Recent Occurrences of Dinophysis fortii (Dinophyceae) in the Okkirai Bay, Sanriku, Northern Japan, and Related Environmental Factors

Occurrence of Dinophysis fortii, a causative organism of diarrhetic shellfish poisoning, in the Okkirai Bay, Sanriku was surveyed in 1995, 1996, 1998 and 1999. In each year, its major occurrence was detected from the late May or early June and continued until the late June or early July. Seawater temperature, salinity and nutrients measurements suggested that inflows of offshore water into the bay played key role on the first major occurrence of D. fortii. With an analysis of continuous temperature data in the Otsuchi Bay which locates north of the Okkirai Bay, this influent was considered to be intermittent inflow of the offshore water by internal tidal waves which propagated from north to south. First occurrence peak of D. fortii was synchronous with phycobilin containing microalgae, synechococcoid cyanobacteria and cryptomonad, in all years. In vivo fluorescence measurement of D. fortii cells in 1995 and 96 showed that the cells in these microalgal-rich water contained more phycobilin pigment than those in the microalgal-poor water. The result may support a hypothesis that D. fortii acquires phycobilin by an uptake of these microalgae. After the first major occurrence in the bay, D. fortii sometimes occurred in rather inshore waters where showed elevated ammonium level possibly due to increased heterotrophic activity. Together with another finding that D. fortii is mixotrophic, it could be assumed that the environment being suited to heterotrophic nutrition also stimulates D. fortii growth in the bay.     

Preferential dissolution of SiO<Subscript>2</Subscript> from enstatite to H<Subscript>2</Subscript> fluid under high pressure and temperature

Stability and phase relations of coexisting enstatite and H₂ fluid were investigated in the pressure and temperature regions of 3.1–13.9 GPa and 1500–2000 K using laser-heated diamond-anvil cells. XRD measurements showed decomposition of enstatite upon heating to form forsterite, periclase, and coesite/stishovite. In the recovered samples, SiO₂ grains were found at the margin of the heating hot spot, suggesting that the SiO₂ component dissolved in the H₂ fluid during heating, then precipitated when its solubility decreased with decreasing temperature. Raman and infrared spectra of the coexisting fluid phase revealed that SiH₄ and H₂O molecules formed through the reaction between dissolved SiO₂ and H₂. In contrast, forsterite and periclase crystals were found within the hot spot, which were assumed to have replaced the initial orthoenstatite crystals without dissolution. Preferential dissolution of SiO₂ components of enstatite in H₂ fluid, as well as that observed in the forsterite H₂ system and the quartz H₂ system, implies that H₂-rich fluid enhances Mg/Si fractionation between the fluid and solid phases of mantle minerals.     

Characterizing the flush of stream chemical runoff from forested watersheds

A flush can be defined as stream chemical exhibiting higher concentrations during the prophase of a storm event at an event scale, or exhibiting progressively lower concentrations during several successive storms at a seasonal scale. Investigating the flush characteristics of chemical runoff from forested watersheds is important and helpful to understand the chemical dynamics as well as to design a sampling schedule strategy during storm events. Here, three parameters describing the flush characteristic are quantified and the flush characteristics of chemicals from four Japanese forested watersheds (Mie, Kochi, Nagano and Tokyo) were investigated at both event and seasonal levels. We found that the characteristics of the flush were complicated, and depended on the constituents of the hydrochemistry, climate and runoff quality. Generally, the flush occurs more readily for particulate components than for those in solution; the flush on nitrate‐nitrogen is weaker in regions of nitrogen saturation, such as Nagano and Tokyo, than in Mie and Kochi. Rainfall feature was the main factor controlling the flush of particulate components. However, the source available in a watershed plays a main role on the flushes of dissolve chemicals. Copyright © 2010 John Wiley & Sons, Ltd.     

Nutrient and Phytoplankton Dynamics in Harima-Nada, Eastern Seto Inland Sea, Japan During a 35-Year Period from 1973 to 2007

Long-term monitoring of water quality and phytoplankton was conducted at 19 sampling stations in Harima-Nada, eastern Seto Inland Sea, Japan for 35 years from 1973 to 2007. There were two significant long-term changes, an increase in winter water temperatures of 0.042°C year^?1, and a decrease in dissolved inorganic nitrogen (DIN) from about 10 μM in the 1970s to ~5 μM in the late 1990s due to the reduction in nutrient inputs. DIN concentrations and total phytoplankton cell density were both higher during the 1970s to the early 1980s and then exhibited a significant decrease in the mid 1980s and remained relatively constant thereafter. Diatoms were the dominant phytoplankton group (>90%) over the 35-year period, and there was a dramatic shift from Skeletonema dominance (~70%) to Chaetoceros in the mid 1980s. This shift in diatom species may be attributed to differences in the life cycle of Skeletonema and Chaetoceros and the response to the decrease in DIN concentration.     

Pressure responses of portlandite and H–D isotope effects on pressure-induced phase transitions

The pressure responses of portlandite and the isotope effect on the phase transition were investigated at room temperature from single-crystal Raman and IR spectra and from powder X-ray diffraction using diamond anvil cells under quasi-hydrostatic conditions in a helium pressure-transmitting medium. Phase transformation and subsequent peak broadening (partial amorphization) observed from the Raman and IR spectra of Ca(OH)₂ occurred at lower pressures than those of Ca(OD)₂. In contrast, no isotope effect was found on the volume and axial compressions observed from powder X-ray diffraction patterns. X-ray diffraction lines attributable to the high-pressure phase remained up to 28.5 GPa, suggesting no total amorphization in a helium pressure medium within the examined pressure region. These results suggest that the H–D isotope effect is engendered in the local environment surrounding H(D) atoms. Moreover, the ratio of sample-to-methanol–ethanol pressure medium (i.e., packing density) in the sample chamber had a significant effect on the increase in the half widths of the diffraction lines, even at pressures below the hydrostatic limit of the pressure medium.     

Horizontal structure of planetary-scale waves at the cloud top of Venus deduced from Galileo SSI images with an improved cloud-tracking technique

An improved cloud tracking method for deriving wind velocities from successive planetary images was developed. The new method incorporates into the traditional cross-correlation method an algorithm that corrects for erroneous cloud motion vectors by re-determining the most plausible correlation peak among all of the local maxima on the correlation surface by comparing each vector with its neighboring vectors. The newly developed method was applied to the Venusian violet images obtained by the Solid State Imaging system (SSI) onboard the Galileo spacecraft during its Venus flyby. Although the results may be biased by the choice of spatial scale of atmospheric features, the cloud tracking is the most practical mean of estimating the wind velocities with extensive spatial and temporal coverage. The two-dimensional distribution of the horizontal wind vector field over 5 days was obtained. It was found from these wind maps that the solar-fixed component in 1990 was similar to that in 1982 obtained by the Pioneer Venus orbiter. The deviation of the instantaneous zonal wind field from the solar-fixed component shows a distinct wavenumber-1 structure in the equatorial region. On the assumption that this structure is a manifestation of an equatorial Kelvin wave, the phase relationship between the zonal wind and the cloud brightness suggests a short photochemical lifetime of the violet absorber. The momentum deposition by this Kelvin wave, which is subject to radiative damping, would induce a westward mean-wind acceleration of ～0.3 m s^?1 per Earth day.     

Reconstruction of historical pressure patterns over Japan using two-point pressure–temperature datasets since the nineteenth century

The temperature and pressure differences between Tokyo and Nagasaki were used to reconstruct past climate conditions. January and July in each available year since the 1820s were classified into several types with characteristic sea level atmospheric pressure patterns. This results in 18 years of pre-1881 data and a continuous series thereafter. The series indicate that the warming after 1900 (after the end of the so-called Little Ice Age) and again after 1960 can at least partly be attributed to an increase in the frequency of warm circulation pattern types at the expense of cold types. The difference in nature of the shifts in circulation types that occurred in the late nineteenth century compared with that in the late twentieth centuries suggests that the mechanism behind the warming in the late nineteenth century differs from that in the late twentieth century.     

Tasks and problems involved in the handling of disaster waste upon April 2016 Kumamoto Earthquake,Japan

The potential impacts of tsunamis along the Catalan Coast (NW Mediterranean) are analysed using numerical modelling. The region is characterized by moderate to low seismic activity and by moderate- to low-magnitude earthquakes. However, the occurrence of historical strong earthquakes and the location of several active offshore faults in front of the coast suggest that the possibility of an earthquake-triggered tsunami is not negligible although of low probability. Up to five faults have been identified to generate tsunamis, being the highest associated possible seismic magnitudes of up to 7.6. Coastal flooding and port agitation are characterized using the Worst-case Credible Tsunami Scenario Analysis approach. The results show a multiple fault source contribution to tsunami hazard. The shelf dimensions and the existence of submerged canyons control the tsunami propagation. In wide shelves, waves travelling offshore may become trapped by refraction causing the wave energy to reach the coastline at some distance from the origin. The free surface water elevation increases at the head of the canyons due to the sharp depth gradients. The effects of potential tsunamis would be very harmful in low-lying coastal stretches, such as deltas, with a high population concentration, assets and infrastructures. The Ebro delta appears to be the most exposed coast, and about the 20% of the delta surface is prone to flooding due to its extremely low-lying nature. The activity at Barcelona port will be severely affected by inflow backflow current at the entrance of up to 2 m/s.     

Evaluation of Containment Performance from Viewpoints of Diffusion and Dispersion for Impervious Structures at Coastal Landfill Sites

The containment performance of impervious structures is considered the most important performance, which the toxic substances are enclosed in coastal landfill sites. The containment performance is evaluated generally by the hydraulic conductivity and the thickness of impervious structures to focus on an advection. However, the leakage of toxic substances is affected by a diffusion and a dispersion. The diffusion and the dispersion are considered to be easily distinguished on the impervious structure which has the low-hydraulic conductivity. Such phenomena should be considered due to evaluate the containment performance. This is because to improve the containment performance and comprehend leakage of the toxic substances. The containment performance is evaluated from the viewpoint of the diffusion and the dispersion in this research. Concretely, the influence which the toxic substances leaks from impervious structures on the diffusion and the dispersion is evaluated by the infiltration and advection–dispersion analysis on steel-made side impervious walls. In other word, The relation between the leaking amount of toxic substances and coefficient of molecular diffusion, the relation between the travel time or the flow velocity and the leaking amount and the change in the water-level difference are considered respectively. So, the leaking amount which is influenced by a diffusion and a dispersion is considered. Consideration about to secure the containment performance of impervious structure which is restrained leakage by a diffusion and a dispersion.     

Structure and crystal chemistry of perovskite-type MgSiO3

Synthetic clinoenstatite (MgSiO₃) has been converted to a single phase with the perovskite structure in complete reactions at approx. 300 kbar in experiments that utilize the laser-heated diamond-anvil pressure apparatus. The structure of this phase after quenching was determined by powder X-ray diffraction intensity measurement to be similar to that of the distorted rare-earth, orthoferrite-type, orthorhombic perovskites, but it is suggested that such distortion from ideal cubic perovskite would diminish at high pressure. The unit cell dimensions and density of perovskite-type MgSiO₃ at ambient conditions (1 bar, 25°C) are a=4.780(1) Å, b=4.933(1) Å, c=6.902(1) Å, V=162.75 ų, and ρ=4.098(1) g/cm³. This phase is 3.1% denser than the isochemical oxide mixture [periclase (MgO)+stishovite (SiO₂)]. The small crystal-field stabilization energy of the cation site in the perovskite structure may play an important role in limiting the high-pressure stability field of perovskites that contain transition metal cations. Approximate calculations of the crystal-field effects indicate that perovskite of pure FeSiO₃ composition may become stable at 400–600 kbar; pressures greater than 800 kbar would be required to stabilize CoSiO₃ or NiSiO₃ perovskite.