w with height under neutral conditions is shown to be consistent with available models for the gradient-diffusion and the pressure-velocity correlation. In addition, an estimate of the mode of the probability density distribution turns out to be helpful in interpreting the height dependence of K _w.