The nature of scattered and concretion pyrite in the Upper Abalak Formation of the Salym oil field (Western Siberia)

Dispersed and concretionary pyrite in chert–clay–carbonate and carbonate rocks of the Abalak Formation (Salym oil field) have been studied. The study was conducted using Scanning Electron Microscopy (SEM), Electron Probe Microanalysis (EPMA), and high spatial resolution Secondary Ion Mass Spectrometry (Nano-SIMS). As a result, three morphological groups of pyrite have been distinguished: large cubic crystals, framboidal pyrite, and fine-crystal aggregates that replace organic remnants. The sulphur isotope ratio allows one to distinguish two genetic types of pyrite. The source of the sulphur for the first genetic group was H₂S produced by bacterial sulphate reduction, while the second group pyrite was formed with sulphur as a product of thermochemical sulphate reduction.     

Measures for groundwater security during and after the Hanshin-Awaji earthquake (1995) and the Great East Japan earthquake (2011), Japan

Many big earthquakes have occurred in the tectonic regions of the world, especially in Japan. Earthquakes often cause damage to crucial life services such as water, gas and electricity supply systems and even the sewage system in urban and rural areas. The most severe problem for people affected by earthquakes is access to water for their drinking/cooking and toilet flushing. Securing safe water for daily life in an earthquake emergency requires the establishment of countermeasures, especially in a mega city like Tokyo. This paper described some examples of groundwater use in earthquake emergencies, with reference to reports, books and newspapers published in Japan. The consensus is that groundwater, as a source of water, plays a major role in earthquake emergencies, especially where the accessibility of wells coincides with the emergency need. It is also important to introduce a registration system for citizen-owned and company wells that can form the basis of a cooperative during a disaster; such a registration system was implemented by many Japanese local governments after the Hanshin-Awaji Earthquake in 1995 and the Great East Japan Earthquake in 2011, and is one of the most effective countermeasures for groundwater use in an earthquake emergency. Emphasis is also placed the importance of establishing of a continuous monitoring system of groundwater conditions for both quantity and quality during non-emergency periods.     

Simplified formulae for designing coastal forest against tsunami run-up: one-dimensional approach

In the present study, laboratory experiments were conducted to validate the applicability of a numerical model based on one-dimensional nonlinear long-wave equations. The model includes drag and inertia resistance of trees to tsunami flow and porosity between trees and a simplified forest in a wave channel. It was confirmed that the water surface elevation and flow velocity by the numerical simulations agree well with the experimental results for various forest conditions of width and tree density. Further, the numerical model was applied to prototype conditions of a coastal forest of Pandanus odoratissimus to investigate the effects of forest conditions (width and tree density) and incident tsunami conditions (period and height) on run-up height and potential tsunami force. The modeling results were represented in curve-fit equations with the aim of providing simplified formulae for designing coastal forest against tsunamis. The run-up height and potential tsunami forces calculated by the curve-fit formulae and the numerical model agreed within ± 10% error.     

Optical properties of the red tide in Isahaya Bay,southwestern Japan: Influence of chlorophyll a concentration

Remote sensing reflectance [R _rs(λ)] and absorption coefficients of red tides were measured in Isahaya Bay, southwestern Japan, to investigate differences in the optical properties of red tide and non-red tide waters. We defined colored areas of the sea surface, visualized from shipboard, as “red tides”. Peaks of the R _rs(λ) spectra of non-red tide waters were at 565 nm, while those of red tides shifted to longer wavelengths (589 nm). The spectral shape of R _rs(λ) was close to that of the reciprocal of the total absorption coefficient [1/a(λ)], implying that the R _rs(λ) peak is determined by absorption. Absorption coefficients of phytoplankton [a _ph(λ)], non-pigment particles and colored dissolved organic matter increased with increasing chlorophyll a concentration (Chl a), and those coefficients were correlated with Chl a for both red tide and non-red tide waters. Using these relationships between absorption coefficients and Chl a, variation in the spectrum of 1/a(λ) as a function of Chl a was calculated. The peak of 1/a(λ) shifted to longer wavelengths with increasing Chl a. Furthermore, the relative contribution of a _ph(λ) to the total absorption in red tide water was significantly higher than in non-red tide water in the wavelength range 550–600 nm, including the peak. Our results show that the variation of a _ph(λ) with Chl a dominates the behavior of the R _rs(λ) peak, and utilization of R _rs(λ) peaks at 589 and 565 nm may be useful to discriminate between red tide and non-red tide waters by remote sensing.     

Effect of open gap in coastal forest on tsunami run-up—investigations by experiment and numerical simulation

The objective of this study is to investigate the effects of an open gap, such as a road, in a coastal forest on tsunami run-up. A numerical model based on two-dimensional nonlinear long-wave equations was developed to account for the effects of drag and turbulence induced shear forces due to the presence of vegetation. Experiments were conducted on a forest simulated with vertical cylinders by changing the gap width. The numerical model was validated in good agreement with the experimental results. The numerical model was then applied to a wide forest of Pandanus odoratissimus, a tree species that is a dominant coastal vegetation on a sand dune in South and Southeast Asia. The effect of vertical stand characteristics of P. odoratissimus with aerial roots was considered on the drag resistance. A straight open gap perpendicular to the shoreline was used to investigate the effect of gap width. As the gap width increases, the flow velocity at the end of the open gap first increases, reaches a maximum, and then decreases, while the run-up height increases monotonously. The maximum velocity in the present condition is 1.7 times the maximum velocity without a coastal forest. The effects of different gap arrangements in the forest on tsunami run-up were also investigated in this paper. The flow velocity at the end of an open gap can be reduced by a staggered arrangement.     

A note on the chemical composition of lake water in the Laguna Amarga,a saline lake in Patagonia,Chile

The chemical composition of lake water in Laguna Amarga, a small, shallow, saline lake near the Torres del Paine National Park (at 51°S), Chilean Patagonia, was studied in January, 1993. The water was strongly alkaline (pH 9.4) conductivity was 71.4 mS cm^–1, and salinity was 77 g L^–1. The major ions were sodium and sulphate.     

Numerical study of the oxidation process of dimethylsulfide in the marine atmosphere

A box model, involving simple heterogeneous reaction processes associated with the production of non-sea-salt sulfate (nss-SO ₄ ^2– ) particles, is used to investigate the oxidation processes of dimethylsulfide (DMS or CH₃SCH₃) in the marine atmosphere. The model is applied to chemical reactions in the atmospheric surface mixing layer, at intervals of 15 degrees latitude between 60° N and 60° S. Given that the addition reaction of the hydroxyl radical (OH) to the sulfur atom in the DMS molecule is faster at lower temperature than at higher temperature and that it is the predominant pathway for the production of methanesulfonic acid (MSA or CH₃SO₃H), the results can well explain both the increasing tendency of the molar ratio of MSA to nss-SO ₄ ^2– toward higher latitudes and the uniform distribution with latitude of sulfur dioxide (SO₂). The predicted production rate of MSA increases with increasing latitude due to the elevated rate constant of the addition reaction at lower temperature. Since latitudinal distributions of OH concentration and DMS reaction rate with OH are opposite, a uniform production rate of SO₂ is realized over the globe. The primary sink of DMS in unpolluted air is caused by the reaction with OH. Reaction of DMS with the nitrate radical (NO₃) also reduces DMS concentration but it is less important compared with that of OH. Concentrations of SO₂, MSA, and nss-SO ₄ ^2– are almost independent of NO _x concentration and radiation field. If dimethylsulfoxide (DMSO or CH₃S(O)CH₃) is produced by the addition reaction and further converted to sulfuric acid (H₂SO₄) in an aqueous solution of cloud droplets, the oxidation process of DMSO might be important for the production of aerosol particles containing nss-SO ₄ ^2– at high latitudes.