Can local linear stochastic theory explain sea surface temperature and salinity variability?

 Sea surface temperature (SST) and salinity (SSS) time series from four ocean weather stations and data from an integration of the GFDL coupled ocean-atmosphere model are analyzed to test the applicability of local linear stochastic theory to the mixed-layer ocean. According to this theory, mixed-layer variability away from coasts and fronts can be explained as a ‘red noise’ response to the ‘white noise’ forcing by atmospheric disturbances. At one weather station, Papa (northeast Pacific), this stochastic theory can be applied to both salinity and temperature, explaining the relative redness of the SSS spectrum. Similar results hold for a model grid point adjacent to Papa, where the relationships between atmospheric energy and water fluxes and actual changes in SST and SSS are what is expected from local linear stochastic theory. At the other weather stations, this theory cannot adequately explain mixed-layer variability. Two oceanic processes must be taken into account: at Panulirus (near Bermuda), mososcale eddies enhance the observed variability at high frequencies. At Mike and India (North Atlantic), variations in SST and SSS advection, indicated by the coherence and equal persistence of SST and SSS anomalies, contribute to much of the low frequency variability in the model and observations. To achieve a global perspective, TOPEX altimeter data and model results are used to identify regions of the ocean where these mechanisms of variability are important. Where mesoscale eddies are as energetic as at Panulirus, indicated by the TOPEX global distribution of sea level variability, one would expect enhanced variability on short time scales. In regions exhibiting signatures of variability similar to Mike and India, variations in SST and SSS advection should dominate at low frequencies. According to the model, this mode of variability is found in the circumpolar ocean and the northern North Atlantic, where it is associated with the irregular oscillations of the model’s thermohaline circulation. Received: 11 March 1996 / Accepted: 6 September 1996     

A pre-screened and normalized multiple endmember spectral mixture analysis for mapping impervious surface area in Lake Kasumigaura Basin,Japan

The impervious surface area (ISA) has emerged not only as an indicator of the degree of urbanization, but also as a major indicator of environmental quality for drainage basin management. However, since almost all of the methods for estimating ISA have been developed for urban environments, it is questionable whether these methods can be successfully applied to drainage basins, such as those found in Japan, which usually have more complicated vegetation components (e.g. paddy field, plowed field and dense forest). This paper presents a pre-screened and normalized multiple endmember spectral mixture analysis (PNMESMA) method, which includes a new endmember selection strategy and an integration of the normalized spectral mixture analysis (NSMA) and multiple endmember spectral mixture analysis (MESMA), for estimating the ISA fraction in Lake Kasumigaura Basin, Japan. This new proposed method is superior to the previous methods in that the estimation error of the proposed method is much smaller than the previous SMA- or NSMA-based methods for drainage basin environments. The overall root mean square error was reduced to 5.2%, and no obvious underestimation or overestimation occurred for high or low ISA areas. Through the assessment of environmental quality in Lake Kasumigaura Basin using the ISA fraction, the results showed that the basin has been in the impacted category since 1987, and that in the two decades since, the environmental quality has continued to decline. If this decline continues, then Lake Kasumigaura Basin will fall into the degraded category by 2017.     

Vertical vibration isolator having piecewise‐constant restoring force

We present a vertical vibration isolator having a piecewise‐constant restoring force, which belongs to a class of passive and nonlinear vibration isolators. In vertical vibration isolation, direct use of low‐stiffness elements leads to unacceptably large deformations due to self‐weight. To overcome the difficulty, we apply a combination of constant‐force springs, each of which sustains a constant load regardless of its stretch. By arranging the constant‐force springs, so that the isolator has a piecewise‐constant restoring force, we alleviate the problem of the excessive deformation caused by self‐weight, provide stability at the static equilibrium state along with the self‐centering capability, and realize a large stroke while keeping the mechanism simple and compact. Further, we attempt to limit the response acceleration within a tolerance regardless of the frequency spectrum and the magnitude of earthquake ground motions. We demonstrate the effectiveness of the present isolator through shaking table tests and numerical simulations. Copyright © 2009 John Wiley & Sons, Ltd.     

Reaction of forsterite with hydrogen molecules at high pressure and temperature

High pressure and temperature reactions of a mixture of forsterite and hydrogen molecules have been carried out using a laser heated diamond anvil cell at 9.8–13.2 GPa and ~1,000 K. In situ X-ray diffraction measurements showed no sign of decomposition or phase transitions of the forsterite under these experimental conditions, indicating that the olivine structure was maintained throughout all runs. However, a substantial expansion of the unit cell volume of the forsterite was observed for samples down to ~3 GPa upon quenching to ambient pressure at room temperature. The Raman spectroscopy measurements under pressure showed significant shifts of the Raman peaks of the Si–O vibration modes for forsterite and of the intramolecular vibration mode for H₂ molecules toward a lower frequency after heating. Additionally, no OH vibration modes were observed by Raman and FT-IR spectroscopic measurements. These lines of evidence show that the observed volume expansion in forsterite is not explained by the incorporation of hydrogen atoms as hydroxyl, but suggest the presence of hydrogen as molecules in the forsterite structure under these high pressure and temperature conditions.     

Synthesis of crystallographically oriented olivine aggregates using colloidal processing in a strong magnetic field

This study develops a fabrication technique to obtain Fe-free and Fe-bearing (Fe:Mg = 1:9) olivine aggregates not only with high density and fine grain size but with crystallographic preferred orientation (CPO). A magnetic field (≤12 T) is applied to synthetic, fine-grained (~120 nm), olivine particles dispersed in solvent. The alignment of certain crystallographic axes of the particles with respect to a magnetic direction is anticipated due to magnetic anisotropy of olivine. The dispersed particles are gradually consolidated on a porous alumina mold covered with a solid–liquid separation filter during drainage of the solvent. The resultant aligned consolidated aggregate is then isostatically pressed and vacuum sintered. We find that (1) preparation of fully reacted olivine particles, with less propensity to coalesce; (2) preparation of a suspension with highly dispersed particles; and (3) application of a certain strength of the magnetic field are essential to obtain well-sintered and well-aligned aggregates. High density (i.e., <1 vol% porosity) and fine grain size (~1 μm) Fe-free and Fe-bearing olivine aggregates were successfully synthesized with uniaxially aligned a- and c-axes, respectively. Attempts to uniaxially align the magnetization hard axis and to triaxially align Fe-bearing olivine by rotating the suspension in the magnetic field succeeded in obtaining weakly developed CPO aggregates.     

Morphology of intergranular pores and wetting angles in pelitic schists studied by transmission electron microscopy

In pelitic schists composed mainly of quartz and albite grains, the morphology of intergranular pores, which were filled with water, was studied by transmission electron microscopy (TEM). Although some pores are defined by crystallographic planes (F-face), most of their form has an ideal shape determined by interface tensions between grains and fluid. High-resolution TEM observations demonstrate that pore-free regions at grain boundaries are tight even at the nanometer scale, showing that the wetting angle is larger than 0° in this rock. The pore distribution in two-grain junctions can be compared to a "necklace microstructure" developed by instability of a fluid film along the boundary induced by microcracking. Wetting angles for pores located at grain edges of quartz and albite decrease in the order albite/albite, quartz/quartz, and quartz/albite. The quartz/quartz wetting angle in a calcite-free sample is smaller than that in a calcite-containing sample. This angle also changes due to grain misorientation. Our results confirm that solid-solid and solid-fluid interfacial energies control the geometry of intergranular fluid in natural rocks.     

Identification of Lower Pleistocene widespread tephras associated with large caldera-forming eruptions in the Tohoku area,north-east Japan

Tephra fingerprinting techniques contributing to volcanology and palaeoenvironmental studies have been developed using a combination of laser-ablation inductively coupled-plasma mass spectrometry (LA-ICP-MS) and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS). In particular, femtosecond LA-ICP-MS can determine major- and trace element abundances in individual glass shards. On the basis of the major oxide and trace element composition of the glass shards, using those methods, we re-examined the identification of four lower Pleistocene tephras originating from north-east Japan. All trace element abundances exhibited the typical pattern of tephras from the Hokkaido–Tohoku area, and major element concentrations were distinct. As a result, we re-examined the correlation of the widespread Tmg-R4 tephra (2.0 Ma), and newly defined the widespread Kd44-Naka tephra (1.968–1.781 Ma), both originating from the Sengan geothermal region. Furthermore, we re-examined identifications of Sr-Asn-Kd8 (1.219 Ma) and Sr-Kc-U8 (0.922–0.910 Ma) in central Japan, both derived from the Aizu volcanic region. The extensive distributions of the former two tephras suggest the occurrence of two large caldera-forming eruptions (Volcanic Explosivity Index 7) during a short period. Also, the distributions and volumes of the latter two tephras are broader and larger than those previously assumed. The results provide insight into large volcanic eruption history and terrestrial and marine palaeoenvironmental history.     

Characterization and correlation of the Hegawa-Kasamori 5 tephra,a widespread tephra aged c. 450 ka associated with large-scale pyroclastic flows from southern Kyushu,SW Japan

A Middle Pleistocene widespread tephra, defined here as Hegawa-Kasamori 5 tephra (Hgw-Ks5), has been newly recognized over a broad area of Japan. Large-scale pyroclastic flow deposits associated with co-ignimbrite ash fall deposits (CAFDs) of Hgw-Ks5 have been identified in the proximal southern Kyushu area, south-west Japan. Hgw-Ks5 possibly originated from the Aira caldera in southern Kyushu, and it is widely spread and intercalated with deposits of the Kasamori Formation, Honshu Island, more than 1000 km away from the source. In the north-west area of the Aira Caldera, the tephra is sparsely distributed in the form of non-welded ignimbrites, and is exposed stratigraphically above the well-known Kobayashi-Kasamori tephra. Hgw-Ks5 is characterized through petrographic features, major element geochemistry of glass shards, and refractive indices of orthopyroxene. The results of previous stratigraphic isotope studies indicate that the eruptive age of Hgw-Ks5 is 434–458 ka (Marine Isotope Stage 12). Assuming that the CAFDs originating from the Aira Caldera are distributed concentrically, the apparent volume of Hgw-Ks5, estimated from the area of distribution and CAFD thickness, is ~100 km³. Therefore, a volcanic explosivity index of 7 is assigned to the Hgw-Ks5 eruption.     

Direct evidence for nitrogen isotope discrimination during sedimentation and early diagenesis in Lake Kasumigaura, Japan

Sediment core samples from the center of Lake Kasumigaura, Japan, were collected from 1979 to 2007 at intervals of 1 month to 5 yr. We evaluated the degree of modification in N isotope composition during sedimentation and diagenesis. We estimated the degree of isotope discrimination during diagenesis by comparing historical changes in N isotope composition of the surface sediment (top 2 cm) against the vertical profile of the isotope composition of sediment core samples (15 cm depth). The degree of ¹⁵N enrichment during sedimentation appeared to be significant under the preferential N decomposition that occurred in the periods with low C/N ratio values of suspended particulate organic matter. We documented ¹⁵N depletion in sediment deeper than approximately 3 cm during diagenesis. The contrasting directions of N isotope discrimination during sedimentation and diagenesis suggest changing mechanisms of isotopic shift across an oxidation-reduction boundary.     

Use of flood chronology for detailed environmental analysis: a case study of Lake Kizaki in the northern Japanese Alps,central Japan

This paper presents a study of the usefulness of flood layers as a time marker in sediments and a report of a case study of Lake Kizaki in central Japan. A flood layer can be identified as a layer having a higher density, coarser grain size, lower TN content, and higher C/N ratio than those of the upper and lower horizons. It can also be characterized by a hyperpycnal sequence composed of a basal coarsening-upward unit and a top fining-upward unit. When flood layers can be correlated with heavy rains in meteorological records, detailed age markers are well established in the sediment. Five flood layers were identified in the surface sediment of Lake Kizaki, and they could be attributed to the historical heavy rainfalls that took place on July 12, 1995; September 28, 1983; August 25, 1974; September 26, 1959; and September 1, 1949 under the constraint of an age model. A precise age model is essential to clarify the environmental changes such as the pollutant history in detail.